Low volatile isocyanate monomer containing polyurethane prepolymer and adhesive system
    1.
    发明申请
    Low volatile isocyanate monomer containing polyurethane prepolymer and adhesive system 审中-公开
    低挥发性异氰酸酯单体含聚氨酯预聚物和粘合剂体

    公开(公告)号:US20060079661A1

    公开(公告)日:2006-04-13

    申请号:US11247655

    申请日:2005-10-11

    Abstract: In one aspect the invention is a composition comprising a prepolymer which is the reaction product of di(isocyanatophenyl)methane or a polymeric di(isocyanatophenyl)methane having an isocyanato functionality of about 2.1 to about 3.0 with a mixture of one or more diols and one or more triols wherein the ratio of isocyanate equivalents to hydroxyl equivalents in the reaction mixtures used to prepare the prepolymer is from about 1.2 to about 1.8 and the ratio of diol to triol where the diisocyanate is a di(isocyanatophenyl)methane in the reaction mixture is from about 5:1 to about 1:1. and where the isocyanate is a polymeric di(isocyanatophenyl)methane is from about 8:1 to about 4:1; wherein the prepolymer could further react with an isocyanate reactive monofunctional compound. The prepolymer herein has an isocyanate content of about 0.5 to about 1.5 percent by weight, a free isocyanate monomer content of about 1.0 percent by weight or less as measured by high pressure liquid chromatography. These prepolymers can be used in many applications including adhesive, sound dampening sealer and coating and especially in making adhesives or adhesive systems with a low content of monomeric isocyanate to bond together similar or dissimilar substrates such as metal, glass, ceramics, plastic and painted steel panel.

    Abstract translation: 在一个方面,本发明是一种组合物,其包含预聚物,其是二(异氰酸根合苯基)甲烷或具有约2.1至约3.0的异氰酸酯官能度的聚合二(异氰酸酯基苯基)甲烷的反应产物与一种或多种二醇和一种 或更多的三醇,其中用于制备预聚物的反应混合物中异氰酸酯当量与羟基当量的比例为约1.2至约1.8,二异氰酸酯是反应混合物中二异氰酸酯基甲烷的二醇与三醇的比例为 约5:1至约1:1。 并且其中异氰酸酯是聚合二(异氰酸酯基苯基)甲烷为约8:1至约4:1; 其中所述预聚物可以进一步与异氰酸酯反应性单官能化合物反应。 本文的预聚物具有约0.5至约1.5重量%的异氰酸酯含量,通过高压液相色谱法测量的约1.0重量%或更少的游离异氰酸酯单体含量。 这些预聚物可用于许多用途,包括粘合剂,防声封闭剂和涂料,特别是在制备具有低含量单体异氰酸酯的粘合剂或粘合剂体系以将类似或不同的基材如金属,玻璃,陶瓷,塑料和涂漆钢板粘合在一起 面板。

    LOW VOLATILE ISOCYANATE MONOMER CONTAINING POLYURETHANE PREPOLYMER AND ADHESIVE SYSTEM
    2.
    发明申请
    LOW VOLATILE ISOCYANATE MONOMER CONTAINING POLYURETHANE PREPOLYMER AND ADHESIVE SYSTEM 审中-公开
    含有聚氨酯预聚物和粘合剂体系的低挥发性异氰酸酯单体

    公开(公告)号:US20080041522A1

    公开(公告)日:2008-02-21

    申请号:US11924114

    申请日:2007-10-25

    Abstract: In one aspect the invention is a composition comprising a prepolymer which is the reaction product of di(isocyanatophenyl) methane or a polymeric di(isocyanatophenyl) methane having an isocyanato functionality of about 2.1 to about 3.0 with a mixture of one or more diols and one or more triols wherein the ratio of isocyanate equivalents to hydroxyl equivalents in the reaction mixtures used to prepare the prepolymer is from about 1.2 to about 1.8 and the ratio of diol to triol where the diisocyanate is a di(isocyanatophenyl) methane in the reaction mixture is from about 5:1 to about 1:1. and where the isocyanate is a polymeric di(isocyanatophenyl) methane is from about 8:1 to about 4:1; wherein the prepolymer could further react with an isocyanate reactive monofunctional compound. The prepolymer herein has an isocyanate content of about 0.5 to about 1.5 percent by weight, a free isocyanate monomer content of about 1.0 percent by weight or less as measured by high pressure liquid chromatography. These prepolymers can be used in many applications including adhesive, sound dampening sealer and coating and especially in making adhesives or adhesive systems with a low content of monomeric isocyanate to bond together similar or dissimilar substrates such as metal, glass, ceramics, plastic and painted steel panel.

    Abstract translation: 在一个方面,本发明是一种组合物,其包含预聚物,其是二(异氰酸根合苯基)甲烷或具有约2.1至约3.0的异氰酸酯官能度的聚合二(异氰酸酯基苯基)甲烷的反应产物与一种或多种二醇和一种 或更多的三醇,其中用于制备预聚物的反应混合物中异氰酸酯当量与羟基当量的比例为约1.2至约1.8,二异氰酸酯是反应混合物中二异氰酸酯基甲烷的二醇与三醇的比例为 约5:1至约1:1。 并且其中异氰酸酯是聚合二(异氰酸酯基苯基)甲烷为约8:1至约4:1; 其中所述预聚物可以进一步与异氰酸酯反应性单官能化合物反应。 本文的预聚物具有约0.5至约1.5重量%的异氰酸酯含量,通过高压液相色谱法测量的约1.0重量%或更少的游离异氰酸酯单体含量。 这些预聚物可用于许多用途,包括粘合剂,防声封闭剂和涂料,特别是在制备具有低含量单体异氰酸酯的粘合剂或粘合剂体系以将类似或不同的基材如金属,玻璃,陶瓷,塑料和涂漆钢板粘合在一起 面板。

    Coated glass articles
    3.
    发明申请
    Coated glass articles 有权
    涂层玻璃制品

    公开(公告)号:US20070151178A1

    公开(公告)日:2007-07-05

    申请号:US11643455

    申请日:2006-12-20

    Abstract: The invention is a composition comprising: a) one or more film forming resins having at least one functional group capable of polymerization; b) one or more reactive diluents capable of reacting with the film forming resin; c) one or more silicon, titanium, zirconium, aluminum or metal containing compounds capable of promoting adhesion of the composition to glass; d) one or more fillers capable of imparting abrasion resistance to the composition when cured; and e) one or more compounds which is reactive with the film forming resin which also contains at least one acidic moiety. The composition of the invention is useful as a frit on the window of a vehicle. Furthermore, the invention relates to a method for applying the coatings to glass and a method for bonding the coated glass to a structure or substrate, for instance, a building.

    Abstract translation: 本发明是一种组合物,其包含:a)一种或多种具有至少一个能够聚合的官能团的成膜树脂; b)能够与成膜树脂反应的一种或多种反应性稀释剂; c)一种或多种能够促进组合物粘附到玻璃上的硅,钛,锆,铝或含金属的化合物; d)当固化时能赋予组合物耐磨性的一种或多种填料; 和e)一种或多种与还含有至少一个酸性部分的成膜树脂反应的化合物。 本发明的组合物可用作车辆窗口上的玻璃料。 此外,本发明涉及一种将涂层施加到玻璃上的方法以及将涂覆的玻璃粘合到例如建筑物的结构或基底上的方法。

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