公开(公告)号：US5026507A

公开(公告)日：1991-06-25

申请号：US347260

申请日：1989-05-04

申请人： John W. Gowan, Jr. ,  David K. Lo

发明人： John W. Gowan, Jr. ,  David K. Lo

IPC分类号： C09K11/06 ,  D21H21/30 ,  D21H27/10

CPC分类号： D21H21/30 ,  C09K11/06 ,  D21H27/10

摘要： A paper additive of high whiteness and low biological toxicity comprising a whitening amount of a compound of the formula ##STR1## wherein R is H or (C.sub.1 -C.sub.6)alkyl R' is independently H or (C.sub.1 -C.sub.6)alkyl, R" is H or NR'.sub.n, and n is 2 or 3, wherein if n=3 the compound further comprises X.sup.-, wherein X.sup.- is an anion.A paper of high whiteness and low biological toxicity is coated or filled with the above additive, and a food product is packaged with the paper of this invention.

摘要翻译： 一种高白度和低生物毒性的纸添加剂，其包含增白量的下式化合物其中R为H或（C 1 -C 6）烷基R'独立地为H或（C 1 -C 6）烷基，R“ 是H或NR'n，n为2或3，其中如果n = 3，该化合物还包含X - ，其中X是阴离子。 用上述添加剂涂布或填充高白度和低生物毒性的纸，并且用本发明的纸包装食品。

公开(公告)号：US4954566A

公开(公告)日：1990-09-04

申请号：US347328

申请日：1989-05-04

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： C08F8/14 ,  C08F8/32

CPC分类号： C08F8/32 ,  C08F8/14

摘要： A one-pot process for preparing a polymer carrying pendant organic residues attached thereto via linking bridges comprises forming an organic solvent solution or suspension of an organic acid, distilling off a water-organic solvent azeotropic solution therefrom to form an organic solvent solution or suspension of the corresponding anhydride of the organic acid, admixing into the organic solvent solution or suspension of the corresponding anhydride a polymer comprising pendant moieties capable of reacting with the --COOH residues of the organic acid derivatized polymer having at least one pendant residue of the organic acid attached thereto via a bridge resulting from the reaction of the --COOH residue of the acid and the pendant reactive residues of the polymer, and free organic acid under conditions permitting the formation of an organic ester or amine-bridged polymer and separating the derivatized polymer from the organic solvent solution of the free organic acid.

摘要翻译： 制备通过连接桥连接有有机残基的聚合物的一锅法包括形成有机溶剂或有机酸的悬浮液，从其中蒸出水 - 有机溶剂的共沸溶液，形成有机溶剂溶液或悬浮液 将有机酸的相应酸酐混合到相应的酸酐的有机溶剂溶液或悬浮液中，所述聚合物包含能够与有机酸衍生化聚合物的-COOH残基反应的侧链部分，所述有机酸衍生化聚合物具有至少一个所附有机酸侧基残基 通过由酸的-COOH残基和聚合物的侧链反应性残基反应产生的桥和在允许形成有机酯或胺桥接的聚合物的条件下的游离有机酸，并将衍生的聚合物与 游离有机酸的有机溶剂溶液。

公开(公告)号：US4461646A

公开(公告)日：1984-07-24

申请号：US487338

申请日：1983-04-21

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： D21H17/62 ,  D21H17/66 ,  C08L93/04 ,  C09F1/04

CPC分类号： D21H17/66 ,  D21H17/62

摘要： A series of inorganic salts are disclosed for their efficacy in lowering surfactant requirements and foam in aqueous dispersed rosin size. The salts are best employed as additives to the surfactant prior to addition of surfactant to molten rosin during preparation of the aqueous dispersion. Selected chlorides, fluorides, nitrates and sulfates of aluminum, calcium, cobalt, lead, magnesium, sodium and tin are disclosed as being effective within a range of about 0.01% to 0.1% by weight of rosin at a surfactant level of about 3.5%. Aluminum nitrate at a level of 0.04 to 0.055% by weight of the rosin, at a surfactant level of 3.5%, is preferred.

摘要翻译： 公开了一系列无机盐，用于降低表面活性剂需求和泡沫水分散松香的功效。 在制备水性分散体期间，在将表面活性剂加入熔融松香之前，最好将盐用作表面活性剂的添加剂。 公开了铝，钙，钴，铅，镁，钠和锡的选定的氯化物，氟化物，硝酸盐和硫酸盐在约3.5％的表面活性剂水平下在约0.01％至0.1％重量的松香的范围内有效。 在表面活性剂含量为3.5％的情况下，以0.04〜0.055重量％的松香为水平的硝酸铝为佳。

公开(公告)号：US4878999A

公开(公告)日：1989-11-07

申请号：US246589

申请日：1988-09-19

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： D21H17/29 ,  D21H17/44 ,  D21H17/58

CPC分类号： D21H17/58 ,  D21H17/29 ,  D21H17/44

摘要： A process is disclosed for sizing cellulose fibers with rosin-base materials in the substantial absence of alum, which can be performed at a neutural pH. According to the process, a saponified fortified rosin is added to the cellulose fibers in the presence of a cationic starch and a cationic polymer of at least medium weight and medium charge.

摘要翻译： 公开了在基本上不存在明矾的情况下对具有松香基材料的纤维素纤维进行定径的方法，其可以在中性pH下进行。 根据该方法，在阳离子淀粉和至少中等重量和中等电荷的阳离子聚合物存在下，将纤维素纤维中加入皂化强化松香。

公开(公告)号：US4517347A

公开(公告)日：1985-05-14

申请号：US634223

申请日：1984-07-25

申请人： John W. Gowan, Jr. ,  Carlton G. Force

发明人： John W. Gowan, Jr. ,  Carlton G. Force

IPC分类号： C08F212/10

CPC分类号： C08F212/10

摘要： In the emulsion copolymerization of styrene and acrylonitrile, the copolymer yield can be increased by adding certain antioxidant compounds to the emulsifier. These antioxidant compounds include an aromatic portion and a fatty acid portion, and may be, for example, a hydroquinone-fatty acid ester.

摘要翻译： 在苯乙烯和丙烯腈的乳液共聚中，通过向乳化剂中加入某些抗氧化剂化合物可以提高共聚物产率。 这些抗氧化化合物包括芳族部分和脂肪酸部分，并且可以是例如氢醌 - 脂肪酸酯。

公开(公告)号：US4505754A

公开(公告)日：1985-03-19

申请号：US533432

申请日：1983-09-19

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： B01F17/10 ,  D21H17/62 ,  C08L93/04

CPC分类号： D21H17/62

摘要： A sulfonated dicarboxylic acid is disclosed as a cosurfactant for its efficacy in lowering foam in alum-containing aqueous dispersed rosin size, and particularly in calcium-containing dispersed rosin size systems. The sulfonated dicarboxylic acid additive also enhances alum sensitivity of the dispersed rosin size. The addition of dioctyl sodium sulfosuccinate, DSS, cosurfactant to a salt of sulfuric acid half ester surfactant-containing dispersed rosin size lowers the tendency for foaming and increases the sensitivity of the size to alum with an attendant increase in sizing efficiency.

摘要翻译： 公开了磺化二羧酸作为辅助表面活性剂，用于其降低含有明矾水分散松香尺寸的泡沫的功效，特别是在含钙分散的松香体系中。 磺化二羧酸添加剂还提高了分散松香尺寸的明矾敏感性。 将磺基琥珀酸二辛基钠，DSS，助表面活性剂加入到含硫酸半酯表面活性剂的分散松香粒度的盐中，降低发泡的倾向，并增加尺寸对明矾的敏感性，随着施胶效率的提高。

公开(公告)号：US4963625A

公开(公告)日：1990-10-16

申请号：US401624

申请日：1989-08-31

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： C08F8/30

CPC分类号： C08F8/30

摘要： A polyacrylamide of high brightness and retention characteristics and low biological toxicity comprises a polyacrylic acid having covalently bound thereto at least one residue of a compound of the formula ##STR1## wherein R.sup.1 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl, (C.sub.2 -C.sub.6)alkynyl or (C.sub.1 -C.sub.6)alkoxyl;R.sup.2 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl, (C.sub.2 -C.sub.6)alkynyl or (C.sub.1 -C.sub.6)alkoxyl; andR.sup.3 is H or NR.sub.n' wherein n is 2 or 3; wherein if n=3 the compound further comprises X.sup.-, wherein X.sup.- is an anion.A paper whitening composition comprises a whitening amount of the above amide polymer.A cellulosic product of high brightness and retention characteristics and low biological toxicity comprising the polyacrylamide of this invention. A food product is packaged with the above cellulosic product.A method of increasing the fluorescent brightness and retention characteristics while lowering the biological toxicity of the fluorescent compound shown above comprises covalently binding at least one residue of the fluorescent compound to a polymer resulting in a polyacrylamide. A method of increasing the brightness and retention characteristics of a cellulosic product while preserving its low biological toxicity comprises covalently binding to a polyacrylic acid polymer at least one residue of the above compound to form a polyacrylamide, and adding a whitening amount of the amide polymer to cellulosic ingredients to form a whitened product. A method of increasing the whiteness of a cellulosic product and its retention characteristics while preserving its low biological toxicity comprises coating the cellulosic product with a whitening amount of a polyacrylamide having bound thereto at least one residue of the above fluorescent compound.

摘要翻译： 具有高亮度和保留特性和低生物毒性的聚丙烯酰胺包括共价结合至少一个下式化合物的残基的聚丙烯酸：其中R 1是H，（C 1 -C 6）烷基，（C 2 -C 6） 烯基，（C 2 -C 6）炔基或（C 1 -C 6）烷氧基; R2是H，（C1-C6）烷基，（C2-C6）烯基，（C2-C6）炔基或（C1-C6）烷氧基; 且R 3为H或NR n'，其中n为2或3; 其中如果n = 3，该化合物还包含X - ，其中X是阴离子。 一种造纸美白组合物包含增白量的上述酰胺聚合物。 包含本发明的聚丙烯酰胺的高亮度和保留特性以及低生物毒性的纤维素产品。 食品与上述纤维素产品一起包装。 提高荧光亮度和保留特性同时降低上述荧光化合物的生物毒性的方法包括将至少一种荧光化合物的残基与聚合物共价结合，得到聚丙烯酰胺。 提高纤维素产品的亮度和保留特性同时保持其低生物毒性的方法包括与聚丙烯酸聚合物共价结合上述化合物的至少一个残基以形成聚丙烯酰胺，并将增白量的酰胺聚合物加入到 纤维素成分以形成增白产品。 提高纤维素产品白度的方法及其保留特性同时保持其低生物毒性的方法包括用增白量的聚丙烯酰胺涂覆纤维素产品，所述聚丙烯酰胺与上述荧光化合物的至少一个残基结合。

公开(公告)号：US5141672A

公开(公告)日：1992-08-25

申请号：US462231

申请日：1990-01-09

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： C07C229/56 ,  C09K11/06

CPC分类号： C07C229/56 ,  C09K11/06

摘要： A cationic group-carrying fluorescent compound of the formula ##STR1## wherein R is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl, (C.sub.2 -C.sub.6)-alkynyl or (C.sub.2 -C.sub.6)alkoxyl;R' is (C.sub.1 -C.sub.16)alkylamine, (C.sub.2 -C.sub.16)alkenylamine, (C.sub.2 -C.sub.16)alkynylamine or (C.sub.1 -C.sub.16) quaternary ammonium salts thereof, which may further comprise O, N, S or halogen;R" is H or --NH--(R').sup.+ X.sup.- ; andX.sup.- is an anion.A fluorescent agent comprises the above compound and a whitening composition comprises a whitening amount of the compound and a filler or binder.

摘要翻译： 其中R是H，（C 1 -C 6）烷基，（C 2 -C 6）烯基，（C 2 -C 6） - 炔基或（C 2 -C 6）烷氧基的具有下式的阳离子基团荧光化合物： R'是可以进一步包含O，N，S或卤素的（C1-C16）烷基胺，（C2-C16）链烯基胺，（C2-C16）炔基胺或（C1-C16） R“是H或-NH-（R'）+ X-; 而X-是阴离子。 荧光剂包括上述化合物，增白组合物包含增白剂量的化合物和填料或粘合剂。

公开(公告)号：US5043370A

公开(公告)日：1991-08-27

申请号：US401427

申请日：1989-08-31

申请人： John W. Gowan, Jr.

发明人： John W. Gowan, Jr.

IPC分类号： C08G73/02 ,  D21H17/55 ,  D21H21/10 ,  D21H21/32

CPC分类号： C08G73/0206 ,  D21H17/55 ,  D21H21/10 ,  D21H21/32 ,  Y10T428/31721

摘要： A polyalkylene imide of high brightness and retention characteristics and low biological toxicity comprises a polyalkylene imine having covalently bound thereto at least one residue of a compound of the formula ##STR1## wherein R.sup.1 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6) alkenyl, (C.sub.2 -C.sub.6)alkynyl or (C.sub.1 -C.sub.6)alkoxyl;R.sup.2 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl, (C.sub.2 -C.sub.6)alkynyl or (C.sub.1 -C.sub.6)alkoxyl; andR.sup.3 is H or NR.sub.n, wherein n is 2 or 3; wherein if n=3 the compound further comprises X.sup.-, wherein X.sup.- is an anion. A paper whitening composition and method for whitening cellulosic products comprising a whitening amount of the above imide polymer.

摘要翻译： 具有高亮度和保留特性以及低生物毒性的聚亚烷基酰亚胺包括共价键合至少一个下式化合物的残基的聚亚烷基亚胺，其中R 1是H，（C 1 -C 6）烷基，（C 2 -C 6） ）烯基，（C 2 -C 6）炔基或（C 1 -C 6）烷氧基; R2是H，（C1-C6）烷基，（C2-C6）烯基，（C2-C6）炔基或（C1-C6）烷氧基; 并且R 3是H或NR n，其中n是2或3; 其中如果n = 3，该化合物还包含X - ，其中X是阴离子。 一种美白组合物和增白纤维素产品的方法，包括增白量的上述酰亚胺聚合物。

公开(公告)号：US4544726A

公开(公告)日：1985-10-01

申请号：US657233

申请日：1984-10-03

申请人： John A. Alford ,  Carlton G. Force ,  John W. Gowan, Jr.

发明人： John A. Alford ,  Carlton G. Force ,  John W. Gowan, Jr.

IPC分类号： C08F2/00 ,  B01F17/36 ,  C07C69/54 ,  C08F2/24 ,  C08F2/26 ,  C08F2/30 ,  C08F212/00 ,  C08F212/08 ,  C08F236/00 ,  C08F236/06 ,  C08F236/10 ,  C08F36/00

CPC分类号： C08F2/30

摘要： Disclosed as an emulsion polymerization emulsifier is a half vinyl ester of C.sub.21 -dicarboxylic acid of the general formula ##STR1## wherein x and y are integers from 3 to 9, x and y together equal 12, one Z is COOH and the other Z is hydrogen. The emulsifier may be blended as a mixture with disproportionated fatty acids and/or C.sub.21 -dicarboxylic acid.

摘要翻译： 作为乳液聚合乳化剂公开的是通式为“IMAGE”的C21-二羧酸的半乙烯基酯，其中x和y为3至9的整数，x和y一起等于12，一个Z为COOH，另一个Z为 氢。 乳化剂可以与歧化脂肪酸和/或C21-二羧酸的混合物共混。