公开(公告)号：US20130338324A1

公开(公告)日：2013-12-19

申请号：US13903546

申请日：2013-05-28

申请人： Christine Beierlein ,  Niko Haberkorn ,  Michael Korell ,  Thomas Gruenfelder ,  Norbert Richter ,  Michael Oldenkott ,  Juergen Pospiech ,  Martin Haneke ,  Andreas Berlineanu ,  Peter Denkinger ,  Juergen Hellwig

发明人： Christine Beierlein ,  Niko Haberkorn ,  Michael Korell ,  Thomas Gruenfelder ,  Norbert Richter ,  Michael Oldenkott ,  Juergen Pospiech ,  Martin Haneke ,  Andreas Berlineanu ,  Peter Denkinger ,  Juergen Hellwig

IPC分类号： C08F2/06

CPC分类号： C08F2/06 ,  C08C1/075 ,  C08F6/003 ,  C08F36/06 ,  C08F36/08 ,  C08L47/00

摘要： A process for polymerization of a diene is provided. The process comprises: a) reacting the diene with hydrogen peroxide in a hydrophilic organic solvent in the presence of water to obtain a polymerization reaction mixture; b) contacting the polymerization reaction mixture with water having a temperature of from 20 to 80° C. to form a mixture having an organic phase and an aqueous phase; c) removing unreacted gaseous diene from the water mixture obtained in b); d) separating the aqueous phase comprising the hydrophilic solvent from the organic phase of the water mixture; and e) distilling volatile materials from the separated organic phase from d) to obtain the polymerization product; wherein a temperature of the reaction a) is from 50-150° C., a pressure of the reaction a) is from 0 to 50 bar, the unreacted gaseous diene removed in c) is condensed, distilled and the distillate obtained reacted according to a), and the hydrophilic solvent is recovered from the separated aqueous phase and reused according to a). Also provided is an apparatus for conducting the process of the invention.

摘要翻译： 提供二烯聚合方法。 该方法包括：a）在水存在下使二烯与过氧化氢在亲水性有机溶剂中反应，得到聚合反应混合物; b）使聚合反应混合物与温度为20至80℃的水接触以形成具有有机相和水相的混合物; c）从b）中得到的水混合物中除去未反应的气态二烯; d）将包含亲水溶剂的水相与水混合物的有机相分离; 和e）从分离的有机相中蒸馏挥发性物质，从d）得到聚合产物; 其中反应a）的温度为50-150℃，反应a）的压力为0至50巴，将在c）中除去的未反应的气体二烯冷凝，蒸馏，得到的馏出物根据 a），并且从分离的水相中回收亲水性溶剂，并根据a）重复使用。 还提供了用于进行本发明的方法的装置。