PURIFICATION METHOD FOR FLUOROOLEFIN HAVING STRUCTURE OF =CF2 OR =CHF, HIGH-PURITY FLUOROOLEFIN, AND PRODUCTION METHOD THEREFOR

    公开(公告)号:US20220281785A1

    公开(公告)日:2022-09-08

    申请号:US17641262

    申请日:2020-09-11

    IPC分类号: C07C17/389

    摘要: Impurities are removed from a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains haloalkene, haloalkane, and/or haloalkyne impurities.
    Provided are: a method of purifying a fluoroolefin having a structure of ═CF2 or ═CHF, comprising bringing a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains at least one of haloalkane, haloalkene, and/or haloalkyne impurities into contact with a solid adsorbent to remove the impurities through adsorption; a high-purity fluoroolefin; and a production method therefor.

    METHOD OF PRODUCING COMPOUND HAVING BUTADIENE SKELETON CONTAINING HYDROGEN AND FLUORINE AND/OR CHLORINE

    公开(公告)号:US20210061735A1

    公开(公告)日:2021-03-04

    申请号:US16959317

    申请日:2019-02-01

    IPC分类号: C07C17/275

    摘要: An object of the present invention is to provide a simple, low-cost, and industrial method of producing a compound having a polyene skeleton containing hydrogen and fluorine and/or chlorine.
    A method of producing a halogenated diene represented by formula (1): A1A2C═CA3-CA4═CA5A6[A1, A2, A5, and A6 are each independently hydrogen, fluorine, chlorine, a (perfluoro)alkyl group having 1 to 3 carbon atoms, or a (perfluoro)alkenyl group; A3 and A4 are each independently hydrogen, fluorine, or chlorine; at least one of A1 to A6 is hydrogen; at least one of A1 to A6 is fluorine or chlorine] comprises a step of subjecting the same or different halogenated olefin(s) represented by formula (2): A7A8C═CA9X[A7 and A8 are each independently hydrogen, fluorine, chlorine, a (perfluoro)alkyl group having 1 to 3 carbon atoms, or a (perfluoro)alkenyl group; A9 is each independently hydrogen, fluorine, or chlorine; X is bromine or iodine] to a coupling reaction in the presence of a zero-valent metal and a metal salt.

    METHOD FOR PRODUCING DIFLUOROPHOSPATE

    公开(公告)号:US20170197834A1

    公开(公告)日:2017-07-13

    申请号:US15316744

    申请日:2015-07-08

    IPC分类号: C01B25/455

    摘要: The purpose of the present invention is to provide a method for easily producing a difluorophosphate using only low-cost starting materials without requiring cumbersome operations. According to the present invention, at least one salt selected from the group consisting of halides, carbonates, borates, phosphates, hydroxides and oxides of an alkali metal, an alkaline earth metal or an onium, at least one phosphorus compound selected from the group consisting of oxychlorides and chlorides of phosphorus, water and hydrogen fluoride are reacted. The above-mentioned purpose is achieved preferably using, as hydrogen fluoride, one substance selected from the group consisting of hydrogen fluoride anhydride, a mixed solution of hydrogen fluoride anhydride and an organic solvent and a mixed gas of hydrogen fluoride anhydride and an inert gas, as a salt used in the reaction, at least one substance selected from the group consisting of halides and carbonates of an alkali metal, and as a phosphorus compound, phosphoryl chloride.