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公开(公告)号:US20220411949A1
公开(公告)日:2022-12-29
申请号:US17823548
申请日:2022-08-31
发明人: Kimitaka OKUBO
IPC分类号: C25D3/12 , C25B11/042 , C01B21/083 , C25B1/245
摘要: An electrode for electrolytic fluorination contains nickel as a base material with a fluorine content 99 mass %, the iron content≤400 ppm, the copper content
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公开(公告)号:US11532838B2
公开(公告)日:2022-12-20
申请号:US16652458
申请日:2018-10-30
发明人: Toshiaki Okamoto
IPC分类号: H01M10/0567 , H01M10/0525 , H01M10/0569
摘要: Disclosed is a nonaqueous electrolyte solution containing a lithium electrolyte, methyl 3,3,3-trifluoropropionate, and a phosphazene compound. Preferably, the phosphazene compound is a cyclic phosphazene compound represented by the disclosed general formula (I).
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公开(公告)号:US20220281785A1
公开(公告)日:2022-09-08
申请号:US17641262
申请日:2020-09-11
发明人: Yuka MATSUTA , Korehito KATO
IPC分类号: C07C17/389
摘要: Impurities are removed from a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains haloalkene, haloalkane, and/or haloalkyne impurities.
Provided are: a method of purifying a fluoroolefin having a structure of ═CF2 or ═CHF, comprising bringing a fluoroolefin having a structure of ═CF2 or ═CHF that has been obtained by a dehydrohalogenation reaction and that contains at least one of haloalkane, haloalkene, and/or haloalkyne impurities into contact with a solid adsorbent to remove the impurities through adsorption; a high-purity fluoroolefin; and a production method therefor.-
公开(公告)号:US20210061735A1
公开(公告)日:2021-03-04
申请号:US16959317
申请日:2019-02-01
IPC分类号: C07C17/275
摘要: An object of the present invention is to provide a simple, low-cost, and industrial method of producing a compound having a polyene skeleton containing hydrogen and fluorine and/or chlorine.
A method of producing a halogenated diene represented by formula (1): A1A2C═CA3-CA4═CA5A6[A1, A2, A5, and A6 are each independently hydrogen, fluorine, chlorine, a (perfluoro)alkyl group having 1 to 3 carbon atoms, or a (perfluoro)alkenyl group; A3 and A4 are each independently hydrogen, fluorine, or chlorine; at least one of A1 to A6 is hydrogen; at least one of A1 to A6 is fluorine or chlorine] comprises a step of subjecting the same or different halogenated olefin(s) represented by formula (2): A7A8C═CA9X[A7 and A8 are each independently hydrogen, fluorine, chlorine, a (perfluoro)alkyl group having 1 to 3 carbon atoms, or a (perfluoro)alkenyl group; A9 is each independently hydrogen, fluorine, or chlorine; X is bromine or iodine] to a coupling reaction in the presence of a zero-valent metal and a metal salt.-
公开(公告)号:US20200235432A1
公开(公告)日:2020-07-23
申请号:US16652458
申请日:2018-10-30
发明人: Toshiaki OKAMOTO
IPC分类号: H01M10/0567 , H01M10/0569 , H01M10/0525
摘要: Disclosed is a nonaqueous electrolyte solution containing a lithium electrolyte, methyl 3,3,3-trifluoropropionate, and a phosphazene compound. Preferably, the phosphazene compound is a cyclic phosphazene compound represented by the disclosed general formula (I).
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公开(公告)号:US10392325B2
公开(公告)日:2019-08-27
申请号:US15561456
申请日:2016-03-29
发明人: Kazuki Kurihara , Tatsuya Sugimoto
摘要: The present invention provides: a method for producing a fluorinated alkane represented by the formula (2): R2—F, wherein an alcohol having 3 to 5 carbon atoms is fluorinated by a fluorinating agent represented by the formula (1): R1SO2F in the absence of a solvent, and in the presence of an amidine base. In the formula, R1 represents a methyl group, an ethyl group or an aromatic group, R2 represents an alkyl group having 3 to 5 carbon atoms, and n is 0 or 2.
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公开(公告)号:US20180118570A1
公开(公告)日:2018-05-03
申请号:US15562223
申请日:2016-04-26
发明人: Hiroki TAKIZAWA , Kazuhide YOSHIYAMA , Keisuke KUDE , Wataru KASHIKURA , Takuro ABE , Mitsuhara SHIMODA , Osamu OMAE , Hiroyuki UEHARA
IPC分类号: C01B25/455 , H01M10/0525 , H01M10/0567
摘要: Disclosed is a method for purifying a difluorophosphate, the method including mixing a difluorophosphate containing an impurity with at least one treatment agent selected from the group consisting of carbonates, hydroxides, and halides of alkali metals or alkali earth metals and amines to isolate the impurity. It is preferable that the method further include filtering off, by filtration, a salt or a complex that has been formed by allowing the impurity to be mixed with the treatment agent. Preferably, a carbonate, a hydroxide, or a halide of an alkali metal is used as the treatment agent, and more preferably a carbonate, a hydroxide, or a halide of lithium is used as the treatment agent.
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公开(公告)号:US20170197834A1
公开(公告)日:2017-07-13
申请号:US15316744
申请日:2015-07-08
发明人: Takuro ABE , Hiroki TAKIZAWA , Teppei OTA
IPC分类号: C01B25/455
CPC分类号: C01B25/455 , C01B25/10 , H01M10/0525 , H01M10/0567 , H01M2300/0025
摘要: The purpose of the present invention is to provide a method for easily producing a difluorophosphate using only low-cost starting materials without requiring cumbersome operations. According to the present invention, at least one salt selected from the group consisting of halides, carbonates, borates, phosphates, hydroxides and oxides of an alkali metal, an alkaline earth metal or an onium, at least one phosphorus compound selected from the group consisting of oxychlorides and chlorides of phosphorus, water and hydrogen fluoride are reacted. The above-mentioned purpose is achieved preferably using, as hydrogen fluoride, one substance selected from the group consisting of hydrogen fluoride anhydride, a mixed solution of hydrogen fluoride anhydride and an organic solvent and a mixed gas of hydrogen fluoride anhydride and an inert gas, as a salt used in the reaction, at least one substance selected from the group consisting of halides and carbonates of an alkali metal, and as a phosphorus compound, phosphoryl chloride.
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公开(公告)号:US20170162909A1
公开(公告)日:2017-06-08
申请号:US15324044
申请日:2015-05-12
发明人: Osamu OMAE , Toshiaki OKAMOTO
IPC分类号: H01M10/0569 , H01M10/0525
CPC分类号: H01M10/0569 , H01M10/052 , H01M10/0525 , H01M10/0567 , H01M2300/0028 , H01M2300/004
摘要: Provided are, a nonaqueous electrolytic solution for secondary batteries that has excellent oxidation resistance, prevents reaction between itself and electrodes, is resistant to decomposition under high-voltage conditions, and is capable of reducing the capacity decrease of and gas evolution in a secondary battery; and a nonaqueous electrolyte secondary battery using the nonaqueous electrolytic solution. The nonaqueous electrolytic solution for secondary batteries comprises a nonaqueous solvent comprising an ester having 3,3,3-trifluoropropionate groups represented by the following formula 1: (wherein n represents an integer of 1 to 20.) a fluorinated cyclic carbonate that is 4-fluoroethylene carbonate (FEC) or a derivative thereof, and at least one selected from a cyclic carbonate, a chain carbonate, and a fluorinated chain carboxylic acid ester; and a lithium salt as an electrolyte.
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公开(公告)号:US20160158696A1
公开(公告)日:2016-06-09
申请号:US14901548
申请日:2014-05-26
发明人: Katsuhiro SAITO , Shinji MITA , Hiromi OYA , Shinsuke KATAYAMA , Yoshimasa SAKURAI , Shogo MASAUJI , Yuuki KUBOTA , Hidehito FUJISAWA
CPC分类号: B01D53/68 , B01D53/73 , B01D2251/50 , B01D2251/502 , B01D2251/512 , B01D2252/103 , B01D2257/204 , B01D2257/55 , C01B25/18 , C02F1/025 , C02F1/66 , C02F1/70 , C02F2101/14
摘要: A treatment process of PF5 including an absorption step for inducing absorption of PF5 by an acidic solution containing an acid to obtain a solution containing PF5A−, an adjustment step to adjust concentration of HCl in the solution, and a thermolysis step for heating the solution containing PF5A− ions obtained in the absorption step or the adjustment step to decompose the solution to an acidic mixture containing H3PO4 and HF.
摘要翻译: PF5的处理方法,包括吸收步骤,用于通过酸性溶液诱导PF5的吸收,以获得含有PF5A的溶液,调节步骤以调节溶液中HCl的浓度;以及热解步骤,用于加热含有 在吸收步骤或调整步骤中获得的PF5A-离子将溶液分解成含有H 3 PO 4和HF的酸性混合物。
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