公开(公告)号：US09035533B2

公开(公告)日：2015-05-19

申请号：US13825727

申请日：2011-09-21

申请人： Toshinori Kato ,  Katsuei Takahashi ,  Takashi Yamashita

发明人： Toshinori Kato ,  Katsuei Takahashi ,  Takashi Yamashita

IPC分类号： H01G9/025 ,  C09D5/24 ,  C09D7/00 ,  C09D7/12 ,  H02N1/00 ,  H01B1/12 ,  H01B1/22 ,  H01B1/24 ,  C08F8/36 ,  C09J153/02

CPC分类号： H01G9/025 ,  C08F8/36 ,  C09D5/24 ,  C09D7/20 ,  C09D7/69 ,  C09D7/70 ,  C09J153/025 ,  H01B1/122 ,  H01B1/22 ,  H01B1/24 ,  H02N1/00 ,  Y10S310/80

摘要： Paste which is prepared by any solid concentration and is excellent in terms of handleability, applicability, and storage stability; an electrolyte film or electrode film which is an even and highly flexible coating film formed in a desired thickness from the paste through a few repetitions of an application/drying step; and a polymer transducer which can be industrially and economically produced and shows excellent performance. The paste comprises: a solid polyelectrolyte (A) consisting of a block copolymer containing; a polymer block (a-1) which is represented by chemical formula (1) and a polymer block (a-2) which has substantially no ionic group and is rubbery at room temperature; an organic solvent (B) having a boiling point at 150° C. or higher; and non-dissociable particles (C) which are insoluble in the organic solvent (B) and have a major-axis length of 1-100 μm and an aspect ratio of 5 or less. The polymer transducer comprises an electrolyte film and a pair of electrode films between which the electrolyte film is sandwiched, wherein the electrolyte film or the pair of electrode films has been formed by drying and solidifying the paste into a film shape.

摘要翻译： 通过任何固体浓度制备并且在可操作性，适用性和储存稳定性方面优异的浆料; 电解质膜或电极膜，其是通过几次重复的施加/干燥步骤，从浆料形成具有所需厚度的均匀且高度柔性的涂膜; 以及可在工业上和经济地制造并显示出优异性能的聚合物换能器。 该糊状物包括：由嵌段共聚物组成的固体聚电解质（A） 由化学式（1）表示的聚合物嵌段（a-1）和在室温下基本上不具有离子性基团且为橡胶状的聚合物嵌段（a-2） 沸点在150℃以上的有机溶剂（B） 和不溶解的有机溶剂（B）中的长度比为1〜100μm，长径比为5以下的非离解性粒子（C）。 聚合物换能器包括电解质膜和一对电极膜，在该对电极膜之间夹有电解质膜，其中电解质膜或一对电极膜通过干燥并固化成胶片形成。

公开(公告)号：US20130175899A1

公开(公告)日：2013-07-11

申请号：US13825727

申请日：2011-09-21

申请人： Toshinori Kato ,  Katsuei Takahashi ,  Takashi Yamashita

发明人： Toshinori Kato ,  Katsuei Takahashi ,  Takashi Yamashita

IPC分类号： H01G9/025 ,  H02N1/00

CPC分类号： H01G9/025 ,  C08F8/36 ,  C09D5/24 ,  C09D7/20 ,  C09D7/69 ,  C09D7/70 ,  C09J153/025 ,  H01B1/122 ,  H01B1/22 ,  H01B1/24 ,  H02N1/00 ,  Y10S310/80

摘要： Paste which is prepared by any solid concentration and is excellent in terms of handleability, applicability, and storage stability; an electrolyte film or electrode film which is an even and highly flexible coating film formed in a desired thickness from the paste through a few repetitions of an application/drying step; and a polymer transducer which can be industrially and economically produced and shows excellent performance. The paste comprises: a solid polyelectrolyte (A) consisting of a block copolymer containing; a polymer block (a-1) which is represented by chemical formula (1) and a polymer block (a-2) which has substantially no ionic group and is rubbery at room temperature; an organic solvent (B) having a boiling point at 150° C. or higher; and non-dissociable particles (C) which are insoluble in the organic solvent (B) and have a major-axis length of 1-100 μm and an aspect ratio of 5 or less. The polymer transducer comprises an electrolyte film and a pair of electrode films between which the electrolyte film is sandwiched, wherein the electrolyte film or the pair of electrode films has been formed by drying and solidifying the paste into a film shape.

摘要翻译： 通过任何固体浓度制备并且在可操作性，适用性和储存稳定性方面优异的糊状物; 电解质膜或电极膜，其是通过几次重复的施加/干燥步骤，从浆料形成具有所需厚度的均匀且高度柔性的涂膜; 以及可在工业上和经济地制造并显示出优异性能的聚合物换能器。 该糊状物包括：由嵌段共聚物组成的固体聚电解质（A） 由化学式（1）表示的聚合物嵌段（a-1）和在室温下基本上不具有离子性基团且为橡胶状的聚合物嵌段（a-2） 沸点在150℃以上的有机溶剂（B） 和不溶解于有机溶剂（B）中的长轴长为1-100μm，长径比为5以下的非离解性粒子（C）。 聚合物换能器包括电解质膜和一对电极膜，在该对电极膜之间夹有电解质膜，其中电解质膜或一对电极膜通过干燥并固化成胶片形成。

公开(公告)号：US06143826A

公开(公告)日：2000-11-07

申请号：US936599

申请日：1997-09-24

申请人： Takashi Ohnaga ,  Katsunori Takamoto ,  Yukihiro Fujieda ,  Katsuei Takahashi ,  Kenichi Hamada

发明人： Takashi Ohnaga ,  Katsunori Takamoto ,  Yukihiro Fujieda ,  Katsuei Takahashi ,  Kenichi Hamada

IPC分类号： C08L33/10 ,  C08L33/06 ,  C08L53/00 ,  C08L101/00

CPC分类号： C08L53/005 ,  C08L33/06 ,  C08L53/00 ,  C08L101/00

摘要： A polymer blend comprising:(A) an acrylic resin;(B) a block copolymer consisting essentially of a polymer block of a polymerized aromatic vinyl compound and/or a polymer block of a polymerized methacrylate monoester and a polyolefin polymer block; and(C) a polymer miscible with the acrylic resin (A) and immiscible with the block copolymer (B),wherein the absolute value (.vertline..eta..sub.AC -.eta..sub.B .vertline.) of the difference between the refractive index (.eta..sub.AC) of the blend of the acrylic resin (A) and the polymer (C) and the refractive index (.eta..sub.B) of the block copolymer (B) is 0.01 or less. This polymer block has excellent transparency, softness and other properties.

摘要翻译： 一种聚合物共混物，其包含：（A）丙烯酸树脂; （B）主要由聚合的芳族乙烯基化合物的聚合物嵌段和/或聚合的甲基丙烯酸酯单酯和聚烯烃聚合物嵌段的聚合物嵌段组成的嵌段共聚物; 和（C）与丙烯酸树脂（A）可混溶并与嵌段共聚物（B）不混溶的聚合物，其中绝对值（| eta AC- eta B |）的折射率（η） 丙烯酸树脂（A）和聚合物（C）的共混物和嵌段共聚物（B）的折射率（eta B）为0.01以下。 该聚合物嵌段具有优异的透明性，柔软性等特性。