公开(公告)号：US20110281196A1

公开(公告)日：2011-11-17

申请号：US13194241

申请日：2011-07-29

Applicant: Ichiro Terada ,  Seigo Kotera ,  Kazuo Hamazaki ,  Shigeru Aida ,  Ken Iruya

Inventor： Ichiro Terada ,  Seigo Kotera ,  Kazuo Hamazaki ,  Shigeru Aida ,  Ken Iruya

IPC: H01M8/10 ,  B32B5/02 ,  D04H3/00

CPC classification number: B01D39/1623 ,  B01D39/163 ,  B01D2239/0622 ,  D04H1/4318 ,  D04H1/4382 ,  D04H1/54 ,  D04H1/56 ,  D04H3/16 ,  H01M2/162 ,  H01M8/1062 ,  Y10T442/602

Abstract: To obtain a nonwoven fabric which is excellent in the heat resistance and the chemical resistance, of which the fiber diameter is small, and which is excellent in the mechanical strength at a temperature at which it is used; and an electrolyte membrane which is excellent in the dimensional stability when it is swollen by water, and of which an increase in the resistance by a reinforcing material is suppressed.A nonwoven fabric 28 containing fibers 26 of an ethylene/tetrafluoroethylene copolymer having a storage elastic modulus E′ at 25° C. of at least 8×108 Pa and a melt viscosity measured at 300° C. of higher than 60 Pa·s and at most 300 Pa·s, wherein the average fiber diameter of the fibers is from 0.01 to 3 μm; and an electrolyte membrane reinforced by the nonwoven fabric 28.

Abstract translation: 为了得到纤维直径小的耐热性和耐化学性优异的非织造布，其使用温度下的机械强度优异; 以及电解质膜，其由水膨胀时的尺寸稳定性优异，并且抑制了增强材料的电阻的增加。 包含25℃下的储能弹性模量E'至少为8×10 8 Pa，在300℃下测定的熔体粘度高于60Pa·s的乙烯/四氟乙烯共聚物的纤维26的无纺布28和 最多300Pa·s，其中纤维的平均纤维直径为0.01〜3μm; 以及由无纺布28增强的电解质膜。

公开(公告)号：US08394549B2

公开(公告)日：2013-03-12

申请号：US13194241

申请日：2011-07-29

Applicant: Ichiro Terada ,  Seigo Kotera ,  Kazuo Hamazaki ,  Shigeru Aida ,  Ken Iruya

Inventor： Ichiro Terada ,  Seigo Kotera ,  Kazuo Hamazaki ,  Shigeru Aida ,  Ken Iruya

IPC: H01M8/10 ,  B01J49/00 ,  C08J5/20 ,  B28B3/20 ,  B29C47/00

CPC classification number: B01D39/1623 ,  B01D39/163 ,  B01D2239/0622 ,  D04H1/4318 ,  D04H1/4382 ,  D04H1/54 ,  D04H1/56 ,  D04H3/16 ,  H01M2/162 ,  H01M8/1062 ,  Y10T442/602

Abstract: To obtain a nonwoven fabric which is excellent in the heat resistance and the chemical resistance, of which the fiber diameter is small, and which is excellent in the mechanical strength at a temperature at which it is used; and an electrolyte membrane which is excellent in the dimensional stability when it is swollen by water, and of which an increase in the resistance by a reinforcing material is suppressed.A nonwoven fabric 28 containing fibers 26 of an ethylene/tetrafluoroethylene copolymer having a storage elastic modulus E′ at 25° C. of at least 8×108 Pa and a melt viscosity measured at 300° C. of higher than 60 Pa·s and at most 300 Pa·s, wherein the average fiber diameter of the fibers is from 0.01 to 3 μm; and an electrolyte membrane reinforced by the nonwoven fabric 28.

Abstract translation: 为了得到纤维直径小的耐热性和耐化学性优异的非织造布，其使用温度下的机械强度优异; 以及电解质膜，其由水膨胀时的尺寸稳定性优异，并且抑制了增强材料的电阻的增加。 包含25℃下的储能弹性模量E'至少为8×10 8 Pa，在300℃下测定的熔体粘度高于60Pa·s的乙烯/四氟乙烯共聚物的纤维26的无纺布28和 最多300Pa·s，其中纤维的平均纤维直径为0.01〜3μm; 以及由无纺布28增强的电解质膜。

公开(公告)号：US07927690B2

公开(公告)日：2011-04-19

申请号：US12398656

申请日：2009-03-05

Applicant: Daisuke Taguchi ,  Ken Iruya ,  Seigo Kotera

Inventor： Daisuke Taguchi ,  Ken Iruya ,  Seigo Kotera

IPC: B32B7/02 ,  D04H1/00

CPC classification number: D04H1/56 ,  D01D5/0985 ,  D01F6/30 ,  D01F6/32 ,  D04H5/06 ,  D04H13/00 ,  Y10T442/60 ,  Y10T442/609 ,  Y10T442/614 ,  Y10T442/68 ,  Y10T442/69

Abstract: It is an object of the present invention to provide a nonwoven fabric which is excellent in the heat resistance and the chemical resistance, of which the fiber diameter is small, which is excellent in the strength and of which the maximum pore diameter is small.A nonwoven fabric made of an ethylene/tetrafluoroethylene copolymer, characterized in that the nonwoven fabric is mutually fused continuous fibers of an ethylene/tetrafluoroethylene copolymer which has a melt viscosity of from higher than 100 to 1,500 Pa·s at 240° C.

Abstract translation: 本发明的目的是提供一种纤维直径小的耐热性和耐化学性优异的非织造布，其强度优异，最大孔径小。 由乙烯/四氟乙烯共聚物制成的无纺布，其特征在于，无纺布是在240℃下熔融粘度高于100〜1500Pa·s的乙烯/四氟乙烯共聚物的相互熔融的连续纤维。

公开(公告)号：US20090226690A1

公开(公告)日：2009-09-10

申请号：US12398656

申请日：2009-03-05

Applicant: Daisuke Taguchi ,  Ken Iruya ,  Seigo Kotera

Inventor： Daisuke Taguchi ,  Ken Iruya ,  Seigo Kotera

IPC: D04H5/06 ,  D04H13/00 ,  D04H1/56

CPC classification number: D04H1/56 ,  D01D5/0985 ,  D01F6/30 ,  D01F6/32 ,  D04H5/06 ,  D04H13/00 ,  Y10T442/60 ,  Y10T442/609 ,  Y10T442/614 ,  Y10T442/68 ,  Y10T442/69

Abstract: It is an object of the present invention to provide a nonwoven fabric which is excellent in the heat resistance and the chemical resistance, of which the fiber diameter is small, which is excellent in the strength and of which the maximum pore diameter is small.A nonwoven fabric made of an ethylene/tetrafluoroethylene copolymer, characterized in that the nonwoven fabric is mutually fused continuous fibers of an ethylene/tetrafluoroethylene copolymer which has a melt viscosity of from higher than 100 to 1,500 Pa˜s at 240° C.

Abstract translation: 本发明的目的是提供一种纤维直径小的耐热性和耐化学性优异的非织造布，其强度优异，最大孔径小。 由乙烯/四氟乙烯共聚物制成的无纺布，其特征在于，无纺布是在240℃下熔融粘度高于100〜1500Pa·s的乙烯/四氟乙烯共聚物的相互熔融的连续纤维。

公开(公告)号：US20120232207A1

公开(公告)日：2012-09-13

申请号：US13477125

申请日：2012-05-22

Applicant: Ken IRUYA ,  Takashi Sato

Inventor： Ken IRUYA ,  Takashi Sato

IPC: C08L27/18 ,  C08K3/34 ,  B82Y40/00

CPC classification number: C08F214/18 ,  B82Y30/00 ,  C08J5/005 ,  C08J2327/18 ,  C08K3/346 ,  C08K5/0008 ,  C08K5/315 ,  C08L27/18

Abstract: To provide a process for producing a fluorinated copolymer nanocomposite comprising a fluorinated copolymer and inorganic fine particles dispersed therein to a high degree, and a process for producing a molded fluororesin product. The process for producing a fluorinated copolymer nanocomposite comprising a fluorinated copolymer and inorganic fine particles, characterized in that a mixture (A) containing a fluorinated copolymer comprised of repeating units based on tetrafluoroethylene and repeating units based on ethylene, inorganic fine particles, and a solvent which can dissolve the fluorinated copolymer under ordinary or elevated pressure at a temperature of not higher than the melting point of the fluorinated copolymer, is heated to at least a temperature at which the fluorinated copolymer dissolves in the solvent, and the solvent is subsequently removed. The process for producing a molded fluororesin product by using the fluorinated copolymer nanocomposite to produce a molded product.

Abstract translation: 提供一种制备含氟共聚物和高分散于其中的无机细颗粒的氟化共聚物纳米复合材料的方法，以及制备模塑氟树脂产品的方法。 包含含氟共聚物和无机细颗粒的含氟共聚物纳米复合材料的制备方法，其特征在于，含有由四氟乙烯重复单元和基于乙烯的重复单元，无机细颗粒和溶剂组成的含氟共聚物的混合物（A） 可以在不高于氟化共聚物的熔点的温度下在常压或高压下溶解氟化共聚物，加热到氟化共聚物溶解在溶剂中的至少一个温度，随后除去溶剂。 通过使用含氟共聚物纳米复合材料来制造模制的氟树脂产品以制备模塑产品的方法。

公开(公告)号：US20110178193A1

公开(公告)日：2011-07-21

申请号：US13071720

申请日：2011-03-25

Applicant: Ken IRUYA ,  Takashi Nakano ,  Tomoyuki Fujita ,  Yoshitomi Morizawa

Inventor： Ken IRUYA ,  Takashi Nakano ,  Tomoyuki Fujita ,  Yoshitomi Morizawa

IPC: C08J9/00 ,  C08F214/26

CPC classification number: C08J9/28 ,  B01D67/0011 ,  B01D67/002 ,  B01D69/087 ,  B01D71/26 ,  B01D71/32 ,  B01D71/36 ,  B01D71/76 ,  B01D2323/08 ,  B01D2323/22 ,  B01D2325/22 ,  B01D2325/30 ,  C08J2201/052 ,  C08J2201/0544 ,  C08J2323/08 ,  C08J2327/18 ,  C08L23/0892 ,  C08L23/28

Abstract: To provide a method for easily producing an ethylene/tetrafluoroethylene copolymer porous material having excellent chemical resistance and filtration performance and has a high heat resistance, within a wide range of the porosity, and an ethylene/tetrafluoroethylene copolymer porous material obtained by such a process.A process for producing an ethylene/tetrafluoroethylene copolymer porous material which comprises a step of dissolving an ethylene/tetrafluoroethylene copolymer having repeating units based on ethylene and repeating units based on tetrafluoroethylene at a temperature of at most 300° C. in a solvent which can dissolve the ethylene/tetrafluoroethylene copolymer at a temperature of at most 300° C., to achieve a predetermined concentration to obtain a solution, a step of forming the solution to obtain a formed product, and a step of cooling the formed product to a temperature of at most the phase separation temperature of the solution to solidify the ethylene/tetrafluoroethylene copolymer.

Abstract translation: 为了提供容易制造具有优异的耐化学性和过滤性能并具有高孔隙率的高耐热性的乙烯/四氟乙烯共聚物多孔材料的方法，以及通过这种方法获得的乙烯/四氟乙烯共聚物多孔材料。 一种乙烯/四氟乙烯共聚物多孔材料的制造方法，其特征在于，在可溶解的溶剂中，溶解乙烯/四氟乙烯共聚物，该乙烯/四氟乙烯共聚物具有基于乙烯的重复单元和基于四氟乙烯的重复单元，在最多300℃的温度下， 乙烯/四氟乙烯共聚物，在至多300℃的温度下，达到预定浓度以获得溶液，形成溶液以获得成形产物的步骤，以及将形成的产物冷却至 最多使溶液的相分离温度固化乙烯/四氟乙烯共聚物。