公开(公告)号：US4720403A

公开(公告)日：1988-01-19

申请号：US894293

申请日：1986-08-07

申请人： Kenneth E. Jasenof ,  Ronald J. Lewarchik ,  John Smyrniotis

发明人： Kenneth E. Jasenof ,  Ronald J. Lewarchik ,  John Smyrniotis

IPC分类号： B05D7/14 ,  C08G59/14 ,  C09D163/00 ,  C08K3/10

CPC分类号： B05D7/14 ,  C08G59/1422 ,  C09D163/00

摘要： A primer coating system is disclosed that is resistant to abrasion and corrosion and includes a basecoat or first layer comprising a resinous polyepoxide, an aminoplast, phenoplast or blocked isocyanate curing agent, an epoxy-phosphate, a chromium-containing pigment and a clay that has the capacity to fix phosphate. The system may further include an overcoat or second layer comprising a resinous polyhydric alcohol, a polyisocyanate, a chromium-containing pigment and the foregoing clay, and a third layer of a finish coating preferably based on a fluorine-containing polymer.

摘要翻译： 公开了一种耐磨损和腐蚀的底漆涂料体系，包括底涂层或第一层，其包含树脂状聚环氧化物，氨基塑料，酚醛树脂或封端异氰酸酯固化剂，环氧磷酸盐，含铬颜料和粘土， 解决磷酸盐的能力。 该系统可以进一步包括包含树脂多元醇，多异氰酸酯，含铬颜料和上述粘土的外涂层或第二层，以及优选基于含氟聚合物的第三层涂层涂层。

公开(公告)号：US5516549A

公开(公告)日：1996-05-14

申请号：US332283

申请日：1994-10-31

申请人： Kenneth E. Jasenof ,  Ronald J. Lewarchik ,  Douglas A. Stumpfl ,  David K. Black

发明人： Kenneth E. Jasenof ,  Ronald J. Lewarchik ,  Douglas A. Stumpfl ,  David K. Black

IPC分类号： B05D1/28 ,  B05D5/06 ,  B05D7/14 ,  B21C47/26 ,  C08G18/40 ,  C08G18/42 ,  C09D167/00 ,  C09D175/06 ,  B05D3/12 ,  B21C47/00

CPC分类号： C09D167/00 ,  B05D1/28 ,  B05D5/061 ,  B05D7/14 ,  B21C47/26 ,  C08G18/4045 ,  C08G18/4202 ,  C09D175/06 ,  Y10T428/24355 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31786

摘要： A polyester-based coating composition capable of forming a striated pattern on a metal surface at a film thickness less than half of that of PVC plastisol films is provided by a thixotropic composition having a thix index of from about 1.5 to about 3 and comprising a hydroxy-functional polyester, a thixotropy-inducing rheologic agent and curing agent. The striated coating is applied to sheet metal in a coil coating operation by introducing the composition into a paint pan of a coil coater, transferring said composition from said paint pan to an applicator roll by rotating a pick-up roll in contact with the composition and with said applicator roll; continuously withdrawing a sheet of metal from a coil thereof and coating said sheet by contacting it with the applicator roll; curing the coating on said sheet by passing the sheet through an oven at an elevated temperature; and continuously rewinding said sheet into a coil.

摘要翻译： 能够以薄膜厚度小于PVC增塑溶胶膜的一半的方式在金属表面上形成条纹图案的聚酯基涂料组合物由具有约1.5至约3的thix指数的触变组合物提供，并且包含羟基 功能性聚酯，触变性流变剂和固化剂。 通过将组合物引入线圈涂布机的油漆盘中将条纹涂层施加到金属板上，通过旋转与组合物接触的拾取辊将所述组合物从所述油漆盘转移到涂布辊，并且 与所述涂布辊; 从其线圈连续地取出金属片，并通过与涂布辊接触来涂覆所述片; 通过使片材在高温下通过烘箱来固化所述片材上的涂层; 并将所述片材连续地卷绕成线圈。

公开(公告)号：US4835018A

公开(公告)日：1989-05-30

申请号：US193687

申请日：1988-05-13

申请人： Clark A. Higginbotham ,  Kenneth E. Jasenof ,  John Smyrniotis

发明人： Clark A. Higginbotham ,  Kenneth E. Jasenof ,  John Smyrniotis

IPC分类号： B05D7/14 ,  B05D5/08 ,  B05D7/00 ,  B05D7/24 ,  C08G18/10 ,  C08G18/58 ,  C08G59/14 ,  C08G59/40 ,  C09D163/00 ,  C09D175/00 ,  C09D175/04

CPC分类号： B05D7/546 ,  B05D5/083 ,  C08G18/10 ,  C08G18/587 ,  C09D175/04 ,  C08G2150/90

摘要： Pigmented, abrasion and corrosion resistant, thermosetting organic solvent solution coating composition comprise: (A) from about 50 percent to about 85 percent of total resin solids of a triol-based blocked polyurethane polyisocyanate having a number average molecular weight in the range of 600 to 4000; (B) from about 15 percent to about 50 percent of total resin solids of an epoxy-phosphate provided by reacting a resinous polyepoxide with at least 0.05 mole of orthophosphoric acid per equivalent of oxirane in the polyepoxide; and (C) a corrosion-inhibiting pigment, preferably a chromium-containing pigment, providing resistance to corrosion. These coatings may be applied to the metal surface to be protected, or the metal surface may be protected with another primer which is overcoated with the subject coatings. The subject coatings are then topcoated, especially with pigmented fluorocarbon coatings.

摘要翻译： 着色，耐磨和耐腐蚀的热固性有机溶剂溶液涂料组合物包含：（A）约50％至约85％的三元醇基封端聚氨酯多异氰酸酯的总树脂固体，其数均分子量范围为600至 4000; （B）占环氧磷酸盐总树脂固体的约15％至约50％，其通过使树脂状聚环氧化物与每当量环氧乙烷中的至少0.05摩尔正磷酸反应而提供; 和（C）耐腐蚀性优异的含铬颜料的腐蚀抑制颜料。 这些涂层可以施加到待保护的金属表面上，或者金属表面可以用与主体涂层涂覆的另一底漆保护。 然后将主题涂料进行表面涂覆，特别是用有色氟碳涂料。

公开(公告)号：US4440894A

公开(公告)日：1984-04-03

申请号：US433389

申请日：1982-10-08

申请人： Zychowski, Edwin A. ,  Kenneth E. Jasenof ,  Artemio L. Jimenez

发明人： Zychowski, Edwin A. ,  Kenneth E. Jasenof ,  Artemio L. Jimenez

IPC分类号： C08F218/00 ,  C08F218/02 ,  C08L31/00 ,  C08L31/04 ,  C08L61/32 ,  C09D131/04 ,  C09D161/20 ,  C09D3/74

CPC分类号： C09D131/04 ,  C08L61/32

摘要： Thermosetting solvent solution coating compositions are disclosed which form hard and impact resistant baked coatings of good gloss retention on exterior exposure. These compositions comprise a butanol-containing solvent having dissolved therein a solution copolymer obtained by copolymerizing from 55% to 75% of vinyl acetate with from 15% to 40% of C.sub.2 -C.sub.8 hydroxyalkyl acrylate or methacrylate, from 3% to 10% of C.sub.2 -C.sub.4 hydroxyalkyl acrylate or methacrylate, and from about 0.5% to about 5% of copolymerizable monoethylenically unsaturated carboxylic acid in organic solvent medium consisting essentially of a butanol at a solids content of at least 65%. This copolymer is used in admixture with a polyalkoxy-methyl melamine in an amount of from 8% to 20%, based on the mixture.

摘要翻译： 公开了热固性溶剂溶液涂料组合物，其形成在外部暴露时具有良好光泽保持性的耐硬且耐冲击的烘烤涂料。 这些组合物包含含有丁醇的溶剂，其中溶解有通过共聚55％至75％的乙酸乙烯酯与15％至40％的丙烯酸酯或甲基丙烯酸C2-C8羟烷基酯，3％至10％的C2 -C4羟烷基丙烯酸酯或甲基丙烯酸酯，以及约0.5％至约5％的可共聚单烯属不饱和羧酸在基本上由固体含量至少为65％的丁醇组成的有机溶剂介质中。 该共聚物与基于混合物的8％至20％的量的聚烷氧基甲基三聚氰胺混合使用。

公开(公告)号：US4312800A

公开(公告)日：1982-01-26

申请号：US924568

申请日：1978-07-14

申请人： Kenneth E. Jasenof ,  James W. Wichmann

发明人： Kenneth E. Jasenof ,  James W. Wichmann

IPC分类号： C09D5/44 ,  C08K3/10

CPC分类号： C09D5/4407 ,  Y10S524/901

摘要： There is disclosed an aqueous anodic electrodeposition bath adapted to electrodeposit substantially clear coatings possessing superior corrosion resistance on aluminum substrates in which water has dispersed therein a carboxy-functional polymer at least partially neutralized with a volatile base together with from 0.08 to 0.5 part, per 1000 parts of the bath, of finely divided particles of pigment grade. The carboxyl-functional polymer preferably comprises a copolymer formed by polymerization in aqueous dispersion of the monomers in solution in an appropriate polyhydric alcohol. The pigment is preferably suspended in a carboxyl-functional resin which dissolves in water with the aid of a base. The preferred soluble resin is a copolymer with an oleyl alcohol ether of a polyepoxide and the preferred pigment is barium chromate.

摘要翻译： 公开了一种水性阳极电沉积浴，其适用于在铝基底上电沉积具有优异耐腐蚀性的基本上透明的涂层，其中水分散有至少部分用挥发性碱中和的羧基官能聚合物，每千克为0.08至0.5份 部分浴液，细分颗粒的颜料级。 羧基官能聚合物优选包含通过在适当的多元醇的溶液中在单体的水分散体中聚合形成的共聚物。 颜料优选悬浮在借助于碱溶解在水中的羧基官能树脂中。 优选的可溶性树脂是与聚环氧化物的油醇醚的共聚物，优选的颜料是铬酸钡。