公开(公告)号：US06929738B1

公开(公告)日：2005-08-16

申请号：US09869981

申请日：2000-01-14

Applicant: Kenneth Llyod Riley ,  Darryl Patrick Klein ,  Zhiguo Hou ,  Stuart Leon Soled ,  Michael Charles Kerby ,  Gary Brice McVicker ,  Edward Stanley Ellis ,  Michele Sue Touvelle ,  Sabato Miseo

Inventor： Kenneth Llyod Riley ,  Darryl Patrick Klein ,  Zhiguo Hou ,  Stuart Leon Soled ,  Michael Charles Kerby ,  Gary Brice McVicker ,  Edward Stanley Ellis ,  Michele Sue Touvelle ,  Sabato Miseo

IPC: C01G53/00 ,  B01J23/00 ,  B01J23/85 ,  B01J23/88 ,  B01J23/883 ,  B01J23/888 ,  B01J37/03 ,  B01J37/08 ,  C07C29/16 ,  C08F8/00 ,  C08F8/04 ,  C08F8/50 ,  C10G45/08 ,  C10G45/16 ,  C10G47/04 ,  C10G47/12 ,  C10G49/04 ,  C10G65/02 ,  C10G65/04 ,  C10G65/08 ,  C10G65/12 ,  C10G67/04 ,  C10G45/04

CPC classification number: C08F8/00 ,  B01J23/002 ,  B01J23/85 ,  B01J23/88 ,  B01J23/883 ,  B01J23/8878 ,  B01J23/888 ,  B01J23/8885 ,  B01J37/03 ,  B01J37/082 ,  B01J2523/00 ,  C08F8/04 ,  C08F8/50 ,  C10G45/08 ,  C10G45/16 ,  C10G47/04 ,  C10G65/04 ,  C10G65/08 ,  C10G65/12 ,  C10G2400/10 ,  C10G2400/14 ,  C08F240/00 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/847

Abstract: A two stage hydrodesulfurizing process for producing low sulfur distillates. A distillate boiling range feedstock containing in excess of about 3,000 wppm sulfur is hydrodesulfurized in a first hydrodesulfurizing stage containing one or more reaction zones in the presence of hydrogen and a hydrodesulfurizing catalyst. The liquid product stream thereof is passed to a first separation stage wherein a vapor phase product stream and a liquid product stream are produced. The liquid product stream, which has a substantially lower sulfur and nitrogen content then the original feedstream is passed to a second hydrodesulfurizing stage also containing one or more reaction zones where it is reacted in the presence of hydrogen and a second hydrodesulfurizing catalyst at hydrodesulfurizing conditions. The catalyst in any one or more reaction zones is a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least two Group VIB metals.

Abstract translation: 一种用于生产低硫馏分的二级加氢脱硫方法。 在含氢和加氢脱硫催化剂的情况下，在含有一个或多个反应区的第一加氢脱硫阶段，加氢脱硫含有超过约3,000wppm硫的馏出物沸程原料。 将其液体产物流送入其中产生气相产物流和液体产物流的第一分离阶段。 具有基本上较低的硫和氮含量的液体产物流然后原始进料流被传递到还含有一个或多个反应区的第二加氢脱硫阶段，其中它在氢气和第二加氢脱硫催化剂的存在下在加氢脱硫条件下反应。 任何一个或多个反应区中的催化剂是由至少一种VIII族非贵金属和至少两种VIB族金属组成的大量多金属催化剂。