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公开(公告)号：US5910373A
公开(公告)日：1999-06-08
申请号：US874320
申请日：1997-06-13
IPC分类号： C08G18/16 , C08G18/22 , C08G18/24 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/65 , C08G18/80 , C09D5/44 , C09D175/00 , B05D1/04
CPC分类号： C08G18/643 , C08G18/161 , C08G18/22 , C08G18/227 , C08G18/242 , C08G18/584 , C08G18/6237 , C08G18/6523 , C08G18/80 , C08G18/807 , C09D5/4492 , C08G2150/20 , Y10T428/31529 , Y10T428/31678
摘要： The invention comprises a curable composition comprising: (i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate; (ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen.; (iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt., nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating compositior can be electrocoated on a conductive substrate and cured.
摘要翻译： 本发明包括可固化组合物，其包含：（i）封闭的反应性组分，其中所述封闭的反应性组分为封端的异氰酸酯或封闭的异硫氰酸酯; （ii）与被封端的活性成分反应的官能化合物，含有活性氢的官能化合物。 （iii）用于促进反应性组分与封端的官能化合物的反应的催化剂，其中所述催化剂基于锰，钴，镍，铜，锌，锗，锑或铋的反应产物或氧化物 其中所述有机酸是己酸，草酸，己二酸，乳酸，酒石酸，水杨酸，巯基乙酸，琥珀酸或巯基琥珀酸，或铜或锗的反应产物或其氧化物与 低级脂肪酸。 锰，钴，镍，铜，锌，锗，锑或铋催化剂可与其他化合物结合使用以促进反应，特别是基于锡的化合物，优选有机锡化合物。 水溶性催化剂是优选的。 涂层组合物可以电涂在导电基材上并固化。
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公开(公告)号：US6124380A
公开(公告)日：2000-09-26
申请号：US266725
申请日：1999-03-12
IPC分类号： C08G18/16 , C08G18/22 , C08G18/24 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/65 , C08G18/80 , C09D5/44 , C08K3/20 , C08L63/02
CPC分类号： C08G18/161 , C08G18/22 , C08G18/227 , C08G18/242 , C08G18/584 , C08G18/6237 , C08G18/643 , C08G18/6523 , C08G18/807 , C09D5/4492 , C08G2150/20
摘要： The invention comprises a curable composition comprising: (i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate; (ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen; (iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating composition can be electrocoated on a conductive substrate and cured.
摘要翻译： 本发明包括可固化组合物，其包含：（i）封闭的反应性组分，其中所述封闭的反应性组分为封端的异氰酸酯或封闭的异硫氰酸酯; （ii）与被封端的活性成分反应的官能化合物，含有活性氢的官能化合物; （iii）促进反应性组分与封端的官能化合物的反应的催化剂，其中所述催化剂基于锰，钴，镍，铜，锌，锗，锑或铋的反应产物或其氧化物 其中所述有机酸是己酸，草酸，己二酸，乳酸，酒石酸，水杨酸，巯基乙酸，琥珀酸或巯基琥珀酸，或铜或锗的反应产物，或其氧化物与 低级脂肪酸。 锰，钴，镍，铜，锌，锗，锑或铋催化剂可与其他化合物结合使用以促进反应，特别是基于锡的化合物，优选有机锡化合物。 水溶性催化剂是优选的。 涂料组合物可以在导电基材上电涂覆并固化。
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公开(公告)号：US6042893A
公开(公告)日：2000-03-28
申请号：US266789
申请日：1999-03-12
IPC分类号： C08G18/16 , C08G18/22 , C08G18/24 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/65 , C08G18/80 , C09D5/44 , C09D175/00 , B05D3/14
CPC分类号： C08G18/643 , C08G18/161 , C08G18/22 , C08G18/227 , C08G18/242 , C08G18/584 , C08G18/6237 , C08G18/6523 , C08G18/80 , C08G18/807 , C09D5/4492 , C08G2150/20 , Y10T428/31529 , Y10T428/31678
摘要： The invention comprises a curable composition comprising: (i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate; (ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen; (iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating composition can be electrocoated on a conductive substrate and cured.
摘要翻译： 本发明包括可固化组合物，其包含：（i）封闭的反应性组分，其中所述封闭的反应性组分为封端的异氰酸酯或封闭的异硫氰酸酯; （ii）与被封端的活性成分反应的官能化合物，含有活性氢的官能化合物; （iii）促进反应性组分与封端的官能化合物的反应的催化剂，其中所述催化剂基于锰，钴，镍，铜，锌，锗，锑或铋的反应产物或其氧化物 其中所述有机酸是己酸，草酸，己二酸，乳酸，酒石酸，水杨酸，巯基乙酸，琥珀酸或巯基琥珀酸，或铜或锗的反应产物，或其氧化物与 低级脂肪酸。 锰，钴，镍，铜，锌，锗，锑或铋催化剂可与其他化合物结合使用以促进反应，特别是基于锡的化合物，优选有机锡化合物。 水溶性催化剂是优选的。 涂料组合物可以在导电基材上电涂覆并固化。
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公开(公告)号：US6028128A
公开(公告)日：2000-02-22
申请号：US174912
申请日：1998-10-19
IPC分类号： C08G18/16 , C08G18/22 , C08G18/24 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/65 , C08G18/80 , C09D5/44 , C09D175/00 , C08K3/20 , C08L63/02
CPC分类号： C08G18/643 , C08G18/161 , C08G18/22 , C08G18/227 , C08G18/242 , C08G18/584 , C08G18/6237 , C08G18/6523 , C08G18/80 , C08G18/807 , C09D5/4492 , C08G2150/20 , Y10T428/31529 , Y10T428/31678
摘要： The invention comprises a curable composition comprising: (i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate; (ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen; (iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating composition can be electrocoated on a conductive substrate and cured.REFERENCE TO RELATED APPLICATIONS
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公开(公告)号：US5859165A
公开(公告)日：1999-01-12
申请号：US471098
申请日：1995-06-06
IPC分类号： C08G18/16 , C08G18/22 , C08G18/24 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/65 , C08G18/80 , C09D5/44 , C09D175/00 , C08G18/08
CPC分类号： C08G18/643 , C08G18/161 , C08G18/22 , C08G18/227 , C08G18/242 , C08G18/584 , C08G18/6237 , C08G18/6523 , C08G18/80 , C08G18/807 , C09D5/4492 , C08G2150/20 , Y10T428/31529 , Y10T428/31678
摘要： The invention comprises a curable composition comprising:(i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate;(ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen;(iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating composition can be electrocoated on a conductive substrate and cured.
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公开(公告)号：US06001900A
公开(公告)日：1999-12-14
申请号：US874630
申请日：1997-06-13
IPC分类号： C08G18/16 , C08G18/22 , C08G18/24 , C08G18/58 , C08G18/62 , C08G18/64 , C08G18/65 , C08G18/80 , C09D5/44 , C08K3/20 , C08L63/02
CPC分类号： C08G18/161 , C08G18/22 , C08G18/227 , C08G18/242 , C08G18/584 , C08G18/6237 , C08G18/643 , C08G18/6523 , C08G18/807 , C09D5/4492 , C08G2150/20
摘要： The invention comprises a curable composition comprising: (i) a blocked reactive component wherein the blocked reactive component is a blocked isocyanate or a blocked isothiocyanate; (ii) a functional compound reactive with the blocked reactive component, the functional compound containing reactive hydrogen; (iii) a catalyst for promoting the reaction of the reactive component with the blocked functional compound, wherein said catalyst is based on the reaction product of manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth, or the oxides thereof with a mercaptan, or an organic acid, wherein said organic acid is hexanoic, oxalic, adipic, lactic, tartaric, salicylic, thioglycolic, succinic, or mercapto succinic acid, or the reaction product of copper or germanium, or the oxides thereof with a lower aliphatic acid. The manganese, cobalt, nickel, copper, zinc, germanium, antimony, or bismuth catalysts can be used in conjunction with other compounds to promote the reaction, especially compounds based on tin, preferably organotin compounds. Water soluble catalysts are preferred. The coating composition can be electrocoated on a conductive substrate and cured.
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