摘要:
The present invention is directed to a method for preparing 3,4-trans-4-ethyl-1,3-disubstituted (substituted phenyl)pyrrolidine-2-one represented by the formula (1) ##STR1## which comprises the steps of dissolving 4-ethyl-1,3-disubstituted (substituted phenyl)-3-pyrroline-2-one in an inert solvent, and then reducing the same with sodium boron hydride in the presence of methanol.
摘要:
A 3-azabicyclo[3.1.0]hexane-2-one derivative represented by the following formula (I), and a herbicidal composition containing the same as a herbicidally active ingredient: ##STR1## (wherein X is a halogen atom, an alkyl group having 1 to 3 carbon atoms, an alkoxy group having 1 to 3 carbon atoms or a haloalkyl group having 1 to 3 carbon atoms; Y is a halogen atom or an alkyl group having 1 to 3 carbon atoms; R.sub.1 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms; R.sub.2 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms; m is an integer of 0 to 3; n is an integer of 0 to 2; and when m is 2 or 3, the groups represented by X may be identical or different, and when n is 2, the groups represented by Y may be identical or different).
摘要翻译:由下式(I)表示的3-氮杂双环[3.1.0]己烷-2-酮衍生物和除草组合物,其含有除草活性成分:(I)(其中X是卤素原子 ,具有1至3个碳原子的烷基,具有1至3个碳原子的烷氧基或具有1至3个碳原子的卤代烷基; Y是卤素原子或具有1至3个碳原子的烷基; R 1是 氢原子或碳原子数1〜3的烷基,R2为氢原子或碳原子数1〜3的烷基,m为0〜3的整数,n为0〜2的整数,m为0〜 是2或3,由X表示的基团可以相同或不同,并且当n为2时,由Y表示的基团可以相同或不同)。
摘要:
A 3,4-cis isomer of 4-ethyl-1-(substituted phenyl)-3-substituted phenyl)pyrrolidin-2-one, when reacted with a base, can be effectively convered into a 3,4-trans isomer thereof which has a high herbicidal activity useful as an effective ingredient for a herbicidal composition. Furthermore, 3,4-trans-4-ethyl-1-(substituted phenyl)-3-(substituted phenyl)pyrrolidin-2-one compounds represented by the formula (III) ##STR1## (wherein R.sup.2 is an isopropyl group, and X is a fluorine atom, chlorine atom or bromine atom substituted at the 3-position, or fluorine atoms substituted at the 3- and 4-positions or the 3- and 5-positions) have an extremely excellent activity particularly as a herbicidally active ingredient of the herbicidal composition for rice paddy fields.
摘要:
2-Methyl-4'-isopropyl-2-pentenoyl anilide, a selective herbicide comprising this compound as a main active ingredient, and a process for producing the aforesaid compound.
摘要:
A herbicidal composition is here disclosed which exerts an excellent herbicidal activity and which is harmless to paddy rice.A 1-[1-methyl-1-(substituted phenyl)ethyl]-4,5-dimethyl-3-(substituted phenyl)-3-pyrroline-2-one derivative represented by the formula (I) ##STR1## (wherein X is a chlorine atom, fluorine atom or bromine atom; Y is a hydrogen atom, fluorine atom, chlorine atom or methoxy group; Z is a hydrogen atom, fluorine atom, bromine atom or chlorine atom; and Q is a hydrogen atom or fluorine atom)is a novel compound, and the herbicidal composition containing this compound as a herbicidally active ingredient has the strong activity and high selectivity as the herbicidal composition for paddy fields.
摘要:
4-Ethyl-3-(phenyl)-1-(3-trifluoromethylphenyl)-2-pyrrolidinones and corresponding compounds bearing a p-substituent on the 1-position phenyl group and/or a substituent on the 3-position phenyl group exhibit selective herbicidal activities against various weeds which cause problems in rice or upland fields, even at extremely low application rates. They can be prepared by reductive dehalogenation of a corresponding .alpha.-haloethyl substituted pyrrolidinone or reductive cyclization of a corresponding N-2-butenyl-N-(substituted phenyl)-haloacetyl-3-trifluoromethylaniline.
摘要:
An N-(3-chloro-4-isopropylphenyl)carboxamide derivative represented by the general formula ##STR1## wherein R represents a 1-methylbutyl, 1-methylcyclopropyl or cyclopropyl group. This derivative is useful as a selective herbicide, and can be produced by reacting 3-chloro-4-isopropylaniline with a carboxylic acid halide derivative of the general formula ##STR2## wherein R is as defined above and X represents halogen, or with a carboxyilc acid anhydride of the general formula ##STR3## wherein R is as defined above.
摘要:
1-(3-Substituted benzyl)-3-halogeno-4-(1-halogenoalkyl)-2-pyrrolidinones of the general formula (I): ##STR1## where X represents a hydrogen atom or halogen atom, Y and Z each represents a chlorine atom or bromine atom, and R represents an alkyl group with 2 to 4 carbon atoms, are herbicides useful in rice paddy fields to control weeds therein, especially Echinochloa crusgalli and can be produced subjecting the corresponding 3-dihalogeno compounds to dehalogenation to remove one of the halogen atoms or by cyclizing a 2,2-dihalogenoacetamide derivative represented by the general formula (II) under the presence of an appropriate catalyst; ##STR2## in which X, Y, Z and R respectively have the same meanings as described above.