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1.发明申请公开(公告)号：US20100186634A1
公开(公告)日：2010-07-29
申请号：US12670104
申请日：2008-07-16
IPC分类号： C04B28/02
CPC分类号： C04B7/3453 , C04B28/18 , C04B2111/00189 , C04B2111/00198 , C04B2111/00206 , Y02P40/148
摘要： The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of no more than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.75 to 2.75, and the binder containing an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder.Furthermore, the invention relates to methods for manufacturing the binder or a mixture containing this binder by converting calcium-containing and silicate-containing starting materials into a preproduct which at least in part contains a calcium hydroxosilicate, subsequent grinding of the calcium hydroxosilicate until the monophase hydraulic binder forms, and optionally drying the monophase hydraulic binder to an H2O content of 3.5% by weight to 20% by weight.Finally, the invention relates to a building material made by setting the binder or a mixture containing this binder with water and subsequent hardening.
摘要翻译： 本发明涉及含有硅，钙，氧和氢原子的单相水硬性粘合剂，其包含平均连接性不超过Q1.5和硅烷醇基团的硅酸盐构建单元，其中没有或部分钙原子被取代 由于与氧的六价或更高配位的金属原子M [6] x +和/或没有或一部分硅原子被与氧四面体配位的金属原子M [4] y +代替，[...] CaO +（x / 2）·（M [6] x + Ox / 2）]：[SiO2 + M [4] y + Oy / 2]，值为0.75〜2.75， ％至20重量％，以及含有该粘合剂的混合物。 此外，本发明涉及通过将含钙和含硅酸盐的原料转化成至少部分含有羟基硅酸钙的前产物来制备粘合剂或含有该粘合剂的混合物的方法，随后研磨羟基硅酸钙直到单相 水硬性粘合剂形式，并且任选地将单相水硬性粘合剂干燥至3.5重量％至20重量％的H 2 O含量。 最后，本发明涉及通过将粘合剂或含有该粘合剂的混合物用水和随后的硬化来制备的建筑材料。
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2.发明授权Single-phase hydraulic binder, methods for the production thereof and building material produced therewith 有权单相液压粘合剂，其制造方法和由其制造的建筑材料公开(公告)号：US08382892B2
公开(公告)日：2013-02-26
申请号：US12670098
申请日：2008-07-16
IPC分类号： C04B7/02
CPC分类号： C04B7/3453 , C04B28/188 , C04B2111/00215 , Y02P40/148
摘要： The invention relates to a monophase amorphous hydraulic binder containing silicon, calcium and oxygen atoms in an arrangement comprising silicate building units having an average connectedness of at least Q1, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or no more than 45 atomic percent of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.2 to 1.5, and the binder having less than 3.5% by weight of water, as well as a mixture containing this binder. Furthermore, the invention relates to methods for manufacturing the binder or a mixture containing this binder by reaction grinding a starting material containing silicate building units having a connectedness of Q0 to Q2, with a solid silicate raw material having a connectedness of the silicate building units of Q3 to Q4 and optionally drying the monophase hydraulic binder to a water content of below 3.5% by weight.Finally, the invention relates to a building material made by setting the binder or a mixture containing this binder with water and subsequent hardening.
摘要翻译： 本发明涉及含有硅，钙和氧原子的单相非晶态水硬性粘合剂，其中包括具有至少Q1的平均连接性的硅酸盐构建单元，没有一部分或部分钙原子被金属原子M [ 6] x +六重或更高配位的氧和/或没有或不超过45原子％的硅原子被与氧四面体配位的金属原子M [4] y +取代，[CaO +（x / 2）·（M [6] x + Ox / 2）]：[SiO 2 + M [4] y + Oy / 2]，其值为0.2〜1.5，粘合剂的含量小于3.5重量％ ，以及含有该粘合剂的混合物。 此外，本发明涉及通过反应研磨含有Q0至Q2的连接性的硅酸盐建筑单元的原料与具有连接性为Q0至Q2的硅酸盐构成单元的固体硅酸盐原料来制造粘合剂或含有该粘合剂的混合物的方法， Q3至Q4，并任选地将单相水硬性粘合剂干燥至含水量低于3.5重量％。 最后，本发明涉及通过将粘合剂或含有该粘合剂的混合物用水和随后的硬化来制备的建筑材料。
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3.发明授权Single-phase hydraulic binder, methods for the production thereof and structural material produced therewith 有权单相水力粘合剂，其制造方法和由其制造的结构材料公开(公告)号：US08226763B2
公开(公告)日：2012-07-24
申请号：US12670104
申请日：2008-07-16
IPC分类号： C04B12/00
CPC分类号： C04B7/3453 , C04B28/18 , C04B2111/00189 , C04B2111/00198 , C04B2111/00206 , Y02P40/148
摘要： The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of no more than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.75 to 2.75, and the binder containing an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder. Furthermore, the invention relates to methods for manufacturing the binder or a mixture containing this binder by converting calcium-containing and silicate-containing starting materials into a preproduct which at least in part contains a calcium hydroxosilicate, subsequent grinding of the calcium hydroxosilicate until the monophase hydraulic binder forms, and optionally drying the monophase hydraulic binder to an H2O content of 3.5% by weight to 20% by weight.Finally, the invention relates to a building material made by setting the binder or a mixture containing this binder with water and subsequent hardening.
摘要翻译： 本发明涉及含有硅，钙，氧和氢原子的单相水硬性粘合剂，其包含平均连接性不超过Q1.5和硅烷醇基团的硅酸盐构建单元，其中没有或部分钙原子被取代 由于与氧的六价或更高配位的金属原子M [6] x +和/或没有或一部分硅原子被与氧四面体配位的金属原子M [4] y +代替，[...] CaO +（x / 2）·（M [6] x + Ox / 2）]：[SiO2 + M [4] y + Oy / 2]，值为0.75〜2.75， ％至20重量％，以及含有该粘合剂的混合物。 此外，本发明涉及通过将含钙和含硅酸盐的原料转化成至少部分含有羟基硅酸钙的前产物来制备粘合剂或含有该粘合剂的混合物的方法，随后研磨羟基硅酸钙直到单相 水硬性粘合剂形式，并且任选地将单相水硬性粘合剂干燥至3.5重量％至20重量％的H 2 O含量。 最后，本发明涉及通过将粘合剂或含有该粘合剂的混合物用水和随后的硬化来制备的建筑材料。
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公开(公告)号：US20080093774A1
公开(公告)日：2008-04-24
申请号：US11912186
申请日：2006-03-24
IPC分类号： C04B35/622
CPC分类号： C04B28/186 , Y02W30/92 , Y02W30/94 , Y10S264/25 , Y10S264/35 , C04B12/04 , C04B14/06 , C04B14/062 , C04B14/305 , C04B14/365 , C04B18/067 , C04B18/141 , C04B22/064 , C04B22/066 , C04B40/0259
摘要： A method for producing components including preparing an aqueous suspension of solids including calcium oxide CaO and silicon dioxide SiO2 with a molar ratio of Ca:Si that is between 0.5:1.0 and 2.5:1.0. Nanocrystalline C—S—H phases are produced by grinding the aqueous suspension and keeping its temperature at or below 100° C. The aqueous phase is separated out from the suspension to form a residue containing the nanocrystalline C—S—H phases. The residued is removed and a powdery product is made by drying the residue. A mold is filled with the powdery product and pressure is applied to form the component. The component is removed from the mold.
摘要翻译： 一种制备组分的方法，包括制备包含氧化钙CaO和二氧化硅SiO 2的固体的水悬浮液，其摩尔比Ca:Si为0.5:1.0至2.5:1.0。 通过研磨水悬浮液并保持其温度在100℃以下，制备纳米晶C-S-H相。将水相从悬浮液中分离出来，形成含有N-C-S-H相的纳米晶体的残余物。 将残留物除去，并通过干燥残余物制备粉状产物。 用粉末状产品填充模具，施加压力以形成组分。 将组件从模具中取出。
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5.发明申请公开(公告)号：US20100206199A1
公开(公告)日：2010-08-19
申请号：US12670109
申请日：2008-07-16
IPC分类号： C04B28/00
CPC分类号： C04B7/3453 , C01B33/20 , C04B28/188 , C04B2111/00215 , Y02P40/148
摘要： The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of higher than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]Yy+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2) (M[6]x+Ox/2)]: [SiO2+M[4]y+Oy/2] having a value of 0.2 to 2.0, and the binder having an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder.Furthermore, the invention relates to methods for manufacturing the binder or a mixture containing this binder by reaction grinding a starting material of silicate building units having a connectedness of Q0 to Q2, and optionally further materials, with a solid silicate raw material having a ceonnectedness of the silicate building units of Q3 to Q4 and optionally drying the monophase hydraulic binder to an H2O content of 3.5% by weight to 20% by weight.Finally, the invention relates to a building material made by setting the binder or a mixture containing this binder with water and subsequent hardening.
摘要翻译： 本发明涉及含有硅，钙，氧和氢原子的单相水硬性粘合剂，其包含平均连接性高于Q1.5的硅酸盐构建单元和硅烷醇基团，其中没有或部分钙原子被取代 通过与氧的六价或更高配位的金属原子M [6] x +和/或没有或一部分硅原子被与氧四面体配位的金属原子M [4] Y y +取代，[CaO + （x / 2）（M [6] x + Ox / 2）]：[SiO2 + M [4] y + Oy / 2]，其值为0.2〜2.0， 重量至20％重量，以及含有该粘合剂的混合物。 此外，本发明涉及用于制造粘合剂的方法或含有该粘合剂的混合物的方法，其通过反应研磨具有Q0至Q2连接性的硅酸盐构建单元的起始材料和任选的其它材料与具有连接性的固体硅酸盐原料 Q3至Q4的硅酸盐建筑单元，并任选地将单相水硬性粘合剂干燥至3.5重量％至20重量％的H 2 O含量。 最后，本发明涉及通过将粘合剂或含有该粘合剂的混合物用水和随后的硬化来制备的建筑材料。
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6.发明授权Single-phase hydraulic binder, methods for the production thereof and structural material produced therewith 有权单相水力粘合剂，其制造方法和由其制造的结构材料公开(公告)号：US08226764B2
公开(公告)日：2012-07-24
申请号：US12670109
申请日：2008-07-16
IPC分类号： C04B12/00
CPC分类号： C04B7/3453 , C01B33/20 , C04B28/188 , C04B2111/00215 , Y02P40/148
摘要： The invention relates to a monophase hydraulic binder containing silicon, calcium, oxygen and hydrogen atoms in an arrangement comprising silicate building units having an average connectedness of higher than Q1.5 and silanol groups, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or a part of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]: [SiO2+M[4]y+Oy/2] having a value of 0.2 to 2.0, and the binder having an H2O content of 3.5% by weight to 20% by weight, as well as a mixture containing this binder. Furthermore, the invention relates to methods for manufacturing the binder or a mixture containing this binder by reaction grinding a starting material of silicate building units having a connectedness of Q0 to Q2, and optionally further materials, with a solid silicate raw material having a ceonnectedness of the silicate building units of Q3 to Q4 and optionally drying the monophase hydraulic binder to an H2O content of 3.5% by weight to 20% by weight.Finally, the invention relates to a building material made by setting the binder or a mixture containing this binder with water and subsequent hardening.
摘要翻译： 本发明涉及含有硅，钙，氧和氢原子的单相水硬性粘合剂，其包含平均连接性高于Q1.5的硅酸盐构建单元和硅烷醇基团，其中没有或部分钙原子被取代 通过与氧的六价或更高配位的金属原子M [6] x +和/或没有或一部分硅原子被与氧四面体配位的金属原子M [4] y +代替，[CaO + （x / 2）·（M [6] x + Ox / 2）]：[SiO2 + M [4] y + Oy / 2]，值为0.2〜2.0， 至20重量％，以及含有该粘合剂的混合物。 此外，本发明涉及用于制造粘合剂的方法或含有该粘合剂的混合物的方法，其通过反应研磨具有Q0至Q2连接性的硅酸盐构建单元的起始材料和任选的其它材料与具有连接性的固体硅酸盐原料 Q3至Q4的硅酸盐建筑单元，并任选地将单相水硬性粘合剂干燥至3.5重量％至20重量％的H 2 O含量。 最后，本发明涉及通过将粘合剂或含有该粘合剂的混合物用水和随后的硬化来制备的建筑材料。
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7.发明申请公开(公告)号：US20110041737A1
公开(公告)日：2011-02-24
申请号：US12670098
申请日：2008-07-16
CPC分类号： C04B7/3453 , C04B28/188 , C04B2111/00215 , Y02P40/148
摘要： The invention relates to a monophase amorphous hydraulic binder containing silicon, calcium and oxygen atoms in an arrangement comprising silicate building units having an average connectedness of at least Q1, with none or a part of the calcium atoms being substituted for by a metal atom M[6]x+ sixfold or higher-coordinated with oxygen and/or none or no more than 45 atomic percent of the silicon atoms being substituted for by a metal atom M[4]y+ tetrahedrally coordinated with oxygen, the molar ratio of [CaO+(x/2)·(M[6]x+Ox/2)]:[SiO2+M[4]y+Oy/2] having a value of 0.2 to 1.5, and the binder having less than 3.5% by weight of water, as well as a mixture containing this binder.Furthermore, the invention relates to methods for manufacturing the binder or a mixture containing this binder by reaction grinding a starting material containing silicate building units having a connectedness of Q0 to Q2, with a solid silicate raw material having a connectedness of the silicate building units of Q3 to Q4 and optionally drying the monophase hydraulic binder to a water content of below 3.5% by weight.Finally, the invention relates to a building material made by setting the binder or a mixture containing this binder with water and subsequent hardening.
摘要翻译： 本发明涉及含有硅，钙和氧原子的单相非晶态水硬性粘合剂，其中包括具有至少Q1的平均连接性的硅酸盐构建单元，没有一部分或部分钙原子被金属原子M [ 6] x +六重或更高配位的氧和/或没有或不超过45原子％的硅原子被与氧四面体配位的金属原子M [4] y +取代，[CaO +（x / 2）·（M [6] x + Ox / 2）]：[SiO 2 + M [4] y + Oy / 2]，其值为0.2〜1.5，粘合剂的含量小于3.5重量％ ，以及含有该粘合剂的混合物。 此外，本发明涉及通过反应研磨含有Q0至Q2的连接性的硅酸盐建筑单元的原料与具有连接性为Q0至Q2的硅酸盐构成单元的固体硅酸盐原料来制造粘合剂或含有该粘合剂的混合物的方法， Q3至Q4，并任选地将单相水硬性粘合剂干燥至含水量低于3.5重量％。 最后，本发明涉及通过将粘合剂或含有该粘合剂的混合物用水和随后的硬化来制备的建筑材料。
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公开(公告)号：US07807078B2
公开(公告)日：2010-10-05
申请号：US11912186
申请日：2006-03-24
IPC分类号： B29C43/02
CPC分类号： C04B28/186 , Y02W30/92 , Y02W30/94 , Y10S264/25 , Y10S264/35 , C04B12/04 , C04B14/06 , C04B14/062 , C04B14/305 , C04B14/365 , C04B18/067 , C04B18/141 , C04B22/064 , C04B22/066 , C04B40/0259
摘要： A method for producing components including preparing an aqueous suspension of solids including calcium oxide CaO and silicon dioxide SiO2 with a molar ratio of Ca:Si that is between 0.5:1.0 and 2.5:1.0. Nanocrystalline C—S—H phases are produced by grinding the aqueous suspension and keeping its temperature at or below 100° C. The aqueous phase is separated out from the suspension to form a residue containing the nanocrystalline C—S—H phases. The residued is removed and a powdery product is made by drying the residue. A mold is filled with the powdery product and pressure is applied to form the component. The component is removed from the mold.
摘要翻译： 一种制备组分的方法，包括制备包含氧化钙CaO和二氧化硅SiO 2的固体的水悬浮液，其摩尔比Ca:Si为0.5:1.0至2.5:1.0。 通过研磨水悬浮液并保持其温度在100℃以下，制备纳米晶C-S-H相。将水相从悬浮液中分离出来，形成含有N-C-S-H相的纳米晶体的残余物。 将残留物除去，并通过干燥残余物制备粉状产物。 用粉末状产品填充模具，施加压力以形成组分。 将组件从模具中取出。
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