Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions
    5.
    发明授权
    Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions 有权
    制备贵金属纳米颗粒的分散体并从所述分散体中分离这些纳米颗粒的方法

    公开(公告)号:US08529963B2

    公开(公告)日:2013-09-10

    申请号:US12811985

    申请日:2009-01-09

    CPC classification number: B01J13/0043 B22F1/0022 B22F9/24 B82Y30/00

    Abstract: The present invention is directed to a method for preparing colloidal dispersions of precious metal nanoparticles selected from the group consisting of Pt, Au, Pd, Ag, Rh, Ru and mixtures or alloys thereof, and to a method for isolating such precious metal nanoparticles from these colloidal dispersions. The colloidal dispersions are prepared by reducing suitable precious metal precursor compounds in aqueous alkaline solutions at reaction temperatures between 40 and 70° C. and a pH≧12.0 in the presence of polysaccharides with average molecular weights (Mw) in the range of 300,000 to 1,000,000. The precious metal nanoparticles are isolated after decomposing the polysaccharide by heating the colloidal dispersions to temperatures >80° C. The nanoparticles can be used for the manufacture of core/shell-type catalyst materials and for electronic, decorative and medical applications.

    Abstract translation: 本发明涉及一种制备选自Pt,Au,Pd,Ag,Rh,Ru及其混合物或合金的贵金属纳米颗粒的胶体分散体的方法,以及用于分离这些贵金属纳米颗粒的方法 这些胶体分散体。 胶体分散体是通过在40〜70℃的反应温度下,在碱性水溶液中还原合适的贵金属前体化合物,在平均分子量(Mw)范围为30万〜 1,000,000。 通过将胶体分散体加热至80℃以上,分解多糖后,分离出贵金属纳米粒子。纳米颗粒可用于制造核/壳型催化剂材料以及电子,装饰和医疗应用。

    Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions
    6.
    发明申请
    Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions 有权
    制备贵金属纳米颗粒的分散体并从所述分散体中分离这些纳米颗粒的方法

    公开(公告)号:US20110064825A1

    公开(公告)日:2011-03-17

    申请号:US12811985

    申请日:2009-01-09

    CPC classification number: B01J13/0043 B22F1/0022 B22F9/24 B82Y30/00

    Abstract: The present invention is directed to a method for preparing colloidal dispersions of precious metal nanoparticles selected from the group consisting of Pt, Au, Pd, Ag, Rh, Ru and mixtures or alloys thereof, and to a method for isolating such precious metal nanoparticles from these colloidal dispersions. The colloidal dispersions are prepared by reducing suitable precious metal precursor compounds in aqueous alkaline solutions at reaction temperatures between 40 and 70° C. and a pH≧12.0 in the presence of polysaccharides with average molecular weights (Mw) in the range of 300,000 to 1,000,000. The precious metal nanoparticles are isolated after decomposing the polysaccharide by heating the colloidal dispersions to temperatures >80° C. The nanoparticles can be used for the manufacture of core/shell-type catalyst materials and for electronic, decorative and medical applications.

    Abstract translation: 本发明涉及一种制备选自Pt,Au,Pd,Ag,Rh,Ru及其混合物或合金的贵金属纳米颗粒的胶体分散体的方法,以及用于分离这些贵金属纳米颗粒的方法 这些胶体分散体。 胶体分散体是通过在反应温度在40-70℃之间的碱性水溶液中还原合适的贵金属前体化合物,在平均分子量(Mw)在30万至1,000,000范围内的多糖存在下的pH≥12.0来制备的 。 通过将胶体分散体加热至80℃以上,分解多糖后,分离出贵金属纳米粒子。纳米颗粒可用于制造核/壳型催化剂材料以及电子,装饰和医疗应用。

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