摘要:
New antistatic compounds of formula ##STR1## WHEREIN R.sub.1 is alkyl optionally interrupted by 1 or 2 S, SO or SO.sub.2 moieties or 1 COO moiety, any alkyl(ene) being optionally hydroxyl-substituted; cycloalkyl; alkylcycloalkyl; or a mono- or polyoxyalkylene group terminated by alkyl, optionally alkyl-substituted phenyl or phenylalkyl:,n is 1 or 2;m is an integer 1 to 7;R.sub.2 is (m + 1) valent alkylene optionally interrupted by 1 or 2 O, S, SO or SO.sub.2 moieties; bivalent benzene, cyclohexane, biphenyl, diphenyloxide, -sulphide, -sulphoxide, -sulphone or -methane, 2,2-diphenylpropane, bis-cyclohexylmethane or 2,2-bis-cyclohexylpropane, or a (m + 1) valent mono- or polyoxyalkylene group containing R.sub.2 ;and each R.sub.3, independently, has one of the meanings given for R.sub.1, or is hydrogen or phenyl, naphthyl or phenylalkyl optionally substituted on the aromatic nucleus; a group ##STR2## having the above meanings; or a group ##STR3## in which R.sub.6 is alkyl, perfluoroalkyl or optionally substituted phenyl or naphthyl.Such compounds are useful as antistatic agents for organic materials, particularly a plastics material such as polypropylene, and may either be incorporated in the organic material directly by admixture therewith or indirectly by admixture with a precondensate thereof and subsequent polymerization, or applied as a coating thereon. They can be produced by processes known per se.
摘要:
Organic materials are stabilized against the effects of heat, light or oxygen by addition of a compound of the formula ##STR1## WHEREIN X is --CH.sub.2 --, --O-- or -- S--,Y.sub.1, y.sub.2, y.sub.3 and Y.sub.4 are --O-- or --S--,R.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen or hydrocarbon radicalsn is 0 or 1And rings A and B may be further substituted by 1 or 2 alkyl groupsOr an inorganic salt of such a compound in which any of R.sub.1 -R.sub.4 are hydrogen.
摘要:
The purpose of the invention are new benzene phosphonous acid compounds in which two to four benzene nuclei are bound together and which contain one to three phosphorus atoms. The new compounds are free acids, their salts with inorganic cations, their esters, thioesters or amides. The invention concerns also the manufacture of these benzene phosphonous acid compounds and their use for the stabilization of organic materials.
摘要:
1,3-Dihydrocarbyl-pyrazole compounds, having a 5-hydroxyl group in free or nickel salt form, characterized by a ketoxyimino group bound directly to the 4-position of the pyrazole ring through the ketoxyimino functional carbon atom, which are useful as stabilizers of organic materials against the adverse effects of ultraviolet light.
摘要:
The present invention concerns novel nickel complexes (I) possessing U.V. stabilizing properties characterized by bearing per molecule 2 monodentate nickel coordinated 1,3-hydrocarbyl-4-(greater than C.sub.1)-acyl-pyrazole-5-oxy ligands and one bidentate or two monodentate nickel coordinated primary or secondary amine ligands, and their use as U.V. stabilizers for e.g. plastics materials.
摘要:
Novel compounds based on a hydroxybiphenyl nucleus in which the hydroxy group is in the para position relative to the other phenyl ring and has an adjacent tertiary alkyl radical, are useful stabilizers for organic compounds against heat, light or oxygen.
摘要:
The present invention concerns a novel method of stabilizing organic material susceptible to degradation under the effect of heat, oxidation or ultra-violet light which comprises treating said material with a compound of the formula: ##STR1## WHEREIN R.sub.1, R.sub.2 and R.sub.3 are substituents, e.g. alkyl and Me is hydrogen or a metal cation.
摘要:
The purpose of the invention are new benzene phosphonous acid compounds in which two to four benzene nuclei are bound together and which contain one to three phosphorus atoms. The new compounds are free acids, their salts with inorganic cations, their esters, thioesters or amides. The invention concerns also the manufacture of these benzene phosphonous acid compounds and their use for the stabilization of organic materials.
摘要:
The present invention concerns novel aromatic heterocyclic hydrazide derivatives of the formula: ##SPC1##Wherein A is a radical ##SPC2##Wherein R.sub.1 is tertiary alkyl and R.sub.2 and R.sub.3 are hydrogen or substituents, e.g. alkyl, R.sub.4 is a group -X-R.sub.14.sub.' wherein X is a bridging function, e.g. O, and R.sub.14 is a substituent, e.g. alkyl, a heterocyclic group--N Zwherein Z, with the nitrogen atom, forms a heterocyclic ring or a radical -NH-A, wherein A is as defined above, R.sub.5 has inter alia one of the significances of R.sub.4 and Y is -N= or -CH=, which are useful antioxidants, e.g. for stabilizing plastics material.
摘要:
The present invention concerns novel nickel complexes (I) possessing U.V. stabilizing properties characterized by bearing per molecule 2 monodentate nickel coordinated 1,3-hydrocarbyl-4-(greater than C.sub.1)-acyl-pyrazole-5-oxy ligands and one bidentate or two monodentate nickel coordinated primary or secondary amine ligands, and their use as U.V. stabilizers for e.g. plastics materials.