Selected chabazite zeolites as catalysts for conversion of methanol and
ammonia to diemethylamine
    4.
    发明授权
    Selected chabazite zeolites as catalysts for conversion of methanol and ammonia to diemethylamine 失效
    选择的菱沸石沸石作为将甲醇和氨转化为二乙胺的催化剂

    公开(公告)号:US4737592A

    公开(公告)日:1988-04-12

    申请号:US909238

    申请日:1986-09-19

    CPC classification number: C07C209/16

    Abstract: A process is provided for producing dimethylamine, comprising reacting methanol and/or dimethylether and ammonia in amounts sufficient to provide a carbon/nitrogen (C/N) ratio from about 0.2 to about 1.5, at a temperature from about 250.degree. C. to about 450.degree. C., in the presence of a catalytic amount of an acidic zeolite catalyst selected from the group consisting of natural, H-exchanged, and M-exchanged chabazites, each having a geometric selectivity index greater than about 3, wherein M is one or more alkali metal ions selected from the group consisting of Na, K, Rb, and Cs.

    Abstract translation: 提供了一种用于生产二甲胺的方法,包括使甲醇和/或二甲醚与氨的反应量足以提供约0.2至约1.5的碳/氮(C / N)比,在约250℃至约 在催化量的酸性沸石催化剂的存在下,选自天然的,H交换的和M交换的菱沸石,每个具有大于约3的几何选择性指数,其中M是一个 或更多选自Na,K,Rb和Cs的碱金属离子。

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