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公开(公告)号：US20140148620A1
公开(公告)日：2014-05-29
申请号：US13822033
申请日：2011-08-25
IPC分类号： C07C37/07
CPC分类号： C07C37/07 , B01J23/38 , B01J23/40 , B01J23/58 , B01J35/023 , B01J37/0201 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C13/28
摘要： In a process for the dehydrogenation of cyclohexanone to produce phenol, cyclohexanone is contacted in a reaction zone under dehydrogenation conditions with a dehydrogenation catalyst comprising (i) a support comprising silica; and (ii) a dehydrogenation component comprising at least one metal selected from Group 10 of Periodic Table of Elements. Contact of the dehydrogenation catalyst with the cyclohexanone is then terminated and the dehydrogenation catalyst is contacted with an inert gas and/or hydrogen at a temperature of at least 300° C. Contact of the dehydrogenation catalyst with additional cyclohexanone is subsequently reestablished.
摘要翻译： 在环己酮脱氢生产苯酚的方法中，环己酮在脱氢条件下在反应区与脱氢催化剂接触，脱氢催化剂包括（i）包含二氧化硅的载体; 和（ii）包含选自元素周期表第10族的至少一种金属的脱氢组分。 然后终止脱氢催化剂与环己酮的接触，脱氢催化剂在至少300℃的温度下与惰性气体和/或氢气接触。随后重新建立脱氢催化剂与另外的环己酮的接触。
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公开(公告)号：US07579511B1
公开(公告)日：2009-08-25
申请号：US12287655
申请日：2008-10-10
CPC分类号： C07C2/74 , C07C2601/14 , C07C13/28
摘要： Provided is a process for making cyclohexylbenzene. The process includes the following steps: (a) contacting benzene and hydrogen in the presence of a first catalyst under hydroalkylation conditions sufficient to form a first effluent stream having cyclohexylbenzene, cyclohexane, methyl cyclopentane, and unreacted benzene; (b) supplying at least part of said first effluent stream to a first separation system to divide said first effluent stream part into a cyclohexane/methylcyclopentane-rich stream, a cyclohexane-rich stream, a benzene-rich stream, and a dicyclohexyl benzene-rich stream; (c) recycling at least part of the benzene-rich stream to the contacting step (a); (d) contacting the cyclohexane/methylcyclopentane-rich stream with a second catalyst that catalyzes dehydrogenation and exhibits low acidity under conditions sufficient to convert at least a portion of the cyclohexane to benzene and at least a portion of the methylcyclopentane to linear and/or branched paraffins to form a second effluent stream; and (e) recycling at least part of the second effluent stream to the contacting step (a).
摘要翻译： 提供了制备环己基苯的方法。 该方法包括以下步骤：（a）在足以形成具有环己基苯，环己烷，甲基环戊烷和未反应苯的第一流出物流的加氢烷基化条件下，在第一催化剂存在下使苯和氢接触; （b）将至少部分所述第一流出物流供应到第一分离系统以将所述第一流出物流部分分解成富环己烷/甲基环戊烷流，富环己烷流，富含苯的流和二环己基苯 - 富流 （c）将至少部分富含苯的物流再循环至接触步骤（a）; （d）使环己烷/甲基环戊烷流与催化脱氢的第二催化剂接触，并且在足以将至少一部分环己烷转化为苯和至少一部分甲基环戊烷的条件下呈现低酸度至线性和/或支化 石蜡形成第二流出物流; 和（e）将至少部分第二流出物流再循环到接触步骤（a）。
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公开(公告)号：US09580368B2
公开(公告)日：2017-02-28
申请号：US14006338
申请日：2011-12-02
申请人： Tan-Jen Chen , Jihad Mohammed Dakka , Terry Eugene Helton , Francisco Manuel Benitez , Charles Morris Smith , Lorenzo Cophard DeCaul
发明人： Tan-Jen Chen , Jihad Mohammed Dakka , Terry Eugene Helton , Francisco Manuel Benitez , Charles Morris Smith , Lorenzo Cophard DeCaul
CPC分类号： C07C5/367 , C07C5/325 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C13/20
摘要： Disclosed herein is a process for dehydrogenating a saturated cyclic hydrocarbon and/or 5-membered ring compound with a dehydrogenation catalyst. The dehydrogenation catalyst comprises: (i) 0.05 wt % to 5 wt % of a metal selected from Group 14 of the Periodic Table of Elements; and (ii) 0.1 wt % to 10 wt % of a metal selected from Groups 6 to 10 of the Periodic Table of Elements. The process is conducted under dehydrogenation conditions effective to dehydrogenate at least a portion saturated cyclic hydrocarbon and/or 5-membered ring compound.
摘要翻译： 本文公开了一种使用脱氢催化剂使饱和环烃和/或五元环化合物脱氢的方法。 脱氢催化剂包括：（i）0.05重量％至5重量％的选自元素周期表第14族的金属; 和（ii）0.1重量％至10重量％的选自元素周期表第6至10族的金属。 该方法在有效使至少一部分饱和环烃和/或五元环化合物脱氢的脱氢条件下进行。
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公开(公告)号：US08884075B2
公开(公告)日：2014-11-11
申请号：US13822033
申请日：2011-08-25
IPC分类号： C07C37/07 , B01J35/02 , C07C2/74 , B01J23/40 , C07C407/00 , C07C45/53 , C07C37/08 , B01J37/02 , B01J23/38 , B01J23/58
CPC分类号： C07C37/07 , B01J23/38 , B01J23/40 , B01J23/58 , B01J35/023 , B01J37/0201 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C13/28
摘要： In a process for the dehydrogenation of cyclohexanone to produce phenol, cyclohexanone is contacted in a reaction zone under dehydrogenation conditions with a dehydrogenation catalyst comprising (i) a support comprising silica; and (ii) a dehydrogenation component comprising at least one metal selected from Group 10 of Periodic Table of Elements. Contact of the dehydrogenation catalyst with the cyclohexanone is then terminated and the dehydrogenation catalyst is contacted with an inert gas and/or hydrogen at a temperature of at least 300° C. Contact of the dehydrogenation catalyst with additional cyclohexanone is subsequently reestablished.
摘要翻译： 在环己酮脱氢生产苯酚的方法中，环己酮在脱氢条件下在反应区与脱氢催化剂接触，脱氢催化剂包括（i）包含二氧化硅的载体; 和（ii）包含选自元素周期表第10族的至少一种金属的脱氢组分。 然后终止脱氢催化剂与环己酮的接触，脱氢催化剂在至少300℃的温度下与惰性气体和/或氢气接触。随后重新建立脱氢催化剂与另外的环己酮的接触。
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公开(公告)号：US20140323782A1
公开(公告)日：2014-10-30
申请号：US14006338
申请日：2011-12-02
申请人： Tan-Jen Chen , Jihad Mohammed Dakka , Terry Eugene Helton , Francisco Manuel Benitez , Charles Morris Smith , Lorenzo Cophard DeCaul
发明人： Tan-Jen Chen , Jihad Mohammed Dakka , Terry Eugene Helton , Francisco Manuel Benitez , Charles Morris Smith , Lorenzo Cophard DeCaul
IPC分类号： C07C5/367
CPC分类号： C07C5/367 , C07C5/325 , C07C2523/14 , C07C2523/42 , C07C2523/62 , C07C13/20
摘要： Disclosed herein is a process for dehydrogenating a saturated cyclic hydrocarbon and/or 5-membered ring compound with a dehydrogenation catalyst. The dehydrogenation catalyst comprises: (i) 0.05 wt % to 5 wt % of a metal selected from Group 14 of the Periodic Table of Elements; and (ii) 0.1 wt % to 10 wt % of a metal selected from Groups 6 to 10 of the Periodic Table of Elements. The process is conducted under dehydrogenation conditions effective to dehydrogenate at least a portion saturated cyclic hydrocarbon and/or 5-membered ring compound.
摘要翻译： 本文公开了一种使用脱氢催化剂使饱和环烃和/或五元环化合物脱氢的方法。 脱氢催化剂包括：（i）0.05重量％至5重量％的选自元素周期表第14族的金属; 和（ii）0.1重量％至10重量％的选自元素周期表第6至10族的金属。 该方法在有效使至少一部分饱和环烃和/或五元环化合物脱氢的脱氢条件下进行。
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