Liquid collector assembly for a reactor
    3.
    发明授权
    Liquid collector assembly for a reactor 失效
    用于反应器的液体收集器组件

    公开(公告)号:US06579502B2

    公开(公告)日:2003-06-17

    申请号:US09280956

    申请日:1999-03-29

    申请人: Luigi Laricchia

    发明人: Luigi Laricchia

    IPC分类号: B01J802

    摘要: A novel liquid collector assembly has been developed for a reactor used in the sweetening of sour hydrocarbons (e.g. sour gasoline). This refinery process normally involves contacting a reaction liquid, comprising both aqueous (caustic solution) and organic (hydrocarbon) phases, with a fixed bed of oxidation catalyst. The collector assembly design, comprising a piping manifold and a plurality of dependent, vertically aligned, and perforated conduits, allows for improved separation of the reaction products into essentially pure treated hydrocarbon and spent alkaline reagent streams. If sodium hydroxide is used as caustic solution, for example, the treated hydrocarbon product will normally contain less than 1 ppm by weight of sodium.

    摘要翻译: 已经开发了用于在酸性碳氢化合物(例如酸性汽油)的脱硫中使用的反应器的新型液体收集器组件。 该炼油工艺通常包括使包含水(苛性碱溶液)和有机(烃)相的反应液与固定床的氧化催化剂接触。 包括管道歧管和多个依赖的,垂直对准的和穿孔的管道的收集器组件设计允许将反应产物改进为基本上纯的经处理的烃和废碱试剂流的分离。 如果使用氢氧化钠作为苛性碱溶液,例如,经处理的烃产物通常含有小于1ppm的钠。

    Hydrocarbon sweetening process using a novel liquid collector assembly
    5.
    发明授权
    Hydrocarbon sweetening process using a novel liquid collector assembly 失效
    使用新型液体收集器组件的碳氢化合物脱硫工艺

    公开(公告)号:US06338792B1

    公开(公告)日:2002-01-15

    申请号:US09557995

    申请日:2000-04-24

    申请人: Luigi Laricchia

    发明人: Luigi Laricchia

    IPC分类号: E10G2700

    摘要: A novel liquid collector assembly has been developed for a reactor used in the sweetening of sour hydrocarbons (e.g. sour gasoline). This refinery process normally involves contacting a reaction liquid, comprising both aqueous (caustic solution) and organic (hydrocarbon) phases, with a fixed bed of oxidation catalyst. The collector assembly design, comprising a piping manifold and a plurality of dependent, vertically aligned, and perforated conduits, allows for improved separation of the reaction products into essentially pure treated hydrocarbon and spent alkaline reagent streams. If sodium hydroxide is used as caustic solution, for example, the treated hydrocarbon product will normally contain less than 1 ppm by weight of sodium.

    摘要翻译: 已经开发了用于在酸性碳氢化合物(例如酸性汽油)的脱硫中使用的反应器的新型液体收集器组件。 该炼油工艺通常包括使包含水(苛性碱溶液)和有机(烃)相的反应液与固定床的氧化催化剂接触。 包括管道歧管和多个依赖的,垂直对准的和穿孔的管道的收集器组件设计允许将反应产物改进为基本上纯的经处理的烃和废碱试剂流的分离。 如果使用氢氧化钠作为苛性碱溶液,例如,经处理的烃产物通常含有小于1ppm的钠。

    Removal of sulfur compounds from gaseous waste streams
    8.
    发明授权
    Removal of sulfur compounds from gaseous waste streams 有权
    从气体废物流中除去硫化合物

    公开(公告)号:US06217839B1

    公开(公告)日:2001-04-17

    申请号:US09377409

    申请日:1999-08-20

    IPC分类号: B01D5348

    CPC分类号: B01D53/1456 B01D53/73

    摘要: Sulfur dioxide and other sulfur compounds are removed from various waste gas streams including those from incineration, refinery sulfur processing, coal burning, or metal smelting operations. The process for sulfur compound removal comprises, in an adsorption vessel, the quenching and subsequent adsorption of the gas with a suitable adsorbent such as an aqueous basic solution (e.g. sodium hydroxide). Sulfur compounds are thus adsorbed into a liquid scrubbing solution predominantly in the form of partially oxidized species (i.e. sulfites, bisulfites, thiosulfites, sulfides, and bisulfides). In a separate heterogeneous catalytic oxidation step, these partially oxidized sulfur compounds are more completely oxidized so that the chemical oxygen demand of the effluent from the oxidation reactor is substantially reduced.

    摘要翻译: 从各种废气流中除去二氧化硫和其他硫化合物,包括来自焚烧,炼厂硫磺加工,燃煤或金属冶炼操作的废气流。 硫化合物去除的方法包括在吸附容器中,用合适的吸附剂如碱性水溶液(如氢氧化钠)进行淬火和随后的气体吸附。 因此,硫化合物被吸附到主要以部分氧化物质(即亚硫酸盐,亚硫酸氢盐,硫代亚硫酸盐,硫化物和二硫化物)形式的液体洗涤溶液中。 在单独的非均相催化氧化步骤中,这些部分氧化的硫化合物被更完全氧化,使得来自氧化反应器的流出物的化学需氧量显着降低。