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公开(公告)号：US07893170B2
公开(公告)日：2011-02-22
申请号：US11579551
申请日：2005-04-25
IPC分类号： C08F283/12 , C08G77/16 , C08G77/18 , C08G77/08
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译： 提供了通过使用非有机锡催化剂具有良好固化性和粘合性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种 ，（C）含有可水解硅基且分子量为100〜1000的低分子量化合物，其特征在于钛原子，铝原子和锆的总摩尔数（a）的比（a / b） 组分（B）的原子与组分（c）的硅原子的总摩尔数（b）大于0.08。
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公开(公告)号：US20080194773A1
公开(公告)日：2008-08-14
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08F20/06 , C08F283/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好粘附性的可固化组合物。 [解决问题的方法]固化性组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆的一种或多种 催化剂，其特征在于，当通过加入和混合1.5份辛酸锡，0.25重量份月桂胺和0.6重量份纯水测定时，50％张力下的应力在0.01MPa至0.20MPa的范围内 至100重量份的组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中以不混合气泡，将混合物在23℃下老化1小时，进一步在70℃ ℃下冲洗20小时，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min） 。
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公开(公告)号：US07910681B2
公开(公告)日：2011-03-22
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08G77/08 , C08G77/46 , C08G77/48 , C08L83/14 , C08F283/06
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good adhesion by using a non-organotin catalyst.The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： 通过使用非有机锡催化剂提供具有良好粘附性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，其特征在于 在50％张力下的应力在0.01MPa至0.20MPa的范围内，当通过将1.5份辛酸锡，0.25重量份的月桂胺和0.6重量份的纯水加入并混合到100重量份的 组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中，不混合气泡，将混合物在23℃下老化1小时，再在70℃下老化20小时 ，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min）。
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公开(公告)号：US20080076878A1
公开(公告)日：2008-03-27
申请号：US11579551
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好的固化性和粘合性的固化性组合物。 [解决问题的方法]可固化组合物包含（A）具有通过形成硅氧烷键而能够交联的具有反应性硅基团的含硅基团的有机聚合物，（B）选自钛催化剂， 铝催化剂和锆催化剂，和（C）含有可水解硅基并且分子量为100〜1000的低分子量化合物，其特征在于钛的总摩尔（a）的比（a / b） 组分（B）的原子，铝原子和锆原子与组分（c）的硅原子的总摩尔数（b）大于0.08。
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