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公开(公告)号：US07893170B2
公开(公告)日：2011-02-22
申请号：US11579551
申请日：2005-04-25
IPC分类号： C08F283/12 , C08G77/16 , C08G77/18 , C08G77/08
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译： 提供了通过使用非有机锡催化剂具有良好固化性和粘合性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种 ，（C）含有可水解硅基且分子量为100〜1000的低分子量化合物，其特征在于钛原子，铝原子和锆的总摩尔数（a）的比（a / b） 组分（B）的原子与组分（c）的硅原子的总摩尔数（b）大于0.08。
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公开(公告)号：US20080194773A1
公开(公告)日：2008-08-14
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08F20/06 , C08F283/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好粘附性的可固化组合物。 [解决问题的方法]固化性组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆的一种或多种 催化剂，其特征在于，当通过加入和混合1.5份辛酸锡，0.25重量份月桂胺和0.6重量份纯水测定时，50％张力下的应力在0.01MPa至0.20MPa的范围内 至100重量份的组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中以不混合气泡，将混合物在23℃下老化1小时，进一步在70℃ ℃下冲洗20小时，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min） 。
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公开(公告)号：US07910681B2
公开(公告)日：2011-03-22
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08G77/08 , C08G77/46 , C08G77/48 , C08L83/14 , C08F283/06
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good adhesion by using a non-organotin catalyst.The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： 通过使用非有机锡催化剂提供具有良好粘附性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，其特征在于 在50％张力下的应力在0.01MPa至0.20MPa的范围内，当通过将1.5份辛酸锡，0.25重量份的月桂胺和0.6重量份的纯水加入并混合到100重量份的 组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中，不混合气泡，将混合物在23℃下老化1小时，再在70℃下老化20小时 ，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min）。
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公开(公告)号：US20080076878A1
公开(公告)日：2008-03-27
申请号：US11579551
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好的固化性和粘合性的固化性组合物。 [解决问题的方法]可固化组合物包含（A）具有通过形成硅氧烷键而能够交联的具有反应性硅基团的含硅基团的有机聚合物，（B）选自钛催化剂， 铝催化剂和锆催化剂，和（C）含有可水解硅基并且分子量为100〜1000的低分子量化合物，其特征在于钛的总摩尔（a）的比（a / b） 组分（B）的原子，铝原子和锆原子与组分（c）的硅原子的总摩尔数（b）大于0.08。
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公开(公告)号：US20080269405A1
公开(公告)日：2008-10-30
申请号：US11547030
申请日：2005-03-18
IPC分类号： C08L83/04
CPC分类号： C08K5/0025 , C08K5/098 , C08K5/544 , C08L71/02
摘要： The present invention has its object to provide a one package curable composition which has good adhesion while containing an organotin-free catalyst.The present invention provides a one package curable composition which comprises (A) an organic polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a carboxylic acid metal salt (b1) and/or a carboxylic acid (b2), (C) a filler, and (D) an amino group-containing silane coupling agent: and has the total amount of carbonyl group composing an acid group in the component (B) per 100 g of the component (A) of 12 mmol or lower; contains substantially no organotin compound; and has the water content of 2,000 ppm or lower.
摘要翻译： 本发明的目的是提供一种包含无机锡催化剂的粘合性良好的一包装可固化组合物。 本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）羧酸金属盐（b1）和/或羧酸（ b2），（C）填料和（D）含氨基的硅烷偶联剂，并且组合物（B）中的每100克组分（A）中构成酸基的羰基的总量为 12 mmol或更低; 基本上不含有机锡化合物; 水含量为2000ppm以下。
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公开(公告)号：US07625990B2
公开(公告)日：2009-12-01
申请号：US11579630
申请日：2005-04-25
IPC分类号： C08G77/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： A curable composition having good curability and adhesion comprising: (A) an reactive silicon group-containing organic polymer, (B) a titanium chelate represented by the general formula (1) or (2) and (C) a high molecular weight plasticizer having a number average molecular weight of 1,000 to 15,000. General formula (1): wherein each of n R1s is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2s is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1s and (4-n) A2s is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2 or 3. General formula (2): wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group having 1 to 20 carbon atoms.
摘要翻译： 具有良好固化性和粘合性的可固化组合物包含：（A）含反应性硅基的有机聚合物，（B）由通式（1）或（2）表示的钛螯合物和（C）具有高分子量增塑剂 数均分子量为1,000〜15,000。 通式（1）：其中，n个R 1各自独立地为取代或未取代的碳原子数1〜20的烃基，（4-n）R 2各自独立地为氢原子或取代或未取代的碳原子数1〜20的烃基 （4-n）A1和（4-n）A2中的每一个独立地为-R 3或-OR 3，其中R 3为取代或未取代的具有1至20个碳原子的烃基，n为1,2或3.通式 （2）：其中R2，A1和A2与上述定义相同，R4为取代或未取代的碳原子数1〜20的二价烃基。
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公开(公告)号：US20080021140A1
公开(公告)日：2008-01-24
申请号：US11547027
申请日：2005-03-18
IPC分类号： C08L101/10 , C08K5/09 , C08L71/02 , C08K5/47
CPC分类号： C08G65/336 , C08K5/09 , C08K5/44 , C08L71/02 , C08L101/10 , C08L2205/02 , C08L2666/02 , C08L2666/14
摘要： The present invention has its object to provide a curable composition having good curability and capable of keeping a curability and mechanical strength even after storage by using a substantially metal-free curing catalyst. The present invention provides a curable composition which comprises (A) an organic polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and (C) a polymer plasticizer.
摘要翻译： 本发明的目的是提供一种具有良好固化性的固化性组合物，即使在使用基本上无金属的固化催化剂进行保存后也能够保持固化性和机械强度。 本发明提供一种可固化组合物，其包含（A）具有通过形成硅氧烷键而能够交联的含硅基团的有机聚合物，（B）与羰基相邻的碳原子为季碳的羧酸 ，（C）聚合物增塑剂。
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公开(公告)号：US20070287780A1
公开(公告)日：2007-12-13
申请号：US11579635
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having satisfactory curability and adhesion by use of a non-tin curing catalyst, and minimizing lowering of mechanical properties of a cured article obtained after storing. [Means to Solve] A one-component type curable composition comprising (A) a polyoxyalkylene polymer (a1) having a silicon-containing group being capable of crosslinking by forming siloxane bonds and/or a (meth)acrylate polymer (a2) having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) a chelate type methyl titanate (b1) and/or a chelate type ethyl titanate (b2), and (C) a compound having, in its molecule, a hydrolyzable silicon group and a nitrogen-substituted group.
摘要翻译： [问题]提供了通过使用非锡固化催化剂具有令人满意的固化性和粘合性的可固化组合物，并且使储存后获得的固化物的机械性能降至最低。 [解决方法]一种单组分型可固化组合物，其包含（A）具有能够通过形成硅氧烷键而交联的含硅基团的聚氧化烯聚合物（a1）和/或具有（甲基）丙烯酸酯聚合物 含硅基团能够通过形成硅氧烷键交联，（B）螯合型甲基钛酸酯（b1）和/或螯合型钛酸乙酯（b2），和（C）在其分子中具有可水解的 硅基和氮取代基。
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公开(公告)号：US20080287636A1
公开(公告)日：2008-11-20
申请号：US11579630
申请日：2005-04-25
IPC分类号： C08G77/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [PROBLEMS] There is provided a curable composition having good curability and adhesiveness. [MEANS FOR SOLVING] A curable composition by comprising (A) an reactive silicon group-containing organic polymer,(B) a titanium chelate represented by the general formula (1) or (2),(C) a high molecular weight plasticizer having a number average molecular weight of 1000 to 15000:General Formula (1): wherein each of n R1's is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2's is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1's and (4-n) A2's is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2, or 3. General Formula wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group havimg 1 to 20 carbon atoms.
摘要翻译： [问题]提供了具有良好的固化性和粘合性的固化性组合物。 [解决方案]一种可固化组合物，其包含（A）含反应性硅基的有机聚合物，（B）由通式（1）或（2）表示的钛螯合物，（C）具有 数均分子量为1000〜15000：通式（1）：其中n R 1各自独立地为取代或未取代的碳原子数1〜20的烃基，（4 -n）R 2独立地为氢原子或取代或未取代的碳原子数1〜20的烃基，（4-n）A 1〜 和（4-n）A 2独立地为-R 3或-OR 3，其中R 3为 是具有1至20个碳原子的取代或未取代的烃基，n为1,2或3.其中R 2，A 1和A 2的通式为 2 与上述定义相同，R 4是取代或未取代的2至20碳a的二价烃基 手铐
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公开(公告)号：US20070203297A1
公开(公告)日：2007-08-30
申请号：US11547028
申请日：2005-03-18
IPC分类号： C08L71/02
CPC分类号： C08F293/005 , C08K5/09 , C08L43/04 , C08L53/00 , C08L71/02 , C09D153/00 , C08L83/12 , C08L2666/22 , C08L2666/02
摘要： The present invention has its object to provide a curable composition which has good curability and adhesiveness while containing an organotin-free catalyst. The present invention provides a one package curable composition which comprises (A) a polyoxyalkylene polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a (meth)acrylic ester polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond and compatible with the component (A), and (C) (c1) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and/or (c2) a metal carboxylate of which the carbon atom adjacent to a carbonyl group is a quaternary carbon.
摘要翻译： 本发明的目的是提供一种含有无机锡催化剂的固化性和粘合性优异的固化性组合物。 本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的聚氧化烯聚合物，（B）具有含硅基团的（甲基）丙烯酸酯聚合物， 通过形成硅氧烷键并与组分（A）相容的交联，和（C）（c1）与羰基相邻的碳原子为季碳的羧酸和/或（c2）羧酸金属的 其中与羰基相邻的碳原子是季碳。
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