SOLVENT SYSTEM
    2.
    发明申请
    SOLVENT SYSTEM 审中-公开
    溶剂系统

    公开(公告)号:US20100043876A1

    公开(公告)日:2010-02-25

    申请号:US12541500

    申请日:2009-08-14

    CPC classification number: H01L51/0007 H01L51/0036 H01L51/4253 Y02E10/549

    Abstract: Improved organic photovoltaic cells including a composition useful for forming an active layer which comprises (a) at least one p-type material, (b) at least one n-type material, (c) at least one first solvent and (d) at least one second solvent, wherein the first solvent is different from the second solvent, and the first solvent comprises at least one alkylbenzene or benzocyclohexane, and the second solvent comprises at least one carbocyclic compound. The second solvent can be used in lesser amounts but can improve efficiency in cells.

    Abstract translation: 改进的有机光伏电池包括可用于形成活性层的组合物,其包含(a)至少一种p型材料,(b)至少一种n型材料,(c)至少一种第一溶剂和(d) 至少一个第二溶剂,其中第一溶剂不同于第二溶剂,第一溶剂包含至少一种烷基苯或苯并环己烷,第二溶剂包括至少一种碳环化合物。 第二溶剂可以以较少量使用,但可以提高细胞的效率。

    Solvent-free method for preparing sterically hindered phosphoramidates
    3.
    发明授权
    Solvent-free method for preparing sterically hindered phosphoramidates 有权
    制备空间位阻氨基磷酸酯的无溶剂方法

    公开(公告)号:US06277988B1

    公开(公告)日:2001-08-21

    申请号:US09515801

    申请日:2000-02-29

    CPC classification number: C07F9/2458 C07F9/650952 C07F9/6521

    Abstract: Sterically hindered phosphoramidates such as N,N′-bis[di-(2,6-xylenoxy)phosphinyl]piperazine are prepared by the reaction of a sterically hindered diaryl chlorophosphate, such as di-(2,6-xylyl) chlorophosphate, with a basic nitrogen compound containing at least two basic N—H groups, preferably a heterocyclic compound such as piperazine, in a predominantly liquid, solvent-free reaction mixture. The reaction may be conducted in the melt or in the presence of a non-solvent carrier, typically an aliphatic hydrocarbon. An excess of the basic nitrogen compound is employed as an acid acceptor.

    Abstract translation: 通过空间位阻的氯化磷酸二芳基酯如氯代磷酸二(2,6-二甲苯基)酯与二(2,6-二甲苯基)氧膦基]哌嗪的反应制备了N,N'-双[二 - (2,6-二甲苯氧基) 在主要是液体,无溶剂的反应混合物中含有至少两个碱性NH基团,优选杂环化合物如哌嗪的碱性氮化合物。 反应可以在熔体中或在非溶剂载体(通常为脂族烃)的存在下进行。 使用过量的碱性氮化合物作为酸受体。

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