Production of hydrogen, acetylene and ammonia gases from lithium
reaction with hydrocarbon materials
    1.
    发明授权
    Production of hydrogen, acetylene and ammonia gases from lithium reaction with hydrocarbon materials 失效
    从碳氢化合物材料的锂反应生产氢气,乙炔和氨气

    公开(公告)号:US4317659A

    公开(公告)日:1982-03-02

    申请号:US114879

    申请日:1980-01-24

    申请人: Michael G. Down

    发明人: Michael G. Down

    摘要: A method of producing H.sub.2 and C.sub.2 H.sub.2 gases comprises the steps of drying a hydrocarbon biomass material to remove water without carbonization, reacting the dried hydrocarbon biomass with a stoichiometric excess of molten lithium metal to produce lithium salts comprising LiH and Li.sub.2 C.sub.2 and then hydrolyzing the lithium salts to produce a gaseous mixture comprising H.sub.2 and C.sub.2 H.sub.2.

    摘要翻译: 一种生产H2和C2H2气体的方法包括以下步骤:干燥烃生物质材料以除去水而不进行碳化,使干燥的烃生物质与化学计量过量的熔融锂金属反应,生成包含LiH和Li2C2的锂盐,然后水解锂盐 以产生包含H 2和C 2 H 2的气体混合物。

    Metal powders and processes for production from oxides
    3.
    发明授权
    Metal powders and processes for production from oxides 失效
    金属粉末和氧化物生产方法

    公开(公告)号:US4519837A

    公开(公告)日:1985-05-28

    申请号:US604398

    申请日:1984-04-26

    申请人: Michael G. Down

    发明人: Michael G. Down

    摘要: Method of forming metal powders from the liquid metal reduction of metal oxides are described. The methods described include the steps of low temperature liquid metal reduction of the oxide, agitation of the reduction reaction mixture and/or distillation of excess reductant upon completion of the reduction step. These steps are designed to limit agglomeration and enhance the purity of the final powder produced. Metal powder produced in accordance with this invention has a basic particle size of 0.1 to 0.5 microns.

    摘要翻译: 描述了从金属氧化物的液态金属还原形成金属粉末的方法。 所述方法包括在还原步骤完成时低温液态金属还原氧化物的步骤,还原反应混合物的搅拌和/或过量还原剂的蒸馏。 这些步骤旨在限制附聚并提高所生产的最终粉末的纯度。 根据本发明生产的金属粉末具有0.1至0.5微米的基本粒度。

    System for the production of ketene and methylene from carbonate minerals
    4.
    发明授权
    System for the production of ketene and methylene from carbonate minerals 失效
    用于从碳酸盐矿物生产乙烯酮和亚甲基的体系

    公开(公告)号:US4434133A

    公开(公告)日:1984-02-28

    申请号:US266671

    申请日:1981-05-26

    摘要: Organic hydrocarbon materials are produced from plentiful inorganic limestone type materials by: (1) reacting the limestone type materials with molten lithium metal to produce Li.sub.2 C.sub.2 (2) hydrolyzing the Li.sub.2 C.sub.2 to produce C.sub.2 H.sub.2, (3) catalytically reacting the C.sub.2 H.sub.2 with steam to produce CH.sub.3 COCH.sub.3, (4) pyrolyzing the CH.sub.3 COCH.sub.3 to provide ketene and methane, and separating the ketene. The ketene may then be decomposed to provide methylene, which can be reacted with an alkane, such as methane in an insertion chain reaction, to provide organic hydrocarbon materials. An in-place nuclear reactor can provide energy for the endothermic reactions of the system.

    摘要翻译: 有机碳氢化合物材料是由丰富的无机石灰石型材料制成的:(1)使石灰石型材料与熔融的锂金属反应生成Li2C2 + L,(2)水解Li2C2以产生C2H2,(3)使C2H2与蒸汽催化反应 产生CH 3 COCH 3,(4)热解CH 3 COCH 3以提供烯酮和甲烷,并分离乙烯酮。 然后可以将乙烯酮分解以提供亚甲基,其可以在插入链反应中与烷烃如甲烷反应,以提供有机烃材料。 原位核反应堆可为系统的吸热反应提供能量。

    System for the production of ketene and methylene from limestone
utilizing a solid electrolyte electrolysis cell
    5.
    发明授权
    System for the production of ketene and methylene from limestone utilizing a solid electrolyte electrolysis cell 失效
    利用固体电解质电解池从石灰石生产乙烯酮和亚甲基的体系

    公开(公告)号:US4428905A

    公开(公告)日:1984-01-31

    申请号:US266672

    申请日:1981-05-22

    摘要: Organic hydrocarbon materials are produced from plentiful inorganic limestone type materials by: (1) thermally decomposing the limestone type materials to produce CaO and CO.sub.2, (2) using the CO.sub.2 in a solid electrolyte electrolysis cell to produce CO, (3) catalytically decomposing the CO to produce carbon, (4) reacting the carbon with the CaO produced in step (1), to produce CaC.sub.2, (5) hydrolyzing the CaC.sub.2 toi produce C.sub.2 H.sub.2, (6) catalytically reacting the C.sub.2 H.sub.2 with steam to produce CH.sub.3 COCH.sub.3, (7) pyrolyzing the CH.sub.3 COCH.sub.3 to provide ketene and methane, and separating the ketene. The ketene may then be decomposed to provide methylene, which can be reacted with an alkane, such as methane in an insertion chain reaction, to provide organic hydrocarbon materials. An in-place nuclear reactor can provide energy for the endothermic reactions of the system.

    摘要翻译: 有机碳氢化合物材料是由丰富的无机石灰石型材料生产的:(1)将石灰石型材料热分解生成CaO和CO2,(2)使用固体电解质电解槽中的CO2制备CO,(3)催化分解 CO,以产生碳,(4)使碳与步骤(1)中生产的CaO反应,生成CaC 2,(5)水解CaCl 2以产生C 2 H 2,(6)使C 2 H 2与蒸汽催化反应以产生CH 3 COCH 3(7 )热解CH 3 COCH 3以提供烯酮和甲烷,并分离乙烯酮。 然后可以将乙烯酮分解以提供亚甲基,其可以在插入链反应中与烷烃如甲烷反应,以提供有机烃材料。 原位核反应堆可为系统的吸热反应提供能量。

    Titanium product collection in a plasma reactor
    6.
    发明授权
    Titanium product collection in a plasma reactor 失效
    钛产品在等离子体反应堆中收集

    公开(公告)号:US4356029A

    公开(公告)日:1982-10-26

    申请号:US333838

    申请日:1981-12-23

    摘要: A method for producing a metal by reduction of a metal halide characterized by the steps of feeding into a plasma such as the arc heated stream of an arc heater, a quantity of a reducing metal such as an alkali or alkaline earth metal, feeding into the plasma a quantity of a metal halide, maintaining the temperature of the reaction chamber wall higher than the vapor point of the alkali metal chloride formed or alkaline earth metal chloride formed but lower than the melting point of the elemental metal, co-products formed being an elemental metal and a gaseous salt, projecting the co-products into the reaction chamber to cause the metal to deposit on the interior wall of the collection chamber, removing the gaseous salt, heating the metal deposited on the interior of the reaction chamber with the arc heated stream thereby causing the elemental metal to fall gravitationally or be blown into an associated receptacle in the form of solidified globules and/or crystals and/or granules and/or large diameter powders.

    摘要翻译: 一种通过还原金属卤化物制造金属的方法,其特征在于,将供给电弧加热器的电弧加热流,一定量的还原金属如碱金属或碱土金属的等离子体供给到 等离子体一定量的金属卤化物,保持反应室壁的温度高于形成的碱金属氯化物的蒸气点或形成的碱土金属氯化物,但低于元素金属的熔点,形成的副产物为 元素金属和气态盐,将共同产品投射到反应室中以使金属沉积在收集室的内壁上,除去气态盐,用沉积在反应室内部的金属加热弧 加热的流,从而导致元素金属重力下落或以固化的小球和/或晶体和/或颗粒的形式吹入相关的容器中和/或 大直径粉末。

    Hydrogen meter for liquid lithium
    7.
    发明授权
    Hydrogen meter for liquid lithium 失效
    液态锂氢表

    公开(公告)号:US4255963A

    公开(公告)日:1981-03-17

    申请号:US11831

    申请日:1979-02-13

    申请人: Michael G. Down

    发明人: Michael G. Down

    IPC分类号: G01N7/10

    CPC分类号: G01N7/10

    摘要: A niobium or vanadium membrane, which resists lithium corrosion and exhibits significant hydrogen permeation at temperatures of about 500.degree. C. or higher, is employed in a membrane/meter device for measuring the hydrogen in a lithium/hydrogen solution.

    摘要翻译: 在用于测量锂/氢溶液中的氢的膜/仪表装置中使用了铌或钒膜,其耐受锂腐蚀并在约500℃或更高的温度下显示出显着的氢渗透。