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    System for the production of ketene and methylene from carbonate minerals
    1.
    发明授权
    System for the production of ketene and methylene from carbonate minerals 失效
    用于从碳酸盐矿物生产乙烯酮和亚甲基的体系

    公开(公告)号：US4434133A

    公开(公告)日：1984-02-28

    申请号：US266671

    申请日：1981-05-26

    申请人： Michael G. Down ,  D. Colin Phillips ,  Werner S. Emmerich

    发明人： Michael G. Down ,  D. Colin Phillips ,  Werner S. Emmerich

    IPC分类号： C07C1/207 ,  C07C9/04 ,  C07C45/26 ,  C07C45/88 ,  G21C15/00

    CPC分类号： C07C45/26 ,  C07C1/2076 ,  C07C45/88 ,  C07C9/04

    摘要： Organic hydrocarbon materials are produced from plentiful inorganic limestone type materials by: (1) reacting the limestone type materials with molten lithium metal to produce Li.sub.2 C.sub.2 (2) hydrolyzing the Li.sub.2 C.sub.2 to produce C.sub.2 H.sub.2, (3) catalytically reacting the C.sub.2 H.sub.2 with steam to produce CH.sub.3 COCH.sub.3, (4) pyrolyzing the CH.sub.3 COCH.sub.3 to provide ketene and methane, and separating the ketene. The ketene may then be decomposed to provide methylene, which can be reacted with an alkane, such as methane in an insertion chain reaction, to provide organic hydrocarbon materials. An in-place nuclear reactor can provide energy for the endothermic reactions of the system.

    摘要翻译： 有机碳氢化合物材料是由丰富的无机石灰石型材料制成的：（1）使石灰石型材料与熔融的锂金属反应生成Li2C2 + L，（2）水解Li2C2以产生C2H2，（3）使C2H2与蒸汽催化反应 产生CH 3 COCH 3，（4）热解CH 3 COCH 3以提供烯酮和甲烷，并分离乙烯酮。 然后可以将乙烯酮分解以提供亚甲基，其可以在插入链反应中与烷烃如甲烷反应，以提供有机烃材料。 原位核反应堆可为系统的吸热反应提供能量。

    System for the production of ketene and methylene from limestone utilizing a solid electrolyte electrolysis cell
    2.
    发明授权
    System for the production of ketene and methylene from limestone utilizing a solid electrolyte electrolysis cell 失效
    利用固体电解质电解池从石灰石生产乙烯酮和亚甲基的体系

    公开(公告)号：US4428905A

    公开(公告)日：1984-01-31

    申请号：US266672

    申请日：1981-05-22

    申请人： D. Colin Phillips ,  Werner S. Emmerich ,  Arnold O. Isenberg ,  Michael G. Down

    发明人： D. Colin Phillips ,  Werner S. Emmerich ,  Arnold O. Isenberg ,  Michael G. Down

    IPC分类号： C07C1/207 ,  C07C9/04 ,  C07C45/26 ,  C07C45/88 ,  G21D9/00 ,  G21C15/00

    CPC分类号： G21D9/00 ,  C07C1/2076 ,  C07C45/26 ,  C07C45/88 ,  C07C9/04

    摘要： Organic hydrocarbon materials are produced from plentiful inorganic limestone type materials by: (1) thermally decomposing the limestone type materials to produce CaO and CO.sub.2, (2) using the CO.sub.2 in a solid electrolyte electrolysis cell to produce CO, (3) catalytically decomposing the CO to produce carbon, (4) reacting the carbon with the CaO produced in step (1), to produce CaC.sub.2, (5) hydrolyzing the CaC.sub.2 toi produce C.sub.2 H.sub.2, (6) catalytically reacting the C.sub.2 H.sub.2 with steam to produce CH.sub.3 COCH.sub.3, (7) pyrolyzing the CH.sub.3 COCH.sub.3 to provide ketene and methane, and separating the ketene. The ketene may then be decomposed to provide methylene, which can be reacted with an alkane, such as methane in an insertion chain reaction, to provide organic hydrocarbon materials. An in-place nuclear reactor can provide energy for the endothermic reactions of the system.

    摘要翻译： 有机碳氢化合物材料是由丰富的无机石灰石型材料生产的：（1）将石灰石型材料热分解生成CaO和CO2，（2）使用固体电解质电解槽中的CO2制备CO，（3）催化分解 CO，以产生碳，（4）使碳与步骤（1）中生产的CaO反应，生成CaC 2，（5）水解CaCl 2以产生C 2 H 2，（6）使C 2 H 2与蒸汽催化反应以产生CH 3 COCH 3（7 ）热解CH 3 COCH 3以提供烯酮和甲烷，并分离乙烯酮。 然后可以将乙烯酮分解以提供亚甲基，其可以在插入链反应中与烷烃如甲烷反应，以提供有机烃材料。 原位核反应堆可为系统的吸热反应提供能量。