公开(公告)号：US08062992B2

公开(公告)日：2011-11-22

申请号：US12598687

申请日：2008-05-05

申请人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

发明人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： C10G2/30 ,  B01J21/12 ,  B01J23/75 ,  B01J23/8913 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/18 ,  C10G2300/703

摘要： A process for producing a supported cobalt-based Fischer-Tropsch synthesis catalyst includes, in a first activation stage, treating a particulate catalyst precursor with a reducing gas, at a heating rate, HR1, until the precursor has reached a temperature, T1, where 80° C.≦T1≦180° C., to obtain a partially treated precursor. In a second activation stage, the partially treated precursor is treated with a reducing gas, at a heating rate, HR2, where 0≦HR2 HR2 until the partially reduced precursor reaches a temperature, T2. The partially reduced precursor is maintained at T2 for a time, t2, where t2 is from 0 to 20 hours, to obtain an activated catalyst.

摘要翻译： 负载型钴基费 - 托合成催化剂的制备方法包括在第一活化阶段中，用还原气体以加热速率HR1处理颗粒状催化剂前体，直到前体达到温度T1，其中 80℃和nlE; T1＆nlE; 180℃，以获得部分处理的前体。 在第二活化阶段，用还原气体处理部分处理的前体，加热速率为HR2，其中0≤n1E; HR2 HR2直到部分还原的前体达到温度T2。 将部分还原的前体保持在T2一段时间t2，其中t2为0至20小时，以获得活化的催化剂。

公开(公告)号：US08067333B2

公开(公告)日：2011-11-29

申请号：US12598742

申请日：2008-05-05

申请人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

发明人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

IPC分类号： B01J23/00 ,  B01J21/00 ,  B01J20/00

CPC分类号： C10G2/30 ,  B01J21/12 ,  B01J23/75 ,  B01J23/8913 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/18 ,  C10G2300/703

摘要： A process for producing a supported cobalt-based Fischer-Tropsch synthesis catalyst includes, in a first activation stage, treating a particulate catalyst precursor with a reducing gas, at a heating rate, HR1, until the precursor has reached a temperature, T1, where 80° C.≦T1≦180° C., to obtain a partially treated precursor. In a second activation stage, the partially treated precursor is treated with a reducing gas, at an average heating rate, HR2, with x step increments, where 0 HR2 until the partially reduced precursor reaches a temperature, T2. The partially reduced precursor is maintained at T2 for a time, t2, where t2 is from 0 to 20 hours, to obtain an activated catalyst.

摘要翻译： 负载型钴基费 - 托合成催化剂的制备方法包括在第一活化阶段中，用还原气体以加热速率HR1处理颗粒状催化剂前体，直到前体达到温度T1，其中 80℃和nlE; T1＆nlE; 180℃，以获得部分处理的前体。 在第二活化阶段，用还原气体处理部分处理的前体，平均加热速率为HR2，其中0 HR2直到部分还原的前体达到温度T2。 将部分还原的前体保持在T2一段时间t2，其中t2为0至20小时，以获得活化的催化剂。

公开(公告)号：US20100144520A1

公开(公告)日：2010-06-10

申请号：US12598742

申请日：2008-05-05

申请人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

发明人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

IPC分类号： B01J23/75

CPC分类号： C10G2/30 ,  B01J21/12 ,  B01J23/75 ,  B01J23/8913 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/18 ,  C10G2300/703

摘要： A process for producing a supported cobalt-based Fischer-Tropsch synthesis catalyst includes, in a first activation stage, treating a particulate catalyst precursor with a reducing gas, at a heating rate, HR1, until the precursor has reached a temperature, T1, where 80° C.≦T1≦180° C., to obtain a partially treated precursor. In a second activation stage, the partially treated precursor is treated with a reducing gas, at an average heating rate, HR2, with x step increments, where 0 HR2 until the partially reduced precursor reaches a temperature, T2. The partially reduced precursor is maintained at T2 for a time, t2, where t2 is from 0 to 20 hours, to obtain an activated catalyst.

摘要翻译： 负载型钴基费 - 托合成催化剂的制备方法包括在第一活化阶段中，用还原气体以加热速率HR1处理颗粒状催化剂前体，直到前体达到温度T1，其中 80℃和nlE; T1＆nlE; 180℃，以获得部分处理的前体。 在第二活化阶段，用还原气体处理部分处理的前体，平均加热速率为HR2，其中0 HR2直到部分还原的前体达到温度T2。 将部分还原的前体保持在T2一段时间t2，其中t2为0至20小时，以获得活化的催化剂。

公开(公告)号：US08394864B2

公开(公告)日：2013-03-12

申请号：US12937491

申请日：2009-04-03

申请人： Jan Van De Loosdrecht ,  Michael Steven Datt ,  Jan Mattheus Botha

发明人： Jan Van De Loosdrecht ,  Michael Steven Datt ,  Jan Mattheus Botha

IPC分类号： C07C1/04 ,  B01J31/04

CPC分类号： B01J23/75 ,  B01J21/12 ,  B01J23/8913 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/08 ,  C10G2/332

摘要： A process for preparing a cobalt based Fischer-Tropsch synthesis catalyst precursor includes introducing a multi-functional carboxylic acid having the general formula (1) HOOC—C*R1C*R2—COOH (1) or a precursor thereof, where C* in each of C*Ri and C*R2 is a sp2 carbon, and R1 and R2 are the same or different, and are each selected from the group consisting of hydrogen and an organic group, into and/or onto a particulate catalyst support. The ratio of the quantity of multifunctional carboxylic acid used relative to the support surface area is at least 0.3 μmol carboxylic acid/m2 of support surface area. Simultaneously with the introduction of the carboxylic acid into and/or onto the catalyst support, or subsequent thereto, a cobalt compound is introduced into and/or onto the catalyst support. The impregnated support is calcined to obtain the cobalt based Fischer-Tropsch synthesis catalyst precursor.

摘要翻译： 一种制备钴基费 - 托合成催化剂前体的方法包括引入具有通式（1）HOOC-C * R1C * R2-COOH（1）或其前体的多官能羧酸，其中C C * R 1和C * R 2是sp 2碳，并且R 1和R 2相同或不同，并且各自选自氢和有机基团，并且在颗粒催化剂载体上和/或之上。 所使用的多官能羧酸的量相对于载体表面积的比例为至少0.3μmol羧酸/ m2的载体表面积。 在将羧酸引入催化剂载体或/或其后的同时，将钴化合物引入催化剂载体和/或催化剂载体上。 将浸渍的载体煅烧以获得基于钴的费 - 托合成催化剂前体。

公开(公告)号：US20110028575A1

公开(公告)日：2011-02-03

申请号：US12937491

申请日：2009-04-03

申请人： Jan Van De Loosdrecht ,  Michael Steven Datt ,  Jan Mattheus Botha

发明人： Jan Van De Loosdrecht ,  Michael Steven Datt ,  Jan Mattheus Botha

IPC分类号： C07C1/04 ,  B01J31/04

CPC分类号： B01J23/75 ,  B01J21/12 ,  B01J23/8913 ,  B01J35/002 ,  B01J35/006 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/08 ,  C10G2/332

摘要： A process for preparing a cobalt based Fischer-Tropsch synthesis catalyst precursor includes introducing a multi-functional carboxylic acid having the general formula (1) HOOC—C*R1C*R2—COOH (1) or a precursor thereof, where C* in each of C*Ri and C*R2 is a sp2 carbon, and R1 and R2 are the same or different, and are each selected from the group consisting of hydrogen and an organic group, into and/or onto a particulate catalyst support. The ratio of the quantity of multifunctional carboxylic acid used relative to the support surface area is at least 0.3 μmol carboxylic acid/m2 of support surface area. Simultaneously with the introduction of the carboxylic acid into and/or onto the catalyst support, or subsequent thereto, a cobalt compound is introduced into and/or onto the catalyst support. The impregnated support is calcined to obtain the cobalt based Fischer-Tropsch synthesis catalyst precursor.

摘要翻译： 一种制备钴基费 - 托合成催化剂前体的方法包括引入具有通式（1）HOOC-C * R1C * R2-COOH（1）或其前体的多官能羧酸，其中C C * R 1和C * R 2是sp 2碳，并且R 1和R 2相同或不同，并且各自选自氢和有机基团，并且在颗粒催化剂载体上和/或之上。 所使用的多官能羧酸的量相对于载体表面积的比例为至少0.3μmol羧酸/ m2的载体表面积。 在将羧酸引入催化剂载体或/或其后的同时，将钴化合物引入催化剂载体和/或催化剂载体上。 将浸渍的载体煅烧以获得基于钴的费 - 托合成催化剂前体。

公开(公告)号：US20100152035A1

公开(公告)日：2010-06-17

申请号：US12598687

申请日：2008-05-05

申请人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

发明人： Jacobus Lucus Visagie ,  Jan Mattheus Botha ,  Johannes Gerhardus Koortzen ,  Michael Steven Datt ,  Alta Bohmer ,  Jan Van De Loosdrecht ,  Abdool Muthalib Saib

IPC分类号： B01J23/75

CPC分类号： C10G2/30 ,  B01J21/12 ,  B01J23/75 ,  B01J23/8913 ,  B01J37/0201 ,  B01J37/08 ,  B01J37/18 ,  C10G2300/703

摘要： A process for producing a supported cobalt-based Fischer-Tropsch synthesis catalyst includes, in a first activation stage, treating a particulate catalyst precursor with a reducing gas, at a heating rate, HR1, until the precursor has reached a temperature, T1, where 80° C.≦T1≦180° C., to obtain a partially treated precursor. In a second activation stage, the partially treated precursor is treated with a reducing gas, at a heating rate, HR2, where 0≦HR2 HR2 until the partially reduced precursor reaches a temperature, T2. The partially reduced precursor is maintained at T2 for a time, t2, where t2 is from 0 to 20 hours, to obtain an activated catalyst.

摘要翻译： 负载型钴基费 - 托合成催化剂的制备方法包括在第一活化阶段中，用还原气体以加热速率HR1处理颗粒状催化剂前体，直到前体达到温度T1，其中 80℃和nlE; T1＆nlE; 180℃，以获得部分处理的前体。 在第二活化阶段，用还原气体处理部分处理的前体，加热速率为HR2，其中0≤n1E; HR2 HR2直到部分还原的前体达到温度T2。 将部分还原的前体保持在T2一段时间t2，其中t2为0至20小时，以获得活化的催化剂。