摘要:
A process for the facile two-step synthesis of methanol from methane is disclosed. In accordance with the invention, an appropriate combination of initiator and reaction medium is employed to achieve methane conversion in very high selectivity and yield under near-ambient temperature.
摘要:
A process for catalytic direct oxidation of hydrocarbons, particularly lower alkanes and single ring aromatics, to acids by dioxygen under mild temperature conditions using specified metal or metal salt catalysts. Turnovers in excess of 1000 for acetic acid formation from ethane and in excess of 100 for formic acid formation from methane have been obtained at reaction temperatures below about 100.degree. C. using palladium catalyst. A coreductant of carbon monoxide in an aqueous system is preferred.
摘要:
A process for the facile two-step synthesis of methanol from methane is disclosed. In accordance with the invention, an appropriate combination of initiator and reaction medium is employed to achieve methane conversion in very high selectivity and yield under near-ambient temperature.
摘要:
Polymer blends having improved electromechanical responses and mechanical properties for use in electromechanical application are disclosed. In particular, polymer blend including at least one electrostrictive terpolymer, e.g., poly(vinylidene fluoride-trifluoroethylene-chlorofluoroethylene) (P(VDF-TrFE-CFE)) or a derivative thereof, and at least one fluoropolymer, e.g., PVDF or derivative thereof such as PVD-TrFE are disclosed. The polymer blends advantageously have a transverse strain, i.e., a strain perpendicular to the applied electric field direction, that is about 1.5% or higher (as measured at 100 MV/m) while also having an elastic modulus of no less than about 400 MPa (as measured at 30° C. and 1 Hz by dynamic mechanical analyzer).
摘要:
A multilayer film useful for capacitive applications comprises a high energy density layer and a dielectric blocking layer. In some embodiments, a conducting film is located between the high energy density layer and the blocking layer. The high energy density layer may be a fluoropolymer, such as a polymer or copolymer of poly-1,1-difluoroethene or a derivative thereof. The multilayer film may have high energy density (for example,. >8 J/cm3) and low dielectric loss, for example less than 2%, and preferably less than 1%.
摘要翻译:用于电容应用的多层膜包括高能量密度层和介电阻挡层。 在一些实施例中,导电膜位于高能量密度层和阻挡层之间。 高能量密度层可以是含氟聚合物,例如聚-1,1-二氟乙烯的聚合物或共聚物或其衍生物。 多层膜可以具有高能量密度(例如> 8J / cm 3)和低介电损耗,例如小于2%,优选小于1%。
摘要:
A process for direct oxidative carbonylation of lower alkanes to acids having one greater carbon atom. The process uses a metal salt catalyst promoted by halide ions and/or a metal with oxygen as the oxidant in an aqueous medium. The process is especially effective for conversion of methane to acetic acid.