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公开(公告)号：US4691053A
公开(公告)日：1987-09-01
申请号：US617187
申请日：1984-06-04
申请人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
发明人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
IPC分类号： B01J31/18 , C07C45/38 , C07C45/34 , C07C45/39 , C07C51/235 , C07C51/255 , C07D307/34 , C07D307/89
CPC分类号： B01J31/1845 , B01J2231/70 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： A novel process for producing oxygen-containing organic compounds with high selectivity and good yield by oxidizing organic compounds under mild conditions is provided, which process comprises using as a catalyst for the oxidation, a complex (M.sub.m X.sub.n.L.sub.l) consisting of a transition metal compound (M.sub.m X.sub.n) and an organic phosphorous compound (L) as a ligand, wherein M represents a transition metal belonging to group I, group IV.about.VII or iron group in group VIII of the periodic table; X represents an anion such as a halogen; ligand L represents an organic phosphorous compound; and m and n mean a number of the atomic valence of said transition metal (ion) M and said anion X, respectively, and l means a number of said ligand.
摘要翻译： 提供了一种通过在温和条件下氧化有机化合物来生产具有高选择性和良好产率的含氧有机化合物的新方法，该方法包括使用由过渡金属化合物组成的络合物（MmXn.Ll） （MmXn）和作为配体的有机磷化合物（L），其中M表示属于元素周期表第I族，第IV族Ⅶ族或第Ⅷ族铁族的过渡金属; X表示阴离子，例如卤素; 配体L表示有机磷化合物; m和n分别表示所述过渡金属（离子）M和所述阴离子X的原子价数，l表示所述配体的数目。
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公开(公告)号：US4620038A
公开(公告)日：1986-10-28
申请号：US706263
申请日：1985-02-27
申请人： Hirotoshi Tanimoto , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Hirotoshi Tanimoto , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Yasuyuki Nishimura , Hiroyuki Kaku
IPC分类号： B01J31/00 , B01J31/16 , B01J31/18 , B01J31/24 , C07B61/00 , C07C45/00 , C07C45/28 , C07C45/30 , C07C45/34 , C07C49/10 , C07C67/00 , C07F15/00
CPC分类号： C07F15/0093 , B01J31/1845 , B01J31/188 , B01J31/24 , C07C45/28 , C07C45/30 , C07C45/34 , C07F15/0066 , B01J2531/16 , B01J2531/46 , B01J2531/56 , B01J2531/824
摘要： A process for producing methyl ethyl ketone selectively and with a high yield by oxygen-oxidizing 1-butene under mild conditions is provided, which process is characterized by using a composite catalyst containing a complex (MmXn.Ll) capable of forming an oxygen complex by coordination of the complex with oxygen and a complex catalyst (M'm'Xn'.L'l') capable of forming a 1-butene complex by coordination of the complex with 1-butene, wherein M represents a specified transition metal such as Cu; X, an anion; L, an organic phosphorus compound as ligand; M', a specified transition metal such as palladium; L', a nitrile, organic fluorine or phosphorus compound as ligand; m, m', n and n', each a number determined by the valences of the transition metals and the anion; l and l', each the number of ligands.
摘要翻译： 提供了在温和条件下通过氧化1-丁烯氧选择性且高收率生产甲基乙基酮的方法，该方法的特征在于使用含有能够形成氧络合物的络合物（MmXn.L1）的复合催化剂， 配合物与氧的配位以及能够通过配合物与1-丁烯配位而形成1-丁烯络合物的复合催化剂（M'''n''L'1'），其中M表示特定的过渡金属，例如 铜 X，阴离子; L，有机磷化合物作为配体; M'，特定的过渡金属如钯; L'，腈，有机氟或磷化合物作为配体; m，m'，n和n'，每个数字由过渡金属和阴离子的化合价决定; l和l'，每个配体数目。
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公开(公告)号：US4521631A
公开(公告)日：1985-06-04
申请号：US620336
申请日：1984-06-13
申请人： Yasuyuki Nishimura , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Takanori Kuwahara , Hirotoshi Tanimoto
发明人： Yasuyuki Nishimura , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Takanori Kuwahara , Hirotoshi Tanimoto
CPC分类号： C07C45/34
摘要： A process for producing acetaldehyde from ethylene under mild reaction conditions, selectively and with high yield is provided, which process comprises preparing a composite catalyst comprising a complex of a transition metal capable of forming an oxygen complex by coordination of oxygen molecule with the metal ion of the transition metal, and a complex of a transition metal capable of forming an ethylene complex by coordination of ethylene with the metal ion of the transition metal, and oxidizing ethylene activated by forming the ethylene complex with the combined oxygen in the oxygen complex, activated by forming the oxygen complex.
摘要翻译： 提供了一种在温和的反应条件下，从温和的反应条件下，以高产率从乙烯中生产乙醛的方法，该方法包括制备复合催化剂，该复合催化剂包括能够通过氧分子与氧分子配位的过渡金属配合物与 过渡金属和能够通过乙烯与过渡金属的金属离子配位形成乙烯络合物的过渡金属的络合物，以及通过与氧络合物中的组合氧形成乙烯络合物来活化乙烯，由 形成氧络合物。
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公开(公告)号：US4605776A
公开(公告)日：1986-08-12
申请号：US694099
申请日：1985-01-23
申请人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
CPC分类号： C07F15/0066 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/35
摘要： A process for producing acetone selectively and with a high yield by oxidizing propylene by means of the combined oxygen in an oxygen complex under milder conditions and at a single stage is provided wherein a composite catalyst comprising as catalyst components, a transition metal complex with the metal ion of which oxygen molecule can coordinate to form an oxygen complex, and another kind transition metal complex with the metal ion of which propylene can coordinate to form a propylene complex is employed, and propylene activated by the complex formation is oxidized by the combined oxygen activated by the complex formation to thereby obtain acetone.
摘要翻译： 提供了一种通过在较温和的条件和单一阶段通过在氧络合物中的组合氧氧化丙烯而选择性且高产率的方法，其中复合催化剂包含作为催化剂组分的过渡金属络合物与金属 氧分子可以配位以形成氧络合物的离子，以及与丙烯可以配位以形成丙烯络合物的金属离子的另一种过渡金属络合物，并且通过复合氧化活化的丙烯被氧化 通过络合物形成从而获得丙酮。
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公开(公告)号：US4806692A
公开(公告)日：1989-02-21
申请号：US820004
申请日：1986-01-21
申请人： Mutsuo Yamada , Taiji Kamiguchi , Hirotoshi Tanimoto , Yoshijiro Arikawa , Hiroyuki Kaku , Shigehito Takamoto
发明人： Mutsuo Yamada , Taiji Kamiguchi , Hirotoshi Tanimoto , Yoshijiro Arikawa , Hiroyuki Kaku , Shigehito Takamoto
摘要： A process for producing an oxygen-containing organic compound by oxidizing olefins under milder conditions is provided, which process comprises oxidizing an olefin activated by its complex formation, in the presence of a platinum group metal complex capable of forming an olefin complex through coordination of the platinum group metal with said olefin, and also in the presence of water, and further oxidizing and regenerating the resulting reduced platinum group metal complex with oxygen coordinated with a transition metal and activated thereby.
摘要翻译： 提供了一种通过在较温和的条件下氧化烯烃来生产含氧有机化合物的方法，该方法包括在能够形成烯烃络合物的铂族金属配合物的存在下氧化由其络合物形成活化的烯烃， 铂族金属与所述烯烃反应，并且还在水的存在下进一步氧化和再生所得到的还原的铂族金属络合物与过渡金属配位的氧并被活化。
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公开(公告)号：US5101062A
公开(公告)日：1992-03-31
申请号：US405955
申请日：1989-09-12
IPC分类号： C07C269/04
CPC分类号： C07C269/04
摘要： A process for producing carbamic acid esters (N-phenyl carbamate) which comprises reacting an amino group-containing compound (aniline), oxygen, a nitro group-containing compound (nitrobenzene), a carbon monoxide-containing gas and a hydroxyl group-containing organic compound (ethyl alcohol) in the presence of a compound of a transition metal belonging to Pt group of VIII group (Pd) of the Periodic Table as catalyst, a non-metal halide (HCl) and water. ##STR1##
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公开(公告)号：US4935549A
公开(公告)日：1990-06-19
申请号：US35209
申请日：1987-04-06
CPC分类号： C07C51/25
摘要： A process for producing acetic acid directly from ethylene under mild conditions is provided, wherein ethylene and oxygen are respectively coordinated with the respective transition metals contained in a specified composite catalyst system, and ethylene activated thereby is successively oxidized by two kinds of oxygen complexes contained in the system and having their electric charge states adjusted, the composite catalyst system comprising a complex represented by a formula (MmXn.Ll) and a complex represented by a formula (M'm'Xn'.L'l') wherein is a transition metal of the groups I, IV.about.VII and iron group; X, an anion; L, an organic phosphorus compound as a ligand; M', a transition metal of Pt group; L', a nitrile, organic fluorine compound or organic phosphorus compound as a ligand; m, m', n and n', each a number determined by the valences of the transition metals and anion; and l and l' each the number of ligands.
摘要翻译： 提供了一种在温和条件下直接从乙烯生产乙酸的方法，其中乙烯和氧分别与指定的复合催化剂体系中所含的各种过渡金属配位，由此活化的乙烯依次被两种含有 该系统并且调整其电荷状态，复合催化剂体系包含由式（MmXn.L1）表示的络合物和由式（M'm'Xn'L'1'）表示的络合物，其中， I，IV差异VII和铁组的金属; X，阴离子; L，有机磷化合物作为配体; M'，Pt族的过渡金属; L'，腈，有机氟化合物或有机磷化合物作为配体; m，m'，n和n'，每个数字由过渡金属和阴离子的化合价决定; 和l和l'各自配体的数目。
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公开(公告)号：US4711828A
公开(公告)日：1987-12-08
申请号：US866400
申请日：1986-05-23
CPC分类号： H01M8/18 , H01M8/22 , Y02E60/528
摘要： A carbon monoxide-oxygen system fuel cell having overcome various drawbacks of such fuel cell and capable of using CO, as it is, as its fuel without employing any shift converters is provided, which fuel cell is provided with a diaphragm between an anode and a cathode to separate the two electrodes and characterized in using a solution containing at least a monovalent copper and a halide as a complexing agent for the copper, as the electrolytic solution for the anode, and reacting CO in the form of a carbonyl complex of the copper in the electrolytic solution.
摘要翻译： 提供了一氧化碳 - 氧气系统燃料电池，其克服了这种燃料电池的各种缺点，并且能够使用CO作为其燃料，而不使用任何换档转换器，该燃料电池在阳极和 阴极分离两个电极，其特征在于使用至少含有一价铜和卤化物作为铜络合剂的溶液作为阳极的电解液，并使铜以铜的羰基络合物的形式反应 在电解液中。
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