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公开(公告)号：US4521631A
公开(公告)日：1985-06-04
申请号：US620336
申请日：1984-06-13
申请人： Yasuyuki Nishimura , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Takanori Kuwahara , Hirotoshi Tanimoto
发明人： Yasuyuki Nishimura , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Takanori Kuwahara , Hirotoshi Tanimoto
CPC分类号： C07C45/34
摘要： A process for producing acetaldehyde from ethylene under mild reaction conditions, selectively and with high yield is provided, which process comprises preparing a composite catalyst comprising a complex of a transition metal capable of forming an oxygen complex by coordination of oxygen molecule with the metal ion of the transition metal, and a complex of a transition metal capable of forming an ethylene complex by coordination of ethylene with the metal ion of the transition metal, and oxidizing ethylene activated by forming the ethylene complex with the combined oxygen in the oxygen complex, activated by forming the oxygen complex.
摘要翻译： 提供了一种在温和的反应条件下，从温和的反应条件下，以高产率从乙烯中生产乙醛的方法，该方法包括制备复合催化剂，该复合催化剂包括能够通过氧分子与氧分子配位的过渡金属配合物与 过渡金属和能够通过乙烯与过渡金属的金属离子配位形成乙烯络合物的过渡金属的络合物，以及通过与氧络合物中的组合氧形成乙烯络合物来活化乙烯，由 形成氧络合物。
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公开(公告)号：US4691053A
公开(公告)日：1987-09-01
申请号：US617187
申请日：1984-06-04
申请人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
发明人： Mutsuo Yamada , Yasuyuki Nishimura , Yoshijiro Arikawa , Takanori Kuwahara , Taiji Kamiguchi , Hirotoshi Tanimoto
IPC分类号： B01J31/18 , C07C45/38 , C07C45/34 , C07C45/39 , C07C51/235 , C07C51/255 , C07D307/34 , C07D307/89
CPC分类号： B01J31/1845 , B01J2231/70 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/57 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： A novel process for producing oxygen-containing organic compounds with high selectivity and good yield by oxidizing organic compounds under mild conditions is provided, which process comprises using as a catalyst for the oxidation, a complex (M.sub.m X.sub.n.L.sub.l) consisting of a transition metal compound (M.sub.m X.sub.n) and an organic phosphorous compound (L) as a ligand, wherein M represents a transition metal belonging to group I, group IV.about.VII or iron group in group VIII of the periodic table; X represents an anion such as a halogen; ligand L represents an organic phosphorous compound; and m and n mean a number of the atomic valence of said transition metal (ion) M and said anion X, respectively, and l means a number of said ligand.
摘要翻译： 提供了一种通过在温和条件下氧化有机化合物来生产具有高选择性和良好产率的含氧有机化合物的新方法，该方法包括使用由过渡金属化合物组成的络合物（MmXn.Ll） （MmXn）和作为配体的有机磷化合物（L），其中M表示属于元素周期表第I族，第IV族Ⅶ族或第Ⅷ族铁族的过渡金属; X表示阴离子，例如卤素; 配体L表示有机磷化合物; m和n分别表示所述过渡金属（离子）M和所述阴离子X的原子价数，l表示所述配体的数目。
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公开(公告)号：US4605776A
公开(公告)日：1986-08-12
申请号：US694099
申请日：1985-01-23
申请人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Taiji Kamiguchi , Mutsuo Yamada , Yoshijiro Arikawa , Takanori Kuwahara , Hirotoshi Tanimoto , Yasuyuki Nishimura , Hiroyuki Kaku
CPC分类号： C07F15/0066 , C07C45/27 , C07C45/28 , C07C45/30 , C07C45/35
摘要： A process for producing acetone selectively and with a high yield by oxidizing propylene by means of the combined oxygen in an oxygen complex under milder conditions and at a single stage is provided wherein a composite catalyst comprising as catalyst components, a transition metal complex with the metal ion of which oxygen molecule can coordinate to form an oxygen complex, and another kind transition metal complex with the metal ion of which propylene can coordinate to form a propylene complex is employed, and propylene activated by the complex formation is oxidized by the combined oxygen activated by the complex formation to thereby obtain acetone.
摘要翻译： 提供了一种通过在较温和的条件和单一阶段通过在氧络合物中的组合氧氧化丙烯而选择性且高产率的方法，其中复合催化剂包含作为催化剂组分的过渡金属络合物与金属 氧分子可以配位以形成氧络合物的离子，以及与丙烯可以配位以形成丙烯络合物的金属离子的另一种过渡金属络合物，并且通过复合氧化活化的丙烯被氧化 通过络合物形成从而获得丙酮。
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公开(公告)号：US4620038A
公开(公告)日：1986-10-28
申请号：US706263
申请日：1985-02-27
申请人： Hirotoshi Tanimoto , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Yasuyuki Nishimura , Hiroyuki Kaku
发明人： Hirotoshi Tanimoto , Mutsuo Yamada , Yoshijiro Arikawa , Taiji Kamiguchi , Yasuyuki Nishimura , Hiroyuki Kaku
IPC分类号： B01J31/00 , B01J31/16 , B01J31/18 , B01J31/24 , C07B61/00 , C07C45/00 , C07C45/28 , C07C45/30 , C07C45/34 , C07C49/10 , C07C67/00 , C07F15/00
CPC分类号： C07F15/0093 , B01J31/1845 , B01J31/188 , B01J31/24 , C07C45/28 , C07C45/30 , C07C45/34 , C07F15/0066 , B01J2531/16 , B01J2531/46 , B01J2531/56 , B01J2531/824
摘要： A process for producing methyl ethyl ketone selectively and with a high yield by oxygen-oxidizing 1-butene under mild conditions is provided, which process is characterized by using a composite catalyst containing a complex (MmXn.Ll) capable of forming an oxygen complex by coordination of the complex with oxygen and a complex catalyst (M'm'Xn'.L'l') capable of forming a 1-butene complex by coordination of the complex with 1-butene, wherein M represents a specified transition metal such as Cu; X, an anion; L, an organic phosphorus compound as ligand; M', a specified transition metal such as palladium; L', a nitrile, organic fluorine or phosphorus compound as ligand; m, m', n and n', each a number determined by the valences of the transition metals and the anion; l and l', each the number of ligands.
摘要翻译： 提供了在温和条件下通过氧化1-丁烯氧选择性且高收率生产甲基乙基酮的方法，该方法的特征在于使用含有能够形成氧络合物的络合物（MmXn.L1）的复合催化剂， 配合物与氧的配位以及能够通过配合物与1-丁烯配位而形成1-丁烯络合物的复合催化剂（M'''n''L'1'），其中M表示特定的过渡金属，例如 铜 X，阴离子; L，有机磷化合物作为配体; M'，特定的过渡金属如钯; L'，腈，有机氟或磷化合物作为配体; m，m'，n和n'，每个数字由过渡金属和阴离子的化合价决定; l和l'，每个配体数目。
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公开(公告)号：US4935549A
公开(公告)日：1990-06-19
申请号：US35209
申请日：1987-04-06
CPC分类号： C07C51/25
摘要： A process for producing acetic acid directly from ethylene under mild conditions is provided, wherein ethylene and oxygen are respectively coordinated with the respective transition metals contained in a specified composite catalyst system, and ethylene activated thereby is successively oxidized by two kinds of oxygen complexes contained in the system and having their electric charge states adjusted, the composite catalyst system comprising a complex represented by a formula (MmXn.Ll) and a complex represented by a formula (M'm'Xn'.L'l') wherein is a transition metal of the groups I, IV.about.VII and iron group; X, an anion; L, an organic phosphorus compound as a ligand; M', a transition metal of Pt group; L', a nitrile, organic fluorine compound or organic phosphorus compound as a ligand; m, m', n and n', each a number determined by the valences of the transition metals and anion; and l and l' each the number of ligands.
摘要翻译： 提供了一种在温和条件下直接从乙烯生产乙酸的方法，其中乙烯和氧分别与指定的复合催化剂体系中所含的各种过渡金属配位，由此活化的乙烯依次被两种含有 该系统并且调整其电荷状态，复合催化剂体系包含由式（MmXn.L1）表示的络合物和由式（M'm'Xn'L'1'）表示的络合物，其中， I，IV差异VII和铁组的金属; X，阴离子; L，有机磷化合物作为配体; M'，Pt族的过渡金属; L'，腈，有机氟化合物或有机磷化合物作为配体; m，m'，n和n'，每个数字由过渡金属和阴离子的化合价决定; 和l和l'各自配体的数目。
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公开(公告)号：US5101062A
公开(公告)日：1992-03-31
申请号：US405955
申请日：1989-09-12
IPC分类号： C07C269/04
CPC分类号： C07C269/04
摘要： A process for producing carbamic acid esters (N-phenyl carbamate) which comprises reacting an amino group-containing compound (aniline), oxygen, a nitro group-containing compound (nitrobenzene), a carbon monoxide-containing gas and a hydroxyl group-containing organic compound (ethyl alcohol) in the presence of a compound of a transition metal belonging to Pt group of VIII group (Pd) of the Periodic Table as catalyst, a non-metal halide (HCl) and water. ##STR1##
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公开(公告)号：US4747548A
公开(公告)日：1988-05-31
申请号：US931878
申请日：1986-11-17
CPC分类号： C10L1/326
摘要： A process for producing a coal-water slurry having a low viscosity and a good stability even in a high coal concentration without increase in the production cost is provided, which process is characterized in that when coal is fed to a wet mill and milled therein, the coal feed is divided in a multi-stage manner, also in that two coals of different grindabilities are milled together.
摘要翻译： 提供一种即使在高煤浓度下也具有低粘度和高稳定性的水煤浆的生产方法，而不增加生产成本，该方法的特征在于当将煤送入湿磨并在其中研磨时， 煤炭进料分为多级，不同的两种煤粉磨在一起。
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公开(公告)号：US4613084A
公开(公告)日：1986-09-23
申请号：US625245
申请日：1984-06-27
申请人： Shigehito Takamoto , Kazunori Shoji , Nobuyasu Meguri , Yoshinori Ohtani , Hirofumi Kikkawa , Yasuyuki Nishimura , Hiroyuki Kaku , Masayasu Murata
发明人： Shigehito Takamoto , Kazunori Shoji , Nobuyasu Meguri , Yoshinori Ohtani , Hirofumi Kikkawa , Yasuyuki Nishimura , Hiroyuki Kaku , Masayasu Murata
IPC分类号： C10L1/32 , C10L20060101 , B02C19/12
CPC分类号： C10L1/326
摘要： A process for producing a coal-water slurry having a high coal concentration (generally 60 to 80% by weight or more) and a lower viscosity, at a lower cost and with a smaller amount of dispersing agent added is provided, which process is directed to a process for producing a high concentration coal-water slurry by feeding coal, water and a dispersing agent into a wet, continuous ball mill and wet-milling them, characterized by feeding the dispersing agent in a multi-stage manner along the milling direction of coal within the ball mill.
摘要翻译： 提供了一种以更低的成本和更少的分散剂的量生产具有高煤浓度（通常为60至80重量％或更高）和较低粘度的煤 - 水浆料的方法，该方法被定向 涉及一种通过将煤，水和分散剂供给到湿式连续球磨机中并将其湿磨的方法生产高浓度水煤浆的方法，其特征在于沿研磨方向以多级方式进料分散剂 的球磨机内的煤。
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公开(公告)号：US4328195A
公开(公告)日：1982-05-04
申请号：US130388
申请日：1980-03-14
CPC分类号： C01F11/464 , B01D53/501 , B01D53/68
摘要： An improved process for desulfurizing combustion exhaust gases of mainly coal containing sulfur oxides, HF and dust containing Al is provided, which process consists of four steps; a first step of contacting the gases with calcium carbonate or hydroxide in the form of slurry to convert the sulfur oxides into CaSO.sub.3 ; a second step of contacting O.sub.2 with the resulting slurry to convert CaSO.sub.3 into CaSO.sub.4 ; a third step of separating CaSO.sub.4 and mother liquor from the resulting slurry; and a fourth step of preparing a slurry of calcium carbonate or hydroxide to be employed in the first step, from the mother liquor, the pHs of the slurry and the mother liquor in the first and fourth steps being adjusted to 5 or higher by adding alkali such as sodium carbonate.According to the present process, it is possible to prevent hindrance of HF and Al contained in dust to the reaction of SO.sub.2 -absorbent (CaCO.sub.3 or Ca[OH].sub.2) with SO.sub.2 gas, and thereby improve percentage desulfurization and also obtain a high quality gypsum.
摘要翻译： 提供了一种改进的主要含硫硫氧化物，HF和含有Al的粉尘的燃烧废气脱硫方法，该方法由四个步骤组成： 将气体与浆料形式的碳酸钙或氢氧化物接触以将硫氧化物转化为CaSO 3的第一步骤; 使O 2与所得浆料接触以将CaSO 3转化为CaSO 4的第二步骤; 从所得浆料中分离出CaSO 4和母液的第三步骤; 以及在母液中制备第一步中使用的碳酸钙或氢氧化物浆料的第四步骤，通过加入碱将第一步骤和第四步骤中的浆料和母液的pH调节至5以上 如碳酸钠。 根据本方法，可以防止SO 2吸收剂（CaCO 3或Ca [OH] 2）与SO 2气体反应中灰尘中含有的HF和Al的阻碍，从而提高脱硫率并获得高质量 石膏
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公开(公告)号：US5921367A
公开(公告)日：1999-07-13
申请号：US805731
申请日：1997-02-25
摘要： A safety device detects when a worker's hand enters a hazardous region between rollers of a kneading machine, and stops rotation of the rolls to prevent an accident. Each time the rollers are stopped, the orientation of photoelectric sensors is switched from the vicinity of the gap between the two rollers to a test reflection member, and the quantity of received light is compared to a predetermined value, to prevent workers form starting work without knowing a fault or accident has happened. More specifically, a bar electrode of an electrostatic capacitance sensor is disposed above and near the gap between the two rollers, for detecting a physical quantity that is changed by entry of a worker's hand. When the electrostatic capacitance detected by the sensor exceeds a predetermined value, a judging circuit supplies a control signal to stop a driving unit that operates the kneading machine. Heat ray sensors or photoelectric sensors may be used as alternatives to electrostatic sensors. As an additional feature, case housing light projectors and photoelectric sensors are rotatably disposed above and near the gap between the two rollers, and a test reflector is disposed on the side of the case. When the rollers are stopped, a light receiving object switching circuit rotates the case and a test circuit tests the light receiving states of the photoelectric sensors.
摘要翻译： 安全装置检测工人的手进入捏合机的辊之间的危险区域，并停止辊的旋转以防止事故。 每次停止辊子时，光电传感器的方向从两辊之间的间隙附近切换到测试反射部件，并将接收到的光量与预定值进行比较，以防止工作人员在没有 知道故障或事故已经发生。 更具体地，静电电容传感器的棒状电极设置在两个辊之间的间隙的上方和附近，用于检测通过工人手的进入而改变的物理量。 当由传感器检测到的静电电容超过预定值时，判断电路提供控制信号以停止操作捏合机的驱动单元。 热射线传感器或光电传感器可用作静电传感器的替代品。 作为附加特征，壳体投光器和光电传感器可旋转地设置在两个辊之间的间隙上方和附近，并且测试反射器设置在壳体的侧面上。 当辊停止时，受光对象切换电路使壳体旋转，并且测试电路测试光电传感器的光接收状态。
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