公开(公告)号：US07411104B2

公开(公告)日：2008-08-12

申请号：US11390880

申请日：2006-03-28

Applicant: Hyun-Ki Yun ,  Byeong-Gyu Lim ,  Myeong-Seog Kim ,  Se-Saeng Oh ,  Jae-Hoon Uhm

Inventor： Hyun-Ki Yun ,  Byeong-Gyu Lim ,  Myeong-Seog Kim ,  Se-Saeng Oh ,  Jae-Hoon Uhm

IPC: C07C2/02 ,  C08F2/00 ,  C08F4/00

CPC classification number: C08F10/08 ,  C08F110/10 ,  C08F4/14 ,  C08F2500/03 ,  C08F2500/02

Abstract: A method for producing high reactive polybutene (HRPB), in which carbon-carbon double bond is positioned at an end of polybutene, is disclosed. The high reactive polybutene having 300˜5000 of number average molecular weight (Mn) can be produced from a raw material containing isobutene, wherein a polymerization reaction of the isobutene is carried out in the presence of a catalyst system including secondary alkylether, tertiary alcohol, and boron trifluoride, the amount of boron trifluoride is 0.05˜1.0 weight part per 100 weight part of isobutene, the mole ratio of a co-catalyst including secondary alkylether and tertiary alcohol:boron trifluoride is 1.0˜2.0:1, and the mole ratio of secondary alkylether:tertiary alcohol is 0.5˜1.2:1.

Abstract translation: 公开了一种生产高活性聚丁烯（HRPB）的方法，其中碳 - 碳双键位于聚丁烯的末端。 具有数均分子量（Mn）为300〜5000的高反应性聚丁烯可以由含有异丁烯的原料制造，其中异丁烯的聚合反应在包括仲烷基醚，叔醇等的催化剂体系的存在下进行， 和三氟化硼，每100重量份异丁烯的三氟化硼的量为0.05〜1.0重量份，包括仲烷基醚和叔醇的助催化剂：三氟化硼的摩尔比为1.0〜2.0:1，摩尔比 二级烷基醚：叔醇为0.5〜1.2：1。

公开(公告)号：US6090170A

公开(公告)日：2000-07-18

申请号：US223914

申请日：1998-12-31

Applicant: Hyun-ki Yun ,  Jung-jin Kim ,  Yong-hwa Yeom ,  Il-seung Kim ,  Myeong-seog Kim ,  Byung-keel Sohn ,  Kyu-shon Jung

Inventor： Hyun-ki Yun ,  Jung-jin Kim ,  Yong-hwa Yeom ,  Il-seung Kim ,  Myeong-seog Kim ,  Byung-keel Sohn ,  Kyu-shon Jung

IPC: C08F8/32 ,  C10L1/2387 ,  C10L10/00 ,  C01L1/22 ,  C01L1/18

CPC classification number: C10L1/2387 ,  C08F8/32 ,  C10L10/04 ,  F02B2275/18

Abstract: The present invention relates to derivatives of polyalkenyl amine substituted with numerous hydroxy groups of the following formula (I) useful as a novel fuel detergent. ##STR1## wherein polyalkenyl denotes a branched alkyl derived from polyolefin which has a molecular weight of 400.about.5,000 and is prepared with olefin having 2 to 6 carbon atoms; m is an integer ranging from 2 to 10, R.sup.1, R.sup.2 and R.sup.3 may be identical or different, and represent a hydrogen atom or a linear or branched alkyl having 1 to 4 carbon atoms: R.sup.4 and R.sup.5 may be identical or different, and denote a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group, a hydroxyalkyl, a phenyl, naphthyl, an aminoalkyl of formula (II) or a polyaminoalkylene of formula (III) ##STR2## wherein R.sup.6 denotes a C.sub.2 -C.sub.10 alkylene group: R.sup.7 and R.sup.8 may be identical or different, and denote a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group, a phenyl, a naphthyl or a C.sub.1 -C.sub.10 hydroxyalkyl group, and n is an integer ranging from 2 to 8.

Abstract translation: 本发明涉及用作新型燃料洗涤剂的下式（I）的许多羟基取代的聚链烯基胺的衍生物。 其中聚烯基表示衍生自聚烯烃的支链烷基，其分子量为400分子量5,000，并由具有2至6个碳原子的烯烃制备; m是2至10的整数，R 1，R 2和R 3可以相同或不同，表示氢原子或具有1至4个碳原子的直链或支链烷基：R 4和R 5可以相同或不同，并且表示 氢原子，C1-C10烷基，羟基烷基，苯基，萘基，式（II）的氨基烷基或式（III）的聚氨基亚烷基，其中R6表示C2-C10亚烷基：R7和R8可以相同 或不同，表示氢原子，C1-C10烷基，苯基，萘基或C1-C10羟烷基，n为2〜8的整数。

公开(公告)号：US20060195000A1

公开(公告)日：2006-08-31

申请号：US11390880

申请日：2006-03-28

Applicant: Hyun-Ki Yun ,  Byeong-Gyu Lim ,  Myeong-Seog Kim ,  Se-Saeng Oh ,  Jae-Hoon Uhm

Inventor： Hyun-Ki Yun ,  Byeong-Gyu Lim ,  Myeong-Seog Kim ,  Se-Saeng Oh ,  Jae-Hoon Uhm

IPC: C07C2/02

CPC classification number: C08F10/08 ,  C08F110/10 ,  C08F4/14 ,  C08F2500/03 ,  C08F2500/02

Abstract: A method for producing high reactive polybutene (HRPB), in which carbon-carbon double bond is positioned at an end of polybutene, is disclosed. The high reactive polybutene having 300˜5000 of number average molecular weight (Mn) can be produced from a raw material containing isobutene, wherein a polymerization reaction of the isobutene is carried out in the presence of a catalyst system including secondary alkylether, tertiary alcohol, and boron trifluoride, the amount of boron trifluoride is 0.05˜1.0 weight part per 100 weight part of isobutene, the mole ratio of a co-catalyst including secondary alkylether and tertiary alcohol:boron trifluoride is 1.0˜2.0:1, and the mole ratio of secondary alkylether:tertiary alcohol is 0.5˜1.2:1.

Abstract translation: 公开了一种生产高活性聚丁烯（HRPB）的方法，其中碳 - 碳双键位于聚丁烯的末端。 具有数均分子量（Mn）为300〜5000的高反应性聚丁烯可以由含有异丁烯的原料制造，其中异丁烯的聚合反应在包括仲烷基醚，叔醇等的催化剂体系的存在下进行， 和三氟化硼，每100重量份异丁烯的三氟化硼的量为0.05〜1.0重量份，包括仲烷基醚和叔醇的助催化剂：三氟化硼的摩尔比为1.0〜2.0:1，摩尔比 二级烷基醚：叔醇为0.5〜1.2：1。