Method for producing polybutene
    1.
    发明授权
    Method for producing polybutene 有权
    聚丁烯的制造方法

    公开(公告)号:US07411104B2

    公开(公告)日:2008-08-12

    申请号:US11390880

    申请日:2006-03-28

    Abstract: A method for producing high reactive polybutene (HRPB), in which carbon-carbon double bond is positioned at an end of polybutene, is disclosed. The high reactive polybutene having 300˜5000 of number average molecular weight (Mn) can be produced from a raw material containing isobutene, wherein a polymerization reaction of the isobutene is carried out in the presence of a catalyst system including secondary alkylether, tertiary alcohol, and boron trifluoride, the amount of boron trifluoride is 0.05˜1.0 weight part per 100 weight part of isobutene, the mole ratio of a co-catalyst including secondary alkylether and tertiary alcohol:boron trifluoride is 1.0˜2.0:1, and the mole ratio of secondary alkylether:tertiary alcohol is 0.5˜1.2:1.

    Abstract translation: 公开了一种生产高活性聚丁烯(HRPB)的方法,其中碳 - 碳双键位于聚丁烯的末端。 具有数均分子量(Mn)为300〜5000的高反应性聚丁烯可以由含有异丁烯的原料制造,其中异丁烯的聚合反应在包括仲烷基醚,叔醇等的催化剂体系的存在下进行, 和三氟化硼,每100重量份异丁烯的三氟化硼的量为0.05〜1.0重量份,包括仲烷基醚和叔醇的助催化剂:三氟化硼的摩尔比为1.0〜2.0:1,摩尔比 二级烷基醚:叔醇为0.5〜1.2:1。

    Method for producing polybutene
    3.
    发明申请
    Method for producing polybutene 有权
    聚丁烯的制造方法

    公开(公告)号:US20060195000A1

    公开(公告)日:2006-08-31

    申请号:US11390880

    申请日:2006-03-28

    Abstract: A method for producing high reactive polybutene (HRPB), in which carbon-carbon double bond is positioned at an end of polybutene, is disclosed. The high reactive polybutene having 300˜5000 of number average molecular weight (Mn) can be produced from a raw material containing isobutene, wherein a polymerization reaction of the isobutene is carried out in the presence of a catalyst system including secondary alkylether, tertiary alcohol, and boron trifluoride, the amount of boron trifluoride is 0.05˜1.0 weight part per 100 weight part of isobutene, the mole ratio of a co-catalyst including secondary alkylether and tertiary alcohol:boron trifluoride is 1.0˜2.0:1, and the mole ratio of secondary alkylether:tertiary alcohol is 0.5˜1.2:1.

    Abstract translation: 公开了一种生产高活性聚丁烯(HRPB)的方法,其中碳 - 碳双键位于聚丁烯的末端。 具有数均分子量(Mn)为300〜5000的高反应性聚丁烯可以由含有异丁烯的原料制造,其中异丁烯的聚合反应在包括仲烷基醚,叔醇等的催化剂体系的存在下进行, 和三氟化硼,每100重量份异丁烯的三氟化硼的量为0.05〜1.0重量份,包括仲烷基醚和叔醇的助催化剂:三氟化硼的摩尔比为1.0〜2.0:1,摩尔比 二级烷基醚:叔醇为0.5〜1.2:1。

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