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1.发明授权Low smoke and heat release glass fiber/carbon fiber/bisoxazoline resin composites and method of manufacture 失效低烟和放热玻璃纤维/碳纤维/双恶唑啉树脂复合材料及其制造方法
公开(公告)号：US4814223A
公开(公告)日：1989-03-21
申请号：US129497
申请日：1987-12-07
申请人： Omar Tiba , Billy M. Culbertson , Donald D. Carlos
发明人： Omar Tiba , Billy M. Culbertson , Donald D. Carlos
IPC分类号： C08L61/04 , B29B11/16 , B29C70/06 , B29C70/08 , B29C70/10 , B29K61/04 , B29K105/10 , B32B5/02 , B32B5/26 , B32B17/04 , B32B27/42 , C04B35/83 , C08J5/04 , C08J5/24 , C08L61/10 , B29C67/14
CPC分类号： C08J5/04 , B29C70/08 , B32B5/26 , C08J5/042 , C08J5/043 , C08J5/24 , C08J2377/00 , Y10T442/3813
摘要： The formation of structural composites having low smoke release and low heat release properties by forming a sandwich comprising a non-woven fiber mat between woven glass fiber mats and impregnating said sandwich with a mixture of a bisoxazoline and a polyphenolic compound to form a prepreg which can be formed and molded at elevated temperatures is described.
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2.发明授权
公开(公告)号：US4748230A
公开(公告)日：1988-05-31
申请号：US30799
申请日：1987-03-27
CPC分类号： C08G69/40
摘要： A process for the copolymerization of bis-2-oxazolines and polyphenolic compounds at greatly improved rates comprising carrying out the copolymerization in the presence of from about 0.5 to about 5% by weight of a phosphine catalyst is described.
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3.发明授权Rapid preparation of polyetheramide from bis-oxazoline, polyphenol and carbonium ion salt catalyst 失效从双恶唑啉，多酚和碳鎓离子盐催化剂快速制备聚醚酰胺
公开(公告)号：US4746719A
公开(公告)日：1988-05-24
申请号：US57476
申请日：1987-06-03
申请人： Anil B. Goel , Omar Tiba
发明人： Anil B. Goel , Omar Tiba
CPC分类号： C08G69/40
摘要： A process for preparing copolymers of a mixture of a bis-oxazoline and a polyphenolic compound at improved rate of copolymerization by the inclusion of a catalytic amount of a carbonium ion salt of the formula Ph.sub.3 CX wherein Ph represents a phenyl group and X represents BF.sub.4, PF.sub.6, SbF.sub.6, AsF.sub.6, BPh.sub.4 or ClO.sub.4, is described.
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4.发明授权Liquid aromatic bisoxazoline and disoxazine monomer mixtures cured with polyphenolic compounds 失效用多酚化合物固化的液体芳族双恶唑啉和二恶嗪单体混合物
公开(公告)号：US4841002A
公开(公告)日：1989-06-20
申请号：US266403
申请日：1988-11-08
申请人： Billy M. Culbertson , Omar Tiba
发明人： Billy M. Culbertson , Omar Tiba
IPC分类号： C08K5/35
CPC分类号： C08K5/35
摘要： Compositions have melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,R independently represents H, CH.sub.3, CH.sub.2 CH.sub.3 or C.sub.6 H.sub.5,R.sup.1 independently represents H or CH.sub.3,R.sup.2 independently represents H or CH.sub.3, andx represents an integer from 0 to 2are described.
摘要翻译： 组合物具有低于100℃的熔点，其可用于通过与由多于两种具有下式的化合物的混合物组成的多酚化合物反应形成树脂：其中A表示环状或非环状的脂族或取代的环状或非环状的 具有1至20个碳原子的脂族部分或具有6至20个碳原子的芳族单核或多核或脂族取代的芳基残基，R独立地表示H，CH 3，CH 2 CH 3或C 6 H 5，R 1独立地表示H或CH 3，R 2 独立地表示H或CH 3，并且x表示0至2的整数。
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公开(公告)号：US20080235929A1
公开(公告)日：2008-10-02
申请号：US10598379
申请日：2005-03-24
IPC分类号： B23P6/00
CPC分类号： E01B31/20 , Y10T29/49723
摘要： A method for restoring a damaged rail seat located on a concrete rail tie. The method comprises applying a polymeric material comprising a poly(urethaneurea) material to the damaged rail seat located in the concrete rail tie; and restoring the damaged rail seat by cursing the polymeric material under ambient temperature and pressure conditions. The polymeric material is substantially sag resistant and maintains its shape without substantial runoff from the concrete rail tie during the restoring of the damage rail seat.
摘要翻译： 一种用于恢复位于混凝土轨枕上的受损轨道座椅的方法。 该方法包括将包含聚（尿烷脲）材料的聚合物材料施加到位于混凝土轨枕中的损坏的轨道座椅上; 并通过在环境温度和压力条件下诅咒聚合材料来恢复损坏的轨道座椅。 聚合物材料在损坏轨道座椅的恢复期间基本上不起伏并且保持其形状而没有从混凝土轨道系带的实质径流。
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6.发明授权Preparation of resins from phenolic compounds and oxazolines using ammonium or phosphonium salt catalysts 失效使用铵或鏻盐催化剂由酚类化合物和恶唑啉制备树脂
公开(公告)号：US5302687A
公开(公告)日：1994-04-12
申请号：US38417
申请日：1993-03-29
申请人： Billy M. Culbertson , Omar Tiba , Gilbert M. Gynn
发明人： Billy M. Culbertson , Omar Tiba , Gilbert M. Gynn
CPC分类号： C08G65/2612 , C08G69/40
摘要： A process for preparing a polymeric composition comprising reacting a mixture of at least one phenolic compound and at least one oxazoline compound in the presence of a catalytic amount of at least one ammonium salt and a tetracarbyl phosphonium salt, and optionally also in the presence of an alkyl halide is described.
摘要翻译： 一种制备聚合物组合物的方法，包括使至少一种酚类化合物和至少一种恶唑啉化合物的混合物在催化量的至少一种铵盐和四溴化鏻盐存在下反应，并且任选地还可以在 描述了卤代烷烃。
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7.发明授权Thermosetting bis oxazoline-polyphenol based resins for resin transfer molding which contain a monooxazine or monooxazoline diluent 失效含有单恶嗪或单恶唑啉稀释剂的用于树脂传递模塑的热固性双恶唑啉 - 多酚类树脂
公开(公告)号：US4839446A
公开(公告)日：1989-06-13
申请号：US229289
申请日：1988-08-08
申请人： Billy M. Culbertson , Omar Tiba
发明人： Billy M. Culbertson , Omar Tiba
IPC分类号： C08G73/02
CPC分类号： C08G73/0233
摘要： A polymerizable thermosetting composition which is a flowable liquid at moderate temperatures which comprises a mixture of:(A) from about 75% to about 95% by weight of a mixture of:(1) from about 80% to about 20% by weight of a bisoxazoline and(2) from about 20% to about 80% by weight of a polyphenolic compound and(B) from about 5% to about 25% by weight of at least one member selected from the group consisting of a monooxazoline and a monooxazine,a method for forming thermoset products therefrom and the novel thermoset products resulting from said method are described.
摘要翻译： 一种中等温度下的可流动液体的可聚合热固性组合物，其包含以下混合物的混合物：（A）约75重量％至约95重量％的混合物：（1）约80重量％至约20重量％ 二恶唑啉和（2）约20％至约80％重量的多酚化合物和（B）约5％至约25％重量的至少一种选自单恶唑啉和单恶嗪 描述了从其形成热固性产物的方法和由所述方法得到的新型热固性产品。
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8.发明授权Liquid aromatic bisoxazoline and bisoxazine monomer mixtures and process for crosslinking using phenolics 失效液体芳族双恶唑啉和二恶嗪单体混合物和使用酚类交联的方法
公开(公告)号：US4806267A
公开(公告)日：1989-02-21
申请号：US144142
申请日：1988-01-15
申请人： Billy M. Culbertson , Omar Tiba
发明人： Billy M. Culbertson , Omar Tiba
CPC分类号： C08K5/35
摘要： Compositions having melting points below 100.degree. C. which are useful in the formation of resins by reaction with polyphenolic compounds consisting of a mixture of more than two compounds having the formula ##STR1## wherein A represents a cyclic or acyclic aliphatic or substituted cyclic or acyclic aliphatic moiety having from 1 to 20 carbon atoms or an aromatic mono- or multi-nuclear or aliphatic substituted aryl residue having from 6 to 20 carbon atoms,R independently represents H, CH.sub.3, CH.sub.2 CH.sub.3 or C.sub.6 H.sub.5,R.sup.1 independently represents H or CH.sub.3,R.sup.2 independently represents H or CH.sub.3, andx represents an integer from 0 to 2as described.
摘要翻译： 熔点低于100℃的组合物，其可用于通过与由多于两种具有下式的化合物的混合物组成的多酚化合物反应形成树脂：其中A表示环状或非环状的脂族或取代的环状或非环状的 具有1至20个碳原子的脂族部分或具有6至20个碳原子的芳族单核或多核或脂族取代的芳基残基，R独立地表示H，CH 3，CH 2 CH 3或C 6 H 5，R 1独立地表示H或CH 3，R 2 独立地表示H或CH 3，x表示0〜2的整数。
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公开(公告)号：US08277705B2
公开(公告)日：2012-10-02
申请号：US10598379
申请日：2005-03-24
IPC分类号： B29C73/00
CPC分类号： E01B31/20 , Y10T29/49723
摘要： A method for restoring a damaged rail seat located on a concrete rail tie. The method comprises applying a polymeric material comprising a poly(urethane-urea) material to the damaged rail seat located on the concrete rail tie; and restoring the damaged rail seat by curing the polymeric material under ambient temperature and pressure conditions. The polymeric material is substantially sag resistant and maintains its shape without substantial runoff from the concrete rail tie during the restoring of the damage rail seat.
摘要翻译： 一种用于恢复位于混凝土轨枕上的受损轨道座椅的方法。 该方法包括将包含聚（氨基甲酸酯 - 尿素）材料的聚合材料施加到位于混凝土轨枕上的受损轨道座上; 并通过在环境温度和压力条件下固化聚合物材料来恢复损坏的轨道座椅。 聚合物材料在损坏轨道座椅的恢复期间基本上不起伏并且保持其形状而没有从混凝土轨道系带的实质径流。
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10.发明授权
公开(公告)号：US4699970A
公开(公告)日：1987-10-13
申请号：US880477
申请日：1986-06-30
申请人： Omar Tiba , Billy M. Culbertson
发明人： Omar Tiba , Billy M. Culbertson
摘要： The process for preparing a polymeric composition at improved rate comprising reacting an oxazoline compound and a phenolic compound in the presence of a catalytic amount of a phosphorous acid ester is described.
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