公开(公告)号：US6013798A

公开(公告)日：2000-01-11

申请号：US009126

申请日：1998-01-20

申请人： Peter T Bishop

发明人： Peter T Bishop

IPC分类号： C03C17/06 ,  C03C17/10 ,  C04B41/45 ,  C04B41/51 ,  C04B41/81 ,  C04B41/88 ,  C07C321/02 ,  C07C323/00 ,  C07C323/10 ,  C07C323/60 ,  C07F1/12 ,  C07K5/02 ,  C08K5/372 ,  C23C18/08 ,  C07C17/06 ,  C07C321/00

CPC分类号： C04B41/009 ,  C03C17/06 ,  C03C17/10 ,  C04B41/4511 ,  C04B41/4554 ,  C04B41/5111 ,  C04B41/5116 ,  C04B41/81 ,  C04B41/88 ,  C07C323/60 ,  C07K5/0212 ,  C08K5/372 ,  C23C18/08 ,  C03C2217/254 ,  C03C2217/255 ,  C03C2217/27 ,  C03C2218/11 ,  C03C2218/32 ,  C04B2103/0093 ,  Y10S428/914 ,  Y10T428/31609 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31703 ,  Y10T428/31993 ,  Y10T428/31996

摘要： Gold thiolates of formula AuSR" or a salt thereof, in which R" is such that HSR" represents: 4,6-dihydroxy-2-mercaptopyrimidine;N-(2-mercaptoacetyl)glycine;N-(3-mercaptopropionyl)glycine; andN-(2-mercaptopropionyl)glycine. The invention provides also processes for preparing novel gold thiolates.

摘要翻译： 式“AuSR”的金硫醇盐或其盐，其中R“使得HSR”表示：4,6-二羟基-2-巯基嘧啶; N-（2-巯基乙酰基）甘氨酸; N-（3-巯基丙酰基）甘氨酸; 和N-（2-巯基丙酰基）甘氨酸。 本发明还提供了制备新型金硫醇盐的方法。

公开(公告)号：US5281635A

公开(公告)日：1994-01-25

申请号：US875412

申请日：1992-04-29

申请人： Peter T. Bishop

发明人： Peter T. Bishop

IPC分类号： C03C17/06 ,  C03C17/10 ,  C04B41/45 ,  C04B41/51 ,  C04B41/81 ,  C04B41/88 ,  C07C321/02 ,  C07C323/00 ,  C07C323/10 ,  C07C323/60 ,  C07F1/12 ,  C07K5/02 ,  C08K5/372 ,  C23C18/08 ,  C08K5/36

CPC分类号： C04B41/009 ,  C03C17/06 ,  C03C17/10 ,  C04B41/4511 ,  C04B41/4554 ,  C04B41/5111 ,  C04B41/5116 ,  C04B41/81 ,  C04B41/88 ,  C07C323/60 ,  C07K5/0212 ,  C08K5/372 ,  C23C18/08 ,  C03C2217/254 ,  C03C2217/255 ,  C03C2217/27 ,  C03C2218/11 ,  C03C2218/32 ,  C04B2103/0093 ,  Y10S428/914 ,  Y10T428/31609 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31703 ,  Y10T428/31993 ,  Y10T428/31996

摘要： A homogeneous composition for forming on firing a film of precious metal, which is one or more of platinum, palladium, gold and silver, on a substrate, for instance to decorate table ware, comprises polymeric resin and a solution, in water and a co-solvent, of thiolate of the precious metal, the composition containing 3-22% by weight of the precious metal as the thiolate, and the co-solvent, resin and thiolate being such that as the composition on a substrate dries and is progressively heated in firing, the water evaporates off to leave a homogeneous composition of the resin and thiolate in the co-solvent, then the co-solvent evaporates off to leave a homogeneous composition of the thiolate in the resin, and then the thiolate decomposes to the precious metal while the resin volatilise.

摘要翻译： 用于在基材上焙烧贵金属薄膜（其为铂，钯，金和银中的一种或多种）的均匀组合物，例如装饰餐具，包括聚合树脂和在水和共混物中的溶液 - 溶剂，贵金属的硫醇盐，组合物含有3-22重量％的贵金属作为硫醇盐，共溶剂，树脂和硫醇盐使得当基底上的组合物干燥并逐渐加热时 在烧制中，水蒸发掉，在共溶剂中留下树脂和硫醇盐的均匀组成，然后共溶剂蒸发掉，在树脂中留下均匀的硫醇盐组合物，然后硫醇盐分解成珍贵的 金属同时树脂挥发。

公开(公告)号：US5401535A

公开(公告)日：1995-03-28

申请号：US155827

申请日：1993-11-23

申请人： Peter T. Bishop

发明人： Peter T. Bishop

IPC分类号： C03C17/06 ,  C03C17/10 ,  C04B41/45 ,  C04B41/51 ,  C04B41/81 ,  C04B41/88 ,  C07C321/02 ,  C07C323/00 ,  C07C323/10 ,  C07C323/60 ,  C07F1/12 ,  C07K5/02 ,  C08K5/372 ,  C23C18/08 ,  B05D3/02

CPC分类号： C04B41/009 ,  C03C17/06 ,  C03C17/10 ,  C04B41/4511 ,  C04B41/4554 ,  C04B41/5111 ,  C04B41/5116 ,  C04B41/81 ,  C04B41/88 ,  C07C323/60 ,  C07K5/0212 ,  C08K5/372 ,  C23C18/08 ,  C03C2217/254 ,  C03C2217/255 ,  C03C2217/27 ,  C03C2218/11 ,  C03C2218/32 ,  C04B2103/0093 ,  Y10S428/914 ,  Y10T428/31609 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31703 ,  Y10T428/31993 ,  Y10T428/31996

摘要： A homogeneous composition for forming on firing a film of precious metal, which is one or more of platinum, palladium, gold and silver, on a substrate, for instance to decorate table ware, comprises polymeric resin and a solution, in water and a co-solvent, of thiolate of the precious metal, the composition containing 3-22% by weight of the precious metal as the thiolate, and the co-solvent, resin and thiolate being such that as the composition on a substrate dries and is progressively heated in firing, the water evaporates off to leave a homogeneous composition of the resin and thiolate in the co-solvent, then the co-solvent evaporates off to leave a homogeneous composition of the thiolate in the resin, and then the thiolate decomposes to the precious metal while the resin volatilize.

摘要翻译： 用于在基材上焙烧贵金属薄膜（其为铂，钯，金和银中的一种或多种）的均匀组合物，例如装饰餐具，包括聚合树脂和在水和共混物中的溶液 - 溶剂，贵金属的硫醇盐，组合物含有3-22重量％的贵金属作为硫醇盐，共溶剂，树脂和硫醇盐使得当基底上的组合物干燥并逐渐加热时 在烧制中，水蒸发掉，在共溶剂中留下树脂和硫醇盐的均匀组成，然后共溶剂蒸发掉，在树脂中留下均匀的硫醇盐组合物，然后硫醇盐分解成珍贵的 金属，同时树脂挥发。

公开(公告)号：US5744245A

公开(公告)日：1998-04-28

申请号：US383219

申请日：1995-02-03

申请人： Peter T. Bishop

发明人： Peter T. Bishop

IPC分类号： C03C17/06 ,  C03C17/10 ,  C04B41/45 ,  C04B41/51 ,  C04B41/81 ,  C04B41/88 ,  C07C321/02 ,  C07C323/00 ,  C07C323/10 ,  C07C323/60 ,  C07F1/12 ,  C07K5/02 ,  C08K5/372 ,  C23C18/08 ,  B32B17/00

CPC分类号： C04B41/009 ,  C03C17/06 ,  C03C17/10 ,  C04B41/4511 ,  C04B41/4554 ,  C04B41/5111 ,  C04B41/5116 ,  C04B41/81 ,  C04B41/88 ,  C07C323/60 ,  C07K5/0212 ,  C08K5/372 ,  C23C18/08 ,  C03C2217/254 ,  C03C2217/255 ,  C03C2217/27 ,  C03C2218/11 ,  C03C2218/32 ,  C04B2103/0093 ,  Y10S428/914 ,  Y10T428/31609 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31703 ,  Y10T428/31993 ,  Y10T428/31996

摘要： A homogeneous composition for forming on firing a film of precious metal, which is one or more of platinum, palladium, gold and silver, on a substrate, for instance to decorate table ware, comprises polymeric resin and a solution, in water and a co-solvent, of thiolate of the precious metal, the composition containing 3-22% by weight of the precious metal as the thiolate, and the co-solvent, resin and thiolate being such that as the composition on a substrate dries and is progressively heated in firing, the water evaporates off to leave a homogeneous composition of the resin and thiolate in the co-solvent, then the co-solvent evaporates off to leave a homogeneous composition of the thiolate in the resin, and then the thiolate decomposes to the precious metal while the resin volatilize.