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1.发明授权公开(公告)号：US06348219B1
公开(公告)日：2002-02-19
申请号：US09663788
申请日：2000-09-18
IPC分类号： A01N5902
CPC分类号： C02F1/766 , A01N59/00 , C02F2303/04 , A01N2300/00
摘要： The process involves (a) continuously forming bromine chloride from separate feed streams of bromine and chlorine by maintaining said streams under automatic feed rate control whereby the streams are continuously proportioned to come together to form bromine chloride; (b) continuously forming an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine greater than 0.93:1 by continuously or intermittently feeding into mixing apparatus separate feed streams of (1) bromine chloride formed in (a), and (2) an aqueous solution of alkali metal salt of sulfamic acid, under automatic feed rate control.
摘要翻译： 该方法包括（a）通过在自动进料速率控制下将所述物流保持在连续成比例以一起形成氯化溴，从溴和氯的不同进料流中连续形成溴氯化物; （b）通过连续或间歇进料连续形成具有至少100,000ppm（wt / wt）的活性溴含量，至少7的pH以及氮与活性溴的原子比大于0.93:1的含水产物 在（a）中形成的（1）溴氯化物的进料流和（2）氨基磺酸的碱金属盐的水溶液中分离进料流，在自动进料速率控制下。
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公开(公告)号：US5103059A
公开(公告)日：1992-04-07
申请号：US601516
申请日：1990-10-23
IPC分类号： B01J31/14 , C07B61/00 , C07C209/68 , C07C211/50
CPC分类号： C07C209/68 , B01J31/143 , B01J2231/4205
摘要： Production of alkyl substituted aromatic diamines by reacting triethylaluminum with an aromatic diamine and a chloride ion source in the presence of an olefin is disclosed. The alkyl substituted aromatic diamines are useful as chain extenders in polyurethane processes.
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公开(公告)号：US4593129A
公开(公告)日：1986-06-03
申请号：US601505
申请日：1984-04-18
IPC分类号： C07C27/00 , C07C29/70 , C07C31/34 , C07C37/66 , C07C39/235 , C07C67/00 , C07F9/06 , C07F9/6581 , C08G79/02 , C07C2/56
CPC分类号： C07C29/70 , C07C37/66 , C07F9/067 , C07F9/65812 , C08G79/02
摘要： A process for making an alkali metal alkoxide (e.g. sodium alkoxide) of a halogen-substituted alcohol (e.g. fluorine-substituted alcohols) by dispersing an alkali metal (e.g. sodium) in a cycloalkane (e.g. cyclohexane) containing a phenol (e.g. o-allylphenol) and adding the resultant dispersion to an ether (e.g. THF) solution of a halogen-substituted alcohol. The resultant alkali metal haloalkoxide solution contains phenoxides and can be reacted with a phosphonitrilic chloride polymer to introduce haloalkoxide and phenoxide substituents.
摘要翻译： 通过将碱金属（例如钠）分散在含有苯酚的环烷烃（例如环己烷）中来制备卤素取代的醇（例如氟取代的醇）的碱金属醇盐（例如烷氧基化钠）的方法（例如邻 - 烯丙基苯酚 ），并将所得分散体加入到卤素取代的醇的醚（例如THF）溶液中。 得到的碱金属卤代醇溶液含有苯氧化物，并且可与磷酰氯化聚合物反应以引入卤代醇和苯酚取代基。
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公开(公告)号：US06306441B1
公开(公告)日：2001-10-23
申请号：US09442025
申请日：1999-11-17
IPC分类号： A01N5902
CPC分类号： C02F1/766 , A01N59/00 , C02F2303/04 , G09F3/10 , A01N59/02 , A01N25/22 , A01N2300/00
摘要： A concentrated liquid biocide composition is produced by a continuous process. The process comprises continuously feeding into mixing apparatus (i) bromine chloride and (ii) an aqueous solution of alkali metal salt of sulfamic acid. These are proportioned to produce an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), and an atom ratio of nitrogen to active bromine from (i) and (ii) greater than 0.93:1. The desired product is withdrawn from the mixing apparatus at a rate sufficient to enable the continuous feeding to be maintained. Thus, the withdrawal of the product can be continuous or intermittent, depending upon the type of mixing apparatus being used.
摘要翻译： 浓缩液体杀生物剂组合物通过连续方法生产。 该方法包括连续进料到混合装置（i）溴氯化物和（ii）氨基磺酸的碱金属盐水溶液中。 这些成分相当于产生具有至少100,000ppm（wt / wt）的活性溴含量的水性产物，以及（i）和（ii）中氮与活性溴的原子比大于0.93:1。 将期望的产品以足以使得能够保持连续进料的速度从混合装置中取出。 因此，取决于所使用的混合装置的类型，产品的抽出可以是连续的或间歇的。
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公开(公告)号：US5030436A
公开(公告)日：1991-07-09
申请号：US346925
申请日：1989-05-03
申请人： J. Francis Steadman , Dennis J. Malfer , George A. Daniels , J. Keitt Hane , R. Woodrow Wilson, Jr.
发明人： J. Francis Steadman , Dennis J. Malfer , George A. Daniels , J. Keitt Hane , R. Woodrow Wilson, Jr.
IPC分类号： C01B17/94
CPC分类号： C01B17/94
摘要： Contaminants in spent nitric-sulfuric nitration acid can be removed by mixing the spent acid with urea and heating to 75.degree.-150.degree. C. Off-gas from the spent acid/urea reaction is passed through a Group IB, VB, VIB or VIII metal containing catalyst to decompose nitrous oxides and the so-treated off-gas is contacted with spent acid, denitrated spent acid, or fresh sulfuric acid, and optionally air (i.e. oxygen), to absorb oxides of nitrogen. The spent acid scrubbing fluid is then subjected to the same process for removing contaminants.
摘要翻译： 废硝酸硝酸中的污染物可以通过将废酸与尿素混合并加热至75°-150℃来除去。废酸/尿素反应的废气通过IB，VB，VIB或VIII族 含有金属的催化剂以分解一氧化二氮，并且如此处理的废气与废酸，脱硝的废酸或新鲜的硫酸以及任选的空气（即氧气）接触以吸收氮的氧化物。 然后对废弃的酸洗涤液进行相同的除去污染物的过程。
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6.发明授权公开(公告)号：US06352725B1
公开(公告)日：2002-03-05
申请号：US09451344
申请日：1999-11-30
IPC分类号： A01N3900
CPC分类号： C02F1/766 , A01N59/00 , C02F2303/04 , A01N2300/00
摘要： The process involves (a) continuously forming bromine chloride from separate feed streams of bromine and chlorine by maintaining said streams under automatic feed rate control whereby the streams are continuously proportioned to come together in equimolar amounts to form bromine chloride; (b) continuously forming an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine greater than 0.93:1 by continuously feeding into mixing apparatus separate feed streams of (1) bromine chloride formed in (a), and (2) an aqueous solution of alkali metal salt of sulfamic acid, under automatic feed rate control whereby the feed streams are continuously proportioned to come together in amounts that produce an aqueous product having an active bromine content of at least 100,000 ppm (wt/wt), a pH of at least 7, and an atom ratio of nitrogen to active bromine from (1) and (2) greater than 0.93:1; and, (c) withdrawing said aqueous product from said mixing apparatus at a rate sufficient to enable the continuous feeding in (a) and (b) to be maintained.
摘要翻译： 该方法包括（a）通过在自动进料速率控制下将所述物流保持在连续成比例的范围内，以等摩尔量混合形成溴氯化物，从溴和氯的不同进料流中连续形成溴氯化物; （b）连续地形成具有至少100,000ppm（wt / wt）的活性溴含量，至少7的pH以及氮与活性溴的原子比大于0.93:1的含水产物， 在（a）中形成的（1）溴化氯和（2）氨基磺酸的碱金属盐的水溶液的分离进料流，其中进料流被连续地成比例地以一定的量生成 活性溴含量至少为100,000ppm（wt / wt），pH至少为7，氮与活性溴的原子比（1）和（2）大于0.93:1的含水产物; 和（c）以足以使（a）和（b）中的连续进料保持的速率从所述混合装置中取出所述含水产物。
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公开(公告)号：US06299909B1
公开(公告)日：2001-10-09
申请号：US09663948
申请日：2000-09-18
IPC分类号： A01N5902
CPC分类号： A01N59/00 , C02F1/766 , C02F2303/04 , A01N2300/00 , A01N59/02 , A01N25/22
摘要： A concentrated liquid biocide composition is produced by a process which comprises continuously or intermittently feeding (i) bromine chloride into mixing apparatus where the bromine chloride contacts (ii) an aqueous solution of alkali metal salt of sulfamic acid. An aqueous product is produced having an active bromine content of at least 100,000 ppm (wt/wt), and an atom ratio of nitrogen to active bromine from (i) and (ii) greater than 0.93:1. The desired product can be withdrawn from the mixing apparatus continuously or intermittently.
摘要翻译： 浓缩的液体杀生物剂组合物通过包括连续地或间歇地将溴氯化物进料到溴化氯接触（ii）氨基磺酸的碱金属盐的水溶液的混合装置中的方法来生产。 产生具有至少100,000ppm（wt / wt）的活性溴含量和（i）和（ii）的氮与活性溴的原子比大于0.93:1的含水产物。 所需产品可以连续或间歇地从混合设备中取出。
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公开(公告)号：US5693861A
公开(公告)日：1997-12-02
申请号：US78500
申请日：1993-06-21
申请人： Rebecca F. Smith , Y.-D. Mark Chen , R. Woodrow Wilson, Jr. , Mayur P. Shah , Kim R. Smith , Sharon B. McGee
发明人： Rebecca F. Smith , Y.-D. Mark Chen , R. Woodrow Wilson, Jr. , Mayur P. Shah , Kim R. Smith , Sharon B. McGee
IPC分类号： C07C291/04 , C07C291/00
CPC分类号： C07C291/04
摘要： A highly pure, white, solid amine oxide is prepared in high yield with minimal decomposition of the solvent by (A) reacting a tert-amine with a 15-20% stoichiometric excess of concentrated hydrogen peroxide at 50.degree.-55.degree. C. in the presence of controlled amounts of carbon dioxide and ethyl acetate until the reaction mixture contains 35-45 % by weight of ethyl acetate and less than 0.8% by weight of unreacted amine, (B) catalytically decomposing residual hydrogen peroxide, (C) separating the reaction mixture from the decomposition catalyst, (D) cooling the reaction mixture to 0.degree. C. to form a slurry, (E) centrifuging the slurry to separate the amine oxide, and (F) vacuum drying the amine oxide at ambient temperature--the reaction mixture being diluted to an amine oxide content of 25-30% by weight with additional ethyl acetate or a mixture thereof with a co-solvent, such as a low-boiling n-alkane, after the completion of Step A and prior to the beginning of Step D.
摘要翻译： 通过（A）使叔胺与15-20％化学计量过量的浓缩过氧化氢在50-55℃下反应，以高产率制备高纯度的白色固体氧化胺，最小化溶剂分解 存在受控量的二氧化碳和乙酸乙酯，直到反应混合物含有35-45重量％的乙酸乙酯和小于0.8重量％的未反应胺，（B）催化分解残余过氧化氢，（C）将 来自分解催化剂的反应混合物，（D）将反应混合物冷却至0℃以形成浆料，（E）离心浆料以分离氧化胺，和（F）在环境温度下真空干燥氧化胺 - 反应混合物在步骤A完成后，在另外的乙酸乙酯或其混合物与共溶剂如低沸点正烷烃之间稀释至氧化胺含量为25-30重量％，并且在 步骤D的开始
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公开(公告)号：US4568779A
公开(公告)日：1986-02-04
申请号：US601506
申请日：1984-04-18
IPC分类号： C07C29/70 , C07C37/66 , C07F9/06 , C07F9/6581 , C08G79/02 , C07C31/34 , C07C31/36 , C07C31/38
CPC分类号： C08G79/02 , C07C29/70 , C07C37/66 , C07F9/067 , C07F9/65812
摘要： A process for making an alkali metal alkoxide (e.g. sodium alkoxide) of a halogen-substituted alcohol (e.g. fluorine-substituted alcohols) by dispersing an alkali metal (e.g. sodium) in a cycloalkane (e.g. cyclohexane) and adding the resultant dispersion to an ether (e.g. THF) solution of a halogen-substituted alcohol. The resultant alkali metal haloalkoxide solution can be reacted with a phosphonitrilic chloride polymer to introduce haloalkoxide substituents.
摘要翻译： 通过将碱金属（例如钠）分散在环烷烃（例如环己烷）中制备卤素取代的醇（例如氟取代的醇）的碱金属醇盐（例如烷氧基化钠）的方法，并将所得分散体加入到醚 （例如THF）溶液。 得到的碱金属卤代醇盐溶液可与磷酰氯化聚合物反应以引入卤代醇盐取代基。
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公开(公告)号：US5204307A
公开(公告)日：1993-04-20
申请号：US820191
申请日：1992-01-13
IPC分类号： B01J31/14 , C07C209/68
CPC分类号： C07C209/68 , B01J31/143 , B01J2231/4205
摘要： Production of alkyl substituted aromatic diamines by reacting triethlyaluminum with an aromatic diamine and a chloride ion source in the presence of an olefin is disclosed. The alkyl substituted aromatic diamines are useful as chain extenders in polyurethane processes.
摘要翻译： 公开了通过三烯丙基铝与芳族二胺和氯离子源在烯烃存在下反应制备烷基取代的芳族二胺。 烷基取代的芳族二胺可用作聚氨酯方法中的扩链剂。
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