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    Phosphorous flame retardant and application thereof to polymer
    2.
    发明授权
    Phosphorous flame retardant and application thereof to polymer 有权

    公开(公告)号：US08487043B2

    公开(公告)日：2013-07-16

    申请号：US12751987

    申请日：2010-03-31

    申请人： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

    发明人： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

    IPC分类号： C08K5/5399 ,  C07F9/02 ,  C09K21/12

    CPC分类号： C09K21/12 ,  C07F9/067 ,  C08K5/5399 ,  C08L63/00

    摘要： A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.

    Phosphazene compound, photosensitive resin composition and use thereof
    3.
    发明授权
    Phosphazene compound, photosensitive resin composition and use thereof 有权
    磷腈化合物，感光性树脂组合物及其用途

    公开(公告)号：US08063245B2

    公开(公告)日：2011-11-22

    申请号：US10559737

    申请日：2004-06-03

    申请人： Koji Okada ,  Toshio Yamanaka

    发明人： Koji Okada ,  Toshio Yamanaka

    IPC分类号： C07F9/547

    CPC分类号： C08G79/025 ,  C07F9/067 ,  C07F9/65812 ,  G03F7/027 ,  G03F7/032 ,  G03F7/037 ,  G03F7/0388

    摘要： Disclosed is a phosphazene compound and a photosensitive resin composition. The phosphazene compound is obtained by reacting a phenoxyphosphazene compound (A-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (A-2) obtained by cross-linking the phenoxyphosphazene compound (A-1) with an epoxy compound (B) having an unsaturated double bond and/or an isocyanate compound (C), wherein the phosphazene compound has an unsaturated double bond in its molecule. The photosensitive resin composition includes at least: a soluble polyimide resin (G-1) having a carboxyl group and/or a hydroxyl group and is soluble in an organic solvent, as the polyimide resins (G); and a phenoxyphosphazene compound (H-1) having a phenolic hydroxyl group and/or a cross-linked phenoxyphosphazene compound (H-2), which is obtained by cross-linking the phenoxyphosphazene compound (H-1) and has at least one phenolic hydroxyl group, as the phosphazene compound (H), and the photosensitive resin composition further includes a (meth)acrylic compound (L).

    摘要翻译： 公开了磷腈化合物和感光性树脂组合物。 通过使具有酚羟基的苯氧基磷腈化合物（A-1）和/或通过将苯氧基磷腈化合物（A-1）交联而获得的交联的苯氧基磷腈化合物（A-2）与环氧化合物 具有不饱和双键的化合物（B）和/或异氰酸酯化合物（C），其中磷腈化合物在其分子中具有不饱和双键。 作为聚酰亚胺树脂（G），感光性树脂组合物至少包括具有羧基和/或羟基并且可溶于有机溶剂的可溶性聚酰亚胺树脂（G-1）。 和具有酚羟基的苯氧基磷腈化合物（H-1）和/或交联的苯氧基磷腈化合物（H-2），其是通过交联苯氧基磷腈化合物（H-1）而得到的，并具有至少一种酚 羟基作为磷腈化合物（H），感光性树脂组合物还含有（甲基）丙烯酸系化合物（L）。

    PHOSPHOROUS FLAME RETARDANT AND APPLICATION THEREOF TO POLYMER
    4.
    发明申请
    PHOSPHOROUS FLAME RETARDANT AND APPLICATION THEREOF TO POLYMER 有权
    磷光阻燃剂及其应用于聚合物

    公开(公告)号：US20100256268A1

    公开(公告)日：2010-10-07

    申请号：US12751987

    申请日：2010-03-31

    申请人： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

    发明人： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

    IPC分类号： C08K5/5399 ,  C07F9/02 ,  C09K21/12

    CPC分类号： C09K21/12 ,  C07F9/067 ,  C08K5/5399 ,  C08L63/00

    摘要： A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.

    摘要翻译： 磷阻燃剂主要包括具有聚（氧化烯）胺替代物的六氯三磷腈（HCP）。 聚（氧化烯）胺包括至少两个端基。 磷阻燃剂还可以包括层状硅酸盐粘土。 层状硅酸盐粘土可以用HCP的聚（氧化烯）胺替代物插层和改性，以有效地促进热稳定性。 阻燃剂，磷腈 - 聚（氧化烯）胺加合物可以应用于聚合物。 通过它们之间的交联，可以提高聚合物的阻燃性能。 还提供了制备磷腈 - 聚（氧化烯）胺加合物的阻燃剂的方法及其在聚合物中的应用。

    Process for producing aryloxy-substituted phosphazene derivatives
    5.
    发明授权
    Process for producing aryloxy-substituted phosphazene derivatives 失效
    制备芳氧基取代的磷腈衍生物的方法

    公开(公告)号：US5075453A

    公开(公告)日：1991-12-24

    申请号：US401570

    申请日：1989-08-29

    申请人： Shinichiro Ueyama ,  Kazuhiko Fujikawa ,  Yasuhiro Yoshikawa ,  Tetsuhiko Okamoto ,  Masayuki Furukawa ,  Tadaichi Nishikawa

    发明人： Shinichiro Ueyama ,  Kazuhiko Fujikawa ,  Yasuhiro Yoshikawa ,  Tetsuhiko Okamoto ,  Masayuki Furukawa ,  Tadaichi Nishikawa

    IPC分类号： C07F9/06 ,  C07F9/6581 ,  C08G79/02 ,  C10M105/74

    CPC分类号： C07F9/65814 ,  C07F9/067 ,  C08G79/025 ,  C10M105/74

    摘要： A process for producing an aryloxy-substituted phosphazene derivative represented by the formula(N.dbd.P).sub.n (OAr).sub.l Cl.sub.m-l R.sup.1.sub.p (III)which comprises reacting a chlorophosphazene derivative represented by the general formula(N.dbd.P).sub.n Cl.sub.m R.sup.1.sub.p (I)with, a hydroxy aryl compound represented by the general formulaHOAr (II)whereR.sup.1 represents hydroxy group, NH.sub.2 group, --OR.sup.4 group, --SR.sup.4 group or ##STR1## group, where R.sup.4, R.sup.5 and R.sup.6 represent independently an alkyl group, an alkenyl group, alkynyl group or an aryl group or one of R.sup.5 or R.sup.6 may be hydrogen or R.sup.5 and R.sup.6 may form, together with a nitrogen atom bonded thereto, a saturated or an unsaturated heterocyclic ring,n is an integer of 3 to 20,m is an integer of 1 to 2n,p is 2n-m,Ar represents substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl, or substituted or unsubstituted N-maleimidophenyl,l is an integer of 1 to m,wherein the reaction is carried out under the presence of an acid acceptor and a pyridine derivative represented by the formula ##STR2## where Q.sup.1 and Q.sup.2 represent identical or different lower alkyl groups or constitute together with a nitrogen atom bonded thereto, a pyrrolidine ring, piperidine ring or morpholine ring.

    摘要翻译： 一种制备由式（N = P）n（OAr）1 Clm-lR1p（III）表示的芳氧基取代的磷腈衍生物的方法，其包括使由通式（N = P）nClmR1p（I）表示的氯代膦腈衍生物 与通式为HOAr（II）表示的羟基芳基化合物，其中R 1表示羟基，NH 2基，-OR 4基团，-SR 4基团或基团，其中R 4，R 5和R 6独立地表示烷基， 烯基，炔基或芳基，或者R 5或R 6中的一个可以是氢或R 5，R 6可以与其键合的氮原子一起形成饱和或不饱和杂环，n为3〜20的整数， m为1〜2n的整数，p为2n-m，Ar表示取代或未取代的苯基，取代或未取代的萘基，或取代或未取代的N-马来酰亚胺基苯基，l为1〜m的整数，其中， 在酸受体和吡啶衍生物代表的存在下 其中Q1和Q2表示相同或不同的低级烷基，或与其键合的氮原子一起构成吡咯烷环，哌啶环或吗啉环。

    Decolorization of polymeric phosphazenes with ozone
    6.
    发明授权
    Decolorization of polymeric phosphazenes with ozone 失效
    聚合氢氧化物与臭氧的分解

    公开(公告)号：US3839513A

    公开(公告)日：1974-10-01

    申请号：US29288172

    申请日：1972-09-28

    申请人： FMC CORP

    发明人： PATEL V

    IPC分类号： C08J3/00 ,  C07F9/06 ,  C07F9/6581 ,  C08G79/02 ,  C07D105/04 ,  C08B21/20

    CPC分类号： C07F9/067 ,  C07F9/65812 ,  C08G79/025

    摘要： 1. A PROCESS FOR DECOLORIZING POLYMERIC PHOSPHAZENES COMPRISING CONTACTING THE PHOSPHAZENE WITH OZONE IN WHICH THE POLYMERIC PHOSPHAZES ARE REPRESENTED BY THE GENERAL FORMULA

    -(N=P(-X)(-Y))N-

    REPRESENTING BOTH CYCLIC AND LINEAR POLYMERS IN WHICH GENERAL FORMULA N IS 3 OR MORE, OFTEN 3 TO 14, BUT SUBSTANTIALLY 3 TO 6, AND X AND Y REPRESENT THE SAME OR DIFFERENT-OR GROUPS WHERE R REPRESENTS AN ALKYL OR CHLOROALKYL RADICAL HAVING FROM 1 TO 12 CARBON ATOMS.

    FLAME-RETARDANT POLYAMIDE RESIN COMPOSITION AND MOLDED ARTICLE
    8.
    发明申请
    FLAME-RETARDANT POLYAMIDE RESIN COMPOSITION AND MOLDED ARTICLE 有权
    阻燃聚酰胺树脂组合物和成型品

    公开(公告)号：US20100069539A1

    公开(公告)日：2010-03-18

    申请号：US12517493

    申请日：2007-12-04

    申请人： Kei Morimoto ,  Yasushi Yamanaka

    发明人： Kei Morimoto ,  Yasushi Yamanaka

    IPC分类号： C08K5/3492 ,  C08K5/51 ,  C08K5/49

    CPC分类号： C08K5/49 ,  C07F9/067 ,  C07F9/301 ,  C08J5/043 ,  C08L71/126 ,  C08L77/00 ,  C08L2666/20

    摘要： To provide a flame-retardant polyamide resin composition generally excellent in flame resistance, mechanical characteristics and electrical characteristics, and suitable for electrics/electronics components and vehicles. Used is a flame-retardant polyamide resin composition comprising, a polyamide resin (A), a phosphorus-containing flame retarder (B), and glass fiber having a non-circular cross-section (C), wherein the contents in the composition are 15 to 78% by weight for the polyamide resin (A), 2 to 20% by weight for the phosphorus-containing flame retarder (B), and 20 to 65% by weight for the glass fiber having a non-circular cross-section (C).

    摘要翻译： 提供通常具有优异的阻燃性，机械特性和电特性的阻燃聚酰胺树脂组合物，并且适用于电气/电子部件和车辆。 使用的是阻燃聚酰胺树脂组合物，其包含聚酰胺树脂（A），含磷阻燃剂（B）和具有非圆形横截面（C）的玻璃纤维，其中组合物中的含量为 对于聚酰胺树脂（A）为15〜78重量％，含磷阻燃剂（B）为2〜20重量％，对于具有非圆形截面的玻璃纤维为20〜65重量％ （C）。

    PROCESS FOR PRODUCING POLY (ALKYLENE OXIDE) IN THE PRESENCE OF A PHOSPHAZENIUM SALT OR COMPOUND
    10.
    发明申请
    PROCESS FOR PRODUCING POLY (ALKYLENE OXIDE) IN THE PRESENCE OF A PHOSPHAZENIUM SALT OR COMPOUND 有权
    在磷酸盐或化合物存在下生产聚（亚烷基氧化物）的方法

    公开(公告)号：US20030105361A1

    公开(公告)日：2003-06-05

    申请号：US09366046

    申请日：1999-08-02

    发明人： TADAHITO NOBORI ,  MASAHIRO KOUNO ,  TOSHIAKI SUZUKI ,  KAZUMI MIZUTANI ,  SHINJI KIYONO ,  YOSHIHO SONOBE ,  USAJI TAKAKI

    IPC分类号： C07F009/02 ,  C07C041/03

    CPC分类号： C07F9/065 ,  C07F9/067 ,  C08G65/2675

    摘要： The present invention provides a novel salt useful as an active species in an organic reaction and represented by the following chemical formula (1): 1 wherein n stands for an integer of from 1 to 8, Znnull represents an n-valent anion of an active hydrogen compound, a, b, c and d each stands for a positive integer, and Rs represent the same or different hydrocarbon groups. Also disclosed is a simple and efficient process for producing a poly(alkylene oxide) by polymerizing an alkylene oxide compound in the presence of the salt represented by the chemical formula (1).

    摘要翻译： 本发明提供了可用作有机反应中的活性物质的新型盐，由以下化学式（1）表示：其中n表示1至8的整数，Zn表示活性的n价阴离子 氢化合物，a，b，c和d分别表示正整数，Rs表示相同或不同的烃基。 还公开了通过在化学式（1）表示的盐的存在下聚合烯化氧化合物来制备聚（环氧烷）的简单和有效的方法。