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1.发明授权Cocatalyst for transition metal-containing .alpha.-olefin polymerization catalyst 失效含过渡金属的α-烯烃聚合催化剂的助催化剂
公开(公告)号：US5344803A
公开(公告)日：1994-09-06
申请号：US11046
申请日：1993-01-29
申请人： Raghu Menon , Albert P. Masino , Mark K. Reinking
发明人： Raghu Menon , Albert P. Masino , Mark K. Reinking
CPC分类号： B01J37/033 , B01J23/10
摘要： The present invention is directed to a novel halosilane cocatalyst component which, when used in conjunction with an aluminum containing cocatalyst, is effective in increasing the activity of a supported magnesium/titanium containing catalyst in the polymerization of ethylene and .alpha.-olefins. In addition to the increased catalytic activity, the polymers produced by the present invention are characterized as having an unexpected enhancement in the polymer melt index. Thus, the catalyst system of the instant invention represents an advancement in the art in view of the combination of increased activity, i.e., yield of polymer produced, and physical properties of the polyolefin product.In another aspect of the present invention, a process for polymerizing .alpha.-olefins is disclosed. In this process at least one olefin is polymerized under olefin polymerization conditions utilizing the catalyst system of the present invention, which includes the solid catalyst component of the present invention, along with the first cocatalyst, an aluminum-containing compound, and the second cocatalyst, a halosilane compound.
摘要翻译： 本发明涉及一种新型卤代硅烷助催化剂组分，当与含铝助催化剂结合使用时，可有效提高在乙烯和α-烯烃聚合中负载的含镁/钛的催化剂的活性。 除了增加的催化活性之外，本发明生产的聚合物的特征在于聚合物熔体指数具有意想不到的增强。 因此，鉴于增加的活性，即所生产的聚合物的产率和聚烯烃产品的物理性能的组合，本发明的催化剂体系代表了本领域的进步。 在本发明的另一方面，公开了聚合α-烯烃的方法。 在该方法中，使用本发明的催化剂体系在烯烃聚合条件下聚合至少一种烯烃，其包括本发明的固体催化剂组分以及第一助催化剂，含铝化合物和第二助催化剂， 卤代硅烷化合物。
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公开(公告)号：US5334567A
公开(公告)日：1994-08-02
申请号：US10740
申请日：1993-01-29
申请人： Raghu Menon , Albert P. Masino , Mark K. Reinking
发明人： Raghu Menon , Albert P. Masino , Mark K. Reinking
CPC分类号： B01J31/143 , B01J31/128 , B01J31/1608 , B01J31/1616 , B01J31/2226 , B01J37/031 , C08F10/00 , B01J2531/56
摘要： The present invention is directed to a novel halosilane cocatalyst component which may be used in conjunction with an aluminum-containing cocatalyst to provide enhanced catalytic activity of a vanadium based solid catalyst component in the polymerization of .alpha.-olefins. In addition to the enhancement in the catalytic activity obtaining using the present catalyst system, the resultant polymer produced by the present invention exhibits improved physical properties compared with polymers produced by prior art vanadium based catalyst systems. Thus, the catalyst system of the instant invention represents an advance in the art in view of the combination of increased catalytic activity, i.e. yield of polymer produced, and enhanced physical properties of the polyolefin produced.In accordance with the present invention, a catalyst system is provided which comprises a solid catalyst component and a halosilane cocatalyst component. The solid catalyst component of the present invention is the product formed by admixing a solid inorganic oxide, an organometallic compound, a vanadium-containing compound and an organic reagent.In another aspect of the present invention, a process of the polymerization of .alpha.-olefins is disclosed. In this process at least one olefin is polymerized under olefin polymerization catalyst utilizing the catalyst system of the present invention, which includes the solid catalyst component of the present invention, and a cocatalyst selected from the group consisting of halosilane compounds and admixtures thereof with aluminum compounds.
摘要翻译： 本发明涉及一种可与含铝助催化剂结合使用的新的卤代硅烷助催化剂组分，以在α-烯烃的聚合中提供钒基固体催化剂组分的增强的催化活性。 除了使用本发明的催化剂体系提高催化活性获得之外，与现有技术的钒基催化剂体系制备的聚合物相比，本发明生产的聚合物显示出改善的物理性能。 因此，鉴于增加的催化活性（即所生产的聚合物的产率）和所生产的聚烯烃的增强的物理性质的组合，本发明的催化剂体系代表了本领域的进步。 根据本发明，提供了一种催化剂体系，其包括固体催化剂组分和卤代硅烷助催化剂组分。 本发明的固体催化剂成分是通过混合固体无机氧化物，有机金属化合物，含钒化合物和有机试剂而形成的产物。 在本发明的另一方面，公开了α-烯烃的聚合方法。 在该方法中，使用本发明的催化剂体系在烯烃聚合催化剂下聚合至少一种烯烃，其包括本发明的固体催化剂组分和选自卤代硅烷化合物及其与铝化合物的混合物的助催化剂 。
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公开(公告)号：US5675052A
公开(公告)日：1997-10-07
申请号：US528959
申请日：1995-09-15
摘要： A hydrocarbon stream is cracked to produce a hot gaseous stream which is compressed and cooled to condense almost all of the hydrocarbons contained in the stream. A noncondensed stream remaining after the condensation step, comprised predominantly of hydrogen and C.sub.1 to C.sub.3 hydrocarbons, is subjected to pressure swing adsorption or temperature swing adsorption at an adsorption temperature of about 0.degree. to about 250.degree. C. in a bed of adsorbent which selectively adsorbs ethene and propene, thereby adsorbing substantially all of the ethene and propene from the gas stream. The ethene and/or propene is recovered upon bed regeneration. Higher alkenes are separated from alkanes by various methods.
摘要翻译： 烃流被裂化以产生热气流，其被压缩和冷却以使包含在流中的几乎所有的烃都冷凝。 在主要由氢和C1至C3烃组成的缩合步骤之后残留的非冷凝流在吸附床中在约0至约250℃的吸附温度下进行变压吸附或变温吸附，其选择性 吸附乙烯和丙烯，从而从气流中吸收基本上所有的乙烯和丙烯。 在床再生时回收乙烯和/或丙烯。 高级烯烃通过各种方法与烷烃分离。
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公开(公告)号：US5534472A
公开(公告)日：1996-07-09
申请号：US412633
申请日：1995-03-29
申请人： Linda N. Winslow , Douglas D. Klendworth , Raghu Menon , Michael W. Lynch , Garry L. Fields , Kenneth W. Johnson
发明人： Linda N. Winslow , Douglas D. Klendworth , Raghu Menon , Michael W. Lynch , Garry L. Fields , Kenneth W. Johnson
CPC分类号： B01J31/2226 , B01J31/128 , B01J31/143 , B01J31/1616 , C08F10/00 , B01J2531/56 , C08F210/16
摘要： A vanadium-containing catalyst system particularly suited to the polymerization of blow moldable olefin polymers. The catalyst system includes a supported, first catalyst component prepared by contacting preheated silica, with (1) a compound or complex which includes at least one carbon to magnesium covalent bond and (2) a compound which includes at least one carbon to Group III metal covalent bond. The sequence of contact of the silica with compound or complex (1) and compound (2) is optional. However, unless the compound or complex (1) and the compound (2) contact the silica simultaneously, the product of this contact is next contacted with whichever of compound (1) or (2) does not initially contact the silica. The product of the step of contacting with compounds (1) and (2) is contacted with a vanadium compound which includes at least one halogen atom. Finally, the product of the vanadium compound contacting step is contacted with an alcohol. A second component of the catalyst system is an organoaluminum compound cocatalyst. The catalyst system also includes a halocarbon compound promoter as a third catalyst component.
摘要翻译： 一种特别适用于可吹塑烯烃聚合物聚合的含钒催化剂体系。 催化剂体系包括通过使预热的二氧化硅与（1）包含至少一个碳 - 镁共价键的化合物或络合物接触而制备的负载的第一催化剂组分和（2）包含至少一个碳至III族金属的化合物 共价键。 二氧化硅与化合物或络合物（1）和化合物（2）的接触顺序是任选的。 然而，除非化合物或络合物（1）和化合物（2）同时与二氧化硅接触，否则接触的产物接下来与化合物（1）或（2）中最初不接触二氧化硅的化合物接触。 与化合物（1）和（2）接触的步骤的产物与包含至少一个卤素原子的钒化合物接触。 最后，将钒化合物接触步骤的产物与醇接触。 催化剂体系的第二个组分是有机铝化合物助催化剂。 催化剂体系还包括作为第三催化剂组分的卤代烃化合物促进剂。
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公开(公告)号：US5346872A
公开(公告)日：1994-09-13
申请号：US10737
申请日：1993-01-29
申请人： Raghu Menon , Albert P. Masino , Mark K. Reinking
发明人： Raghu Menon , Albert P. Masino , Mark K. Reinking
CPC分类号： B01J31/2226 , B01J31/0212 , B01J31/128 , B01J31/143 , B01J31/1616 , C08F110/02 , B01J2531/46 , B01J2531/56
摘要： The present invention relates to a novel catalyst component for ethylene polymerization comprising vanadium and titanium. Moreover, when the vanadium/titanium containing catalyst of the present invention is employed with an aluminum-containing cocatalyst enhanced activity as well as melt index is obtained.The present invention is directed to a novel halosilane cocatalyst component which, when used in conjunction with an aluminum containing cocatalyst, is effective in increasing the activity of a silica supported titanium/vanadium containing solid catalyst component in the polymerization of ethylene and/or .alpha.-olefins. In addition to the increased catalytic activity, the polymers produced by the present invention exhibit improved melt index values compared with melt index values typically obtained using prior art catalyst systems. Thus, the catalyst system of the instant invention represent an advancement in the art in view of the combination of increased activity, i.e., yield of polymer produced, and physical properties of the polyolefin product.In another aspect of the present invention, a process for polymerizing ethylene and/or .alpha.-olefins is disclosed. In this process at least one olefin is polymerized under olefin polymerization conditions utilizing the catalyst system of the present invention, which includes the solid catalyst component of the present invention, along with the first cocatalyst, an aluminum-containing compound, and the second cocatalyst, a halosilane.
摘要翻译： 本发明涉及包含钒和钛的乙烯聚合新型催化剂组分。 此外，当使用本发明的含钒/钛的催化剂与含铝助催化剂增强活性以及熔体指数一起使用时。 本发明涉及一种新型卤代硅烷助催化剂组分，当与含铝助催化剂结合使用时，可有效地提高二氧化硅负载的含钛/钒的固体催化剂组分在乙烯和/或α-烯烃聚合中的活性， 烯烃。 除了增加的催化活性之外，与通常使用现有技术催化剂体系获得的熔体指数值相比，本发明生产的聚合物显示出改善的熔体指数值。 因此，本发明的催化剂体系代表了本领域的进步，考虑到增加的活性，即所生产的聚合物的产率和聚烯烃产品的物理性质的组合。 在本发明的另一方面，公开了一种聚合乙烯和/或α-烯烃的方法。 在该方法中，使用本发明的催化剂体系在烯烃聚合条件下聚合至少一种烯烃，其包括本发明的固体催化剂组分以及第一助催化剂，含铝化合物和第二助催化剂， 卤代硅烷。
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6.发明授权Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol 失效支持的高活性聚烯烃催化剂组分，其具有规则的镁值分布，其利用受控的干燥方案提供
公开(公告)号：US5275991A
公开(公告)日：1994-01-04
申请号：US984052
申请日：1992-11-30
CPC分类号： C08F10/00
摘要： A novel catalyst support and a method for preparation thereof, characterized by the presence of selected amounts of a hydrocarbon soluble magnesium-containing compound applied to the support relative to solvent, wherein a surface uniformly and essentially continuously moistened with the solvated magnesium compound in a condition of incipient precipitation to permit the formation of a regular essentially continuous distribution of the magnesium compound onto and conforming to the support material. The drying process under these conditions is effective in maintaining to a high degree the effective surface area and pore volume of the material. The support containing the adsorbed magnesium is then dried in a controlled manner to essential incipient wetness conditions providing a regular spatial distribution of stacked reticular magnesium values at a level of one to five molecular monolayers on the support.A representative process for polymerizing or copolymerizing olefins providing stereospecific polymers such as propylene is disclosed.
摘要翻译： 一种新颖的催化剂载体及其制备方法，其特征在于存在相对于溶剂施加到载体上的选择量的可溶于烃的可溶性镁化合物，其中表面在溶剂化镁化合物的条件下均匀且基本上连续地润湿 初始沉淀以允许形成规则的基本上连续的镁化合物分布到载体材料上并与之相符合。 在这些条件下的干燥过程有效地保持材料的有效表面积和孔体积的高度。 然后将含有吸附的镁的载体以受控的方式干燥至必需的初始湿度条件，从而提供在载体上1-5个分子单层水平的堆叠网状镁值的规则空间分布。 公开了提供立体特异性聚合物如丙烯的烯烃聚合或共聚的代表性方法。
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