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公开(公告)号:US5675052A
公开(公告)日:1997-10-07
申请号:US528959
申请日:1995-09-15
摘要: A hydrocarbon stream is cracked to produce a hot gaseous stream which is compressed and cooled to condense almost all of the hydrocarbons contained in the stream. A noncondensed stream remaining after the condensation step, comprised predominantly of hydrogen and C.sub.1 to C.sub.3 hydrocarbons, is subjected to pressure swing adsorption or temperature swing adsorption at an adsorption temperature of about 0.degree. to about 250.degree. C. in a bed of adsorbent which selectively adsorbs ethene and propene, thereby adsorbing substantially all of the ethene and propene from the gas stream. The ethene and/or propene is recovered upon bed regeneration. Higher alkenes are separated from alkanes by various methods.
摘要翻译: 烃流被裂化以产生热气流,其被压缩和冷却以使包含在流中的几乎所有的烃都冷凝。 在主要由氢和C1至C3烃组成的缩合步骤之后残留的非冷凝流在吸附床中在约0至约250℃的吸附温度下进行变压吸附或变温吸附,其选择性 吸附乙烯和丙烯,从而从气流中吸收基本上所有的乙烯和丙烯。 在床再生时回收乙烯和/或丙烯。 高级烯烃通过各种方法与烷烃分离。
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公开(公告)号:US5417742A
公开(公告)日:1995-05-23
申请号:US160999
申请日:1993-12-03
IPC分类号: B01D53/04 , B01D53/047 , C07C17/38
CPC分类号: C07C17/38 , B01D53/0462 , B01D53/047 , C07C17/389 , B01D2253/108 , B01D2253/30 , B01D2253/308 , B01D2257/2066 , B01D2259/4006 , B01D2259/40064 , Y02C20/30 , Y02P20/154 , Y02P20/155 , Y10S95/902 , Y10S95/903
摘要: Perfluorocarbons are recovered from gas streams by subjecting the gas stream to an adsorption process in a bed of one or more energetically homogeneous adsorbents such as silicon-rich adsorbents of the FAU structure, silicon-rich adsorbents of the BEA structure, silicon-rich adsorbents of the MOR structure. The adsorption process is preferably pressure swing adsorption or temperature swing adsorption.
摘要翻译: 通过使气流在一种或多种能量均匀的吸附剂的床中进行吸附过程,例如FAU结构的富硅吸附剂,BEA结构的富含硅吸附剂,富含硅的吸附剂的富含硅的吸附剂,从气流中回收全氟化碳 MOR结构。 吸附过程优选为变压吸附或变温吸附。
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公开(公告)号:US5992478A
公开(公告)日:1999-11-30
申请号:US679417
申请日:1996-07-08
申请人: Andre Micke , Martin Bulow
发明人: Andre Micke , Martin Bulow
CPC分类号: B01F15/00357 , B01F3/026 , F17C5/06 , F17C2201/0109 , F17C2201/0119 , F17C2205/0326 , F17C2205/0338 , F17C2221/014 , F17C2221/016 , F17C2221/017 , F17C2221/03 , F17C2227/0114 , F17C2250/043 , F17C2250/0443 , F17C2250/0626 , F17C2250/0636 , F17C2260/024 , F17C2265/025
摘要: Gas cylinders are filled with mixtures of gases comprising a minor component, which is to be present in the mixture at a concentration of 10% or less of the total volume of the cylinder, and a major component, which is to be present at a concentration greater than about 10% of the total volume, by charging the lighter component into a chamber of given volume to a pressure and at a temperature such that the volume provides the desired fraction of minor component in the gas mixture, and then flushing the minor component into the cylinder using major component gas as the flushing agent. The pressure at which the minor component volume is to be measured is preferably at or near the final pressure of the filled gas cylinder.
摘要翻译: 气瓶装有气体的混合物,该气体包含少量组分,该组分以混合物的总体积的10%或更低的浓度存在于混合物中,主要组分以浓度存在 大于总体积的约10%,通过将较轻组分装入给定体积的室至压力和温度,使得体积在气体混合物中提供所需的次要组分,然后冲洗次要组分 使用主要组分气体作为冲洗剂进入气缸。 要测量次要组分体积的压力优选处于或接近填充气瓶的最终压力。
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公开(公告)号:US5531808A
公开(公告)日:1996-07-02
申请号:US363187
申请日:1994-12-23
申请人: Adeola F. Ojo , Frank R. Fitch , Martin Bulow
发明人: Adeola F. Ojo , Frank R. Fitch , Martin Bulow
IPC分类号: B01D53/02 , B01D53/04 , B01D53/26 , B01J20/08 , B01J20/10 , B01J20/18 , F25J3/04 , F25J3/08 , B01D53/047
CPC分类号: B01D53/04 , B01D2253/108 , B01D2253/1085 , B01D2253/30 , B01D2257/50 , B01D2257/504 , B01D2257/80 , B01D2259/40083 , B01D2259/401 , B01D2259/402 , B01D2259/416 , B01D53/02 , B01D53/0462 , B01D53/047 , Y02C10/04 , Y02C10/08 , Y10S95/902
摘要: Carbon dioxide is removed from gas streams comprised predominantly of gases that are less polar than carbon dioxide by passing the gas stream through a bed of type X zeolite having a silicon to aluminum atomic ratio not greater than about 1.15, thereby adsorbing the carbon dioxide from the gas stream. The process is particularly advantageous when applied to the removal of low levels of carbon dioxide from gas streams at temperatures above 20.degree. C.
摘要翻译: 通过使气流通过硅与铝原子比不大于约1.15的X型沸石床,从主要由二氧化碳极性小的气体中除去二氧化碳,从而吸附二氧化碳 气流。 当应用于在高于20℃的温度下从气流中除去低水平的二氧化碳时,该方法是特别有利的。
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公开(公告)号:US20050176589A1
公开(公告)日:2005-08-11
申请号:US11005579
申请日:2004-12-06
申请人: Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
发明人: Martin Bulow , Jurgen Boer , Wolfgang Burckhardt , Hans Guth , Helmut Ullmann , Vladimir Vashook
CPC分类号: C01B13/0255 , C01B3/382 , C01B2203/0244 , C01B2203/0844 , C01B2203/1258 , C01B2203/142 , C01B2203/82 , C01B2210/0046 , Y10S502/525
摘要: Composites and methods useful for oxygen sorption and other uses are presented, the composites comprising: (A) one or more crystalline ceramic oxides selected from compounds within general formula (1): AxA′x′ByB′y′O3-δ (1) and (B) one or more crystalline ceramic oxides selected from compounds within general formulas (2), (3), (4), (5), (6), (7), and (8): A2BO4-δ (2) A2B2O5-δ (3) AO(ABO3-δ)n (4) AM2Cu3O7-δ (5) Bi4V2(1-x)Me2xO11-3x, (6) A″B″O3 (7) A2B2O7-δ (8)
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公开(公告)号:US06350298B1
公开(公告)日:2002-02-26
申请号:US09426994
申请日:1999-10-26
申请人: Bao-Lian Su , Martin Bulow , Jean-Luc Blin , Adeola F. Ojo , Sudhakar Jale , Dongmin Shen , Qing Min Wang , Frank R. Fitch
发明人: Bao-Lian Su , Martin Bulow , Jean-Luc Blin , Adeola F. Ojo , Sudhakar Jale , Dongmin Shen , Qing Min Wang , Frank R. Fitch
IPC分类号: B01D53047
CPC分类号: B01D53/02 , B01D53/0462 , B01D53/047 , B01D2253/104 , B01D2253/108 , B01D2253/112 , B01D2256/12 , B01D2257/102 , B01D2257/402 , B01D2257/502 , B01D2257/504 , B01J20/186 , Y02C10/08 , Y02C20/10 , Y10S95/902
摘要: Novel compositions of molecular sieve adsorbents are provided in which at least 50% of the exchangeable cations are selected from those of Li, Ca, Ag and Cu and which have within their pore system metal oxide, metal oxide precursors or mixtures thereof. These compositions are useful for the separation of gases and, in particular, the separation of nitrogen from air to produce oxygen or oxygen-enriched gas.
摘要翻译: 提供分子筛吸附剂的新型组合物,其中至少50%的可交换阳离子选自Li,Ca,Ag和Cu的那些,并且在它们的孔体系内具有金属氧化物,金属氧化物前体或其混合物。 这些组合物可用于分离气体,特别是氮气与空气分离以产生氧气或富氧气体。
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公开(公告)号:US6024781A
公开(公告)日:2000-02-15
申请号:US62338
申请日:1998-04-17
申请人: Martin Bulow , Chang Jie Guo , Dongmin Shen , Frank R. Fitch , Arthur I. Shirley , Alberto I. La Cava , Silvia Beatriz Dougill , Jonathan Paul Brooks
发明人: Martin Bulow , Chang Jie Guo , Dongmin Shen , Frank R. Fitch , Arthur I. Shirley , Alberto I. La Cava , Silvia Beatriz Dougill , Jonathan Paul Brooks
IPC分类号: B01D53/04 , B01D53/047
CPC分类号: B01D53/04 , B01D2253/108 , B01D2256/24 , B01D2257/504 , B01D2259/40086 , B01D53/0462 , B01D53/047 , Y02C10/08 , Y10S95/902
摘要: Carbon dioxide is separated from gaseous hydrocarbons by a cyclic adsorption process using at a temperature in the range of about -50 to about 200.degree. C., wherein the adsorption step of the process is conducted by passing the gas mixture through an adsorption zone containing carbon molecular sieve or type A zeolite whose exchangeable cations are made up of about 50 to about 90% sodium ions and about 10 to about 50 percent potassium ions.
摘要翻译: 二氧化碳通过循环吸附法在约-50至约200℃的温度范围内与气态烃分离,其中该方法的吸附步骤是通过使气体混合物通过含有碳的吸附区进行的 分子筛或A型沸石,其可交换阳离子由约50至约90%的钠离子和约10至约50%的钾离子组成。
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公开(公告)号:US5587003A
公开(公告)日:1996-12-24
申请号:US407817
申请日:1995-03-21
申请人: Martin Bulow , Loc Dao , Frank R. Fitch
发明人: Martin Bulow , Loc Dao , Frank R. Fitch
IPC分类号: B01D53/02 , B01D53/04 , B01J21/16 , B01D53/047
CPC分类号: B01D53/04 , B01D2253/108 , B01D2256/10 , B01D2256/12 , B01D2256/18 , B01D2256/24 , B01D2257/504 , B01D2259/416 , B01D53/02 , Y02C10/04 , Y02C10/06 , Y02C10/08 , Y10S95/902
摘要: Carbon dioxide is removed from a gas stream by passing the gas stream through a bed of natural or synthetic clinoptilolite or their chemically-modified derivatives. The process is particularly advantageous when applied to the removal of ppm levels of carbon dioxide from gas streams at temperatures above 20.degree. C.
摘要翻译: 通过使气流通过天然或合成斜发沸石床或其化学修饰的衍生物从气流中除去二氧化碳。 当应用于在高于20℃的温度从气流中除去ppm水平的二氧化碳时,该方法是特别有利的。
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公开(公告)号:US20050203327A1
公开(公告)日:2005-09-15
申请号:US11070466
申请日:2005-03-02
申请人: Stevan Jovanovic , Kirk Limbach , Ravi Jain , Frank Fitch , Martin Bulow , Seungdoo Park
发明人: Stevan Jovanovic , Kirk Limbach , Ravi Jain , Frank Fitch , Martin Bulow , Seungdoo Park
CPC分类号: B01D53/04 , B01D53/0462 , B01D53/047 , B01D53/0476 , B01D2253/108 , B01D2253/308 , B01D2256/24 , B01D2259/40001
摘要: The present invention provides for a process of separating hydrocarbons such as short chain paraffins and olefins from non-hydrocarbon gases using short-cycle time concentration swing adsorption processes. The hydrocarbons are adsorbed from the gaseous stream on highly siliceous nanoporous materials, e.g., such as of aluminum-deficient faujasite-type zeolites, by way of a pressure, vacuum or temperature swing adsorption, then desorbed from the adsorbent in the presence of steam. Optionally, the steam is desorbed from the adsorbent through the use of air or inert gas or a recycle of the waste gas effluent. The invention also provides for a new method of preparing novel shapes such as beads and monolithic structures of the highly sileceous nanoporous materials.
摘要翻译: 本发明提供了使用短循环时间浓度挥发吸附法从非烃气体分离烃类如短链烷烃和烯烃的方法。 烃通过压力,真空或变温吸附在高度硅质的纳米多孔材料(例如缺铝的八面沸石型沸石)上从气态物质中吸附,然后在蒸汽存在下从吸附剂中脱附。 任选地,蒸汽通过使用空气或惰性气体或废气流出物的循环从吸附剂中解吸。 本发明还提供了一种制备新颖形状的新方法,例如高亲水性纳米多孔材料的珠粒和整体结构。
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10.
公开(公告)号:US20050164890A1
公开(公告)日:2005-07-28
申请号:US11038610
申请日:2005-01-19
申请人: Yongxian Zeng , Rudolph Wolf , Frank Fitch , Martin Bulow , Satish Tamhankar , Divyanshu Acharya
发明人: Yongxian Zeng , Rudolph Wolf , Frank Fitch , Martin Bulow , Satish Tamhankar , Divyanshu Acharya
IPC分类号: C01B32/40 , B01D53/04 , B01J20/06 , B01J20/32 , B01J23/00 , B01J23/83 , B01J37/00 , B01J37/03 , C01B3/38 , C01B3/40 , H01L39/24
CPC分类号: C01B3/40 , B01D53/02 , B01D53/0462 , B01D53/053 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/25 , B01D2253/304 , B01D2253/306 , B01D2253/308 , B01D2253/342 , B01J20/0207 , B01J20/0225 , B01J20/0233 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/28004 , B01J20/28019 , B01J20/28042 , B01J20/28045 , B01J20/28057 , B01J20/3007 , B01J20/3021 , B01J20/3042 , B01J20/305 , B01J20/3078 , B01J20/3204 , B01J20/3236 , B01J20/3289 , B01J23/002 , B01J23/83 , B01J37/0009 , B01J37/03 , B01J2220/42 , B01J2523/00 , C01B3/382 , C01B3/386 , C01B2203/0205 , C01B2203/0244 , C01B2203/043 , C01B2203/0844 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , C01B2203/1088 , C01B2203/1241 , C01B2203/142 , C01B2203/82 , Y02P20/52 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/845 , B01J2523/847
摘要: Supported perovskite-type oxides are described. The perovskite-type oxides have the general formula of AxA′x′ByB′y′O3-δ, wherein A is an ion of a metal of Group IIIa or IIIb of the periodic table of elements or mixtures thereof; A′ is an ion of a metal of Groups Ia or IIa of the periodic table or mixtures thereof; B and B′ are ions of a d-block transition metal of the periodic table or mixtures thereof; x, x′, y and y′ vary from 0 to 1; 0.95
摘要翻译: 描述了支承的钙钛矿型氧化物。 钙钛矿型氧化物具有以下通式:A A x B x Y B'y' 其中A是元素周期表IIIa或IIIb族金属的离子或其混合物; A'是周期表的Ia或IIa族金属的离子或其混合物; B和B'是周期表的d-块过渡金属的离子或其混合物; x,x',y和y'从0变化到1; 0.95
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