摘要:
A method of producing hydrogen chloride, or an aqueous solution thereof, includes the steps: a) furnishing a first electrolyte containing chloride ions; b) carrying out an electrodialysis, wherein the first electrolyte is subjected to a cathodic reduction resulting in a catholyte, wherein the concentration of chloride ions drops in the first electrolyte, the concentration of hydroxide ions increases in the first electrolyte, and a product in the form of hydrogen chloride or an aqueous solution thereof is produced; c) processing of at least a partial quantity of the catholyte, resulting in the first electrolyte, wherein an untreated saline water is used, the concentration of chloride ions increases in the catholyte and the concentration of hydroxide ions drops in the catholyte; and d) at least partial reuse of the catholyte processed according to step c) as the first electrolyte in step b).
摘要:
The present invention provides a method for electrolytically recovering orinning pure metallic nickel from nickel sulfate-containing solution using an electrolysis cell having nickel electrodes. The cell has at least one anode space, at least one cathode space and a diaphragm disposed therebetween. Certain of the nickel electrodes are employed alternatively as anode electrodes and as cathode electrodes in the anode and cathode spaces, respectively, while maintaining other electrodes as fixed cathode electrodes in the cathode spaces for electro-winning of nickel. Nickel regenerated using the process of the present invention may be employed as anode material in nickel electroplating processes.
摘要:
A method of producing hydrogen chloride, or an aqueous solution thereof, includes the steps: a) furnishing a first electrolyte containing chloride ions; b) carrying out an electrodialysis, wherein the first electrolyte is subjected to a cathodic reduction resulting in a catholyte, wherein the concentration of chloride ions drops in the first electrolyte, the concentration of hydroxide ions increases in the first electrolyte, and a product in the form of hydrogen chloride or an aqueous solution thereof is produced; c) processing of at least a partial quantity of the catholyte, resulting in the first electrolyte, wherein an untreated saline water is used, the concentration of chloride ions increases in the catholyte and the concentration of hydroxide ions drops in the catholyte; and d) at least partial reuse of the catholyte processed according to step c) as the first electrolyte in step b).
摘要:
The present invention relates to a method and device for the electrochemical treatment of at least one component, which has a treatment chamber and at least one feed unit for an electrolyte to the treatment chamber, and at least one way for setting the pH value of the electrolyte being provided before the treatment chamber.
摘要:
A method is described for the electrophoretic enamelling of chromatizable metal surfaces. Improved adhesion of the enamel is achieved by a chromating pretreatment of the metal surfaces, the chromated metal surfaces being kept wet from the time of their being chromated up to the time of their introduction into the bath for the electrophoretic enamelling.
摘要:
The present invention relates to a method of treating an untreated saline water (RW), a process water (PW) thereby produced, and a device for carrying out said method. The method includes the steps of: a) furnishing the untreated water (RW); b) producing a mixture (M) by mixing the untreated saline water (RW) with an aqueous solution (HL) containing hydroxide ions; c) sedimenting the solid (FS) forming from the mixture (M) with concurrent formation of an essentially clear supernatant (U); and d) withdrawing process water (PW) from the essentially clear supernatant (U).
摘要:
A process for metal-coating plastic surfaces by chemical pretreatment withn acid pickling agent whereby to prepare the plastic surfaces for the subsequent superposition thereon of a metal layer is described. The plastic surfaces to be coated are chemically pretreated by means of an acid pickling agent in the gaseous phase, the chemical pretreatment is then terminated by chemical reaction of the said pickling agent with another material in the gaseous phase to form gaseous reaction products. If desired, the chemically pretreated plastic surface may then be treated with an aldehyde in solution. The treated surface may then be metal coated, if desired employing a galvanic process without external current.
摘要:
The present invention relates to a method and device for the electrochemical treatment of at least one component, which has a treatment chamber and at least one feed unit for an electrolyte to the treatment chamber, and at least one way for setting the pH value of the electrolyte being provided before the treatment chamber.
摘要:
In making a lead electrode for a lead-acid accumulator or the like, a supporting body of titanium is pickled in a boiling solution of oxalic acid and then adsorptively coated with a titanium (IV) layer in a treatment bath. This treatment is followed by the anodic coating of the titanium body with PbO.sub.2 in an electrolyte containing the ions of lead (II), in the presence of a lead (II) nitrate or a lead (II) salt of an amido, imido, nitrido or fluoro sulfate or phosphate. The treatment bath may be an aqueous solution of an organic titanium salt, the pickling solution, or the electrolyte. If the pickling solution is used for this purpose, the titanium body is anodically connected or the solution is oxygenated. If the electrolyte is utilized, Ti(IV) ions are introduced into that liquid in which the titanium body is immersed for an extended period before closure of the anodizing circuit.