公开(公告)号：US07592464B2

公开(公告)日：2009-09-22

申请号：US11694466

申请日：2007-03-30

申请人： Rajshekhar Basale ,  Hyacinth Mary Bastian ,  Balakrishnan Ganesan ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Gurram Kishan ,  Pushpa Narayanan ,  Swaminathan Shubashree ,  Ravindra Vikram Singh

发明人： Rajshekhar Basale ,  Hyacinth Mary Bastian ,  Balakrishnan Ganesan ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Gurram Kishan ,  Pushpa Narayanan ,  Swaminathan Shubashree ,  Ravindra Vikram Singh

IPC分类号： C07D209/44 ,  C08G64/00 ,  C08G63/02

CPC分类号： C07D209/46 ,  C08G64/12

摘要： Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 99 weight percent phenolphthalein, based on the total weight of the phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is purified by a combination of techniques to produce a solid comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine with sufficient purity to be used as a monomer in the synthesis of clear polymers.

摘要翻译： 本文公开了一种方法，其包括在酸催化剂存在下使酚酞材料和主要烃基胺反应以形成包含2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的反应混合物，其中酚酞材料包含更大的 等于99重量％的酚酞，基于酚酞材料的总重量; 淬灭反应混合物并处理淬灭的反应混合物以获得第一固体。 第一固体通过技术的组合来纯化，以产生包含具有足够纯度的2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶的固体，以用作合成透明聚合物的单体。

公开(公告)号：US07514524B2

公开(公告)日：2009-04-07

申请号：US11694405

申请日：2007-03-30

申请人： Rajshekhar Basale ,  Balakrishnan Ganesan ,  Venkata Rama Narayanan Ganapathy Bholta ,  Gurram Kishan ,  Surendra Kulkarni ,  Pradeep Nadkarni ,  Suresh Shanmugam ,  Ravindra Vikram Singh

发明人： Rajshekhar Basale ,  Balakrishnan Ganesan ,  Venkata Rama Narayanan Ganapathy Bholta ,  Gurram Kishan ,  Surendra Kulkarni ,  Pradeep Nadkarni ,  Suresh Shanmugam ,  Ravindra Vikram Singh

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C07D209/46

摘要： Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 95 weight percent phenolphthalein, based on the total weight of phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is then triturated with a trituration solvent and washed to obtain a second solid, wherein the second solid comprises greater than or equal to 97 weight percent 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, based on the total weight of the second solid. The second solid may be polymerized to form a polycarbonate.

摘要翻译： 本文公开了一种方法，其包括在酸催化剂存在下使酚酞材料和主要烃基胺反应以形成包含2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的反应混合物，其中酚酞材料包含更大的 基于酚酞材料的总重量计，酚酞总重≥95重量％ 淬灭反应混合物并处理淬灭的反应混合物以获得第一固体。 然后将第一固体用研磨溶剂研磨并洗涤以获得第二固体，其中第二固体包含大于或等于97重量％的2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶，基于 第二固体的总重量。 可以将第二固体聚合以形成聚碳酸酯。

公开(公告)号：US20080242873A1

公开(公告)日：2008-10-02

申请号：US11694466

申请日：2007-03-30

申请人： Rajshekhar Basale ,  Hyacinth Mary Bastian ,  Balakrishnan Ganesan ,  Venkata Rama Narayana Ganapathy Bhotla ,  Gurram Kishan ,  Pushpa Narayanan ,  Swaminathan Shubashree ,  Ravindra Vikram Singh

发明人： Rajshekhar Basale ,  Hyacinth Mary Bastian ,  Balakrishnan Ganesan ,  Venkata Rama Narayana Ganapathy Bhotla ,  Gurram Kishan ,  Pushpa Narayanan ,  Swaminathan Shubashree ,  Ravindra Vikram Singh

IPC分类号： C07D209/32

CPC分类号： C07D209/46 ,  C08G64/12

摘要： Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 99 weight percent phenolphthalein, based on the total weight of the phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is purified by a combination of techniques to produce a solid comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine with sufficient purity to be used as a monomer in the synthesis of clear polymers.

摘要翻译： 本文公开了一种方法，其包括在酸催化剂存在下使酚酞材料和主要烃基胺反应以形成包含2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的反应混合物，其中酚酞材料包含更大的 等于99重量％的酚酞，基于酚酞材料的总重量; 淬灭反应混合物并处理淬灭的反应混合物以获得第一固体。 第一固体通过技术的组合来纯化，以产生包含具有足够纯度的2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶的固体，以用作合成透明聚合物的单体。

公开(公告)号：US20080242829A1

公开(公告)日：2008-10-02

申请号：US11694405

申请日：2007-03-30

申请人： Rajshekhar Basale ,  Balakrishnan Ganesan ,  Venkata Rama Narayanan Ganapathy Bholta ,  Gurram Kishan ,  Surendra Kulkarni ,  Pradeep Nadkarni ,  Suresh Shanmugam ,  Ravindra Vikram Singh

发明人： Rajshekhar Basale ,  Balakrishnan Ganesan ,  Venkata Rama Narayanan Ganapathy Bholta ,  Gurram Kishan ,  Surendra Kulkarni ,  Pradeep Nadkarni ,  Suresh Shanmugam ,  Ravindra Vikram Singh

IPC分类号： C08G65/38 ,  C07D209/32

CPC分类号： C07D209/46

摘要： Disclosed herein is a method comprising reacting a phenolphthalein material and a primary hydrocarbyl amine in the presence of an acid catalyst to form a reaction mixture comprising 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, wherein the phenolphthalein material comprises greater than or equal to 95 weight percent phenolphthalein, based on the total weight of phenolphthalein material; quenching the reaction mixture and treating the quenched reaction mixture to obtain a first solid. The first solid is then triturated with a trituration solvent and washed to obtain a second solid, wherein the second solid comprises greater than or equal to 97 weight percent 2-hydrocarbyl-3,3-bis(4-hydroxyaryl)phthalimidine, based on the total weight of the second solid. The second solid may be polymerized to form a polycarbonate.

摘要翻译： 本文公开了一种方法，其包括在酸催化剂存在下使酚酞材料和主要烃基胺反应以形成包含2-烃基-3,3-双（4-羟基芳基）苯并嘧啶的反应混合物，其中酚酞材料包含更大的 基于酚酞材料的总重量计，酚酞总重≥95重量％ 淬灭反应混合物并处理淬灭的反应混合物以获得第一固体。 然后将第一固体用研磨溶剂研磨并洗涤以获得第二固体，其中第二固体包含大于或等于97重量％的2-烃基-3,3-双（4-羟基芳基）苯并二氮嘧啶，基于 第二固体的总重量。 可以将第二固体聚合以形成聚碳酸酯。

公开(公告)号：US07208620B1

公开(公告)日：2007-04-24

申请号：US11261720

申请日：2005-10-28

申请人： Jan Henk Kamps ,  Jan-Pleun Lens ,  A. S. Radhakrishna ,  T. Tilak Raj ,  Ravindra Vikram Singh

发明人： Jan Henk Kamps ,  Jan-Pleun Lens ,  A. S. Radhakrishna ,  T. Tilak Raj ,  Ravindra Vikram Singh

IPC分类号： C07C69/76 ,  C07C67/00

CPC分类号： C07C45/69 ,  C07C45/74 ,  C07C67/343 ,  C07C67/347 ,  C07C69/757 ,  C07C2601/14 ,  C07C49/223

摘要： A dihydroxy aromatic compound having a Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4.

摘要翻译： 具有式（I）的二羟基芳族化合物，其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团，具有2个 具有4至10个碳的脂环族酯官能团和具有4至10个碳原子的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; 并且每次出现时，每个R 3和R 4可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团 具有3至10个碳，“n”是0至4的整数，“m”是0至4的整数。

公开(公告)号：US07790832B2

公开(公告)日：2010-09-07

申请号：US11849523

申请日：2007-09-04

申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanumgam ,  Gurram Kishan ,  Ravindra Vikram Singh

发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanumgam ,  Gurram Kishan ,  Ravindra Vikram Singh

IPC分类号： C08G64/00 ,  C08G63/02

CPC分类号： C07D209/46 ,  C08G64/12

摘要： A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical. The purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines have low color, and are useful for preparing polymers, such as polycarbonates having a low color. The polycarbonates are useful for producing articles.

摘要翻译： 纯化2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶的方法包括使粗2-二芳基-3,3-双（羟基芳基）苯并二氮吡啶与纯化剂接触，除去2-芳基-3-（氨基芳基 ）-3-（羟基芳基）苯并二氮嘧啶化合物，并制备纯化的2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶产物，其包含小于200份 百万的2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并嘧啶化合物。 净化剂选自酸性物质，有机酰氯，有机酸酐或其组合。 2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并二氮嘧啶化合物具有下式：其中每个R 1独立地选自烃基，硝基和卤素原子; “a”是从0到4的整数; Ar 1和Ar 2在每次出现时独立地为芳族基团。 纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺具有低的颜色，并且可用于制备聚合物，例如具有低颜色的聚碳酸酯。 聚碳酸酯可用于制造制品。

公开(公告)号：US07563817B2

公开(公告)日：2009-07-21

申请号：US11300225

申请日：2005-12-14

申请人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Vikram Singh

发明人： Balakrishnan Ganesan ,  Pradeep Jeevaji Nadkarni ,  Kumar Arun Satyanarayana ,  Venkata Rama Narayanan Ganapathy Bhotla ,  Suresh Shanmugam ,  Gurram Kishan ,  Ravindra Vikram Singh

IPC分类号： A61K31/405 ,  C07D209/34

CPC分类号： C07D209/46 ,  C08G64/12

摘要： A method for purifying a 2-aryl-3,3-bis(hydroxyaryl)phthalimidine comprises contacting a crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine with a purification agent, removing a 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound from the crude 2-aryl-3,3-bis(hydroxyaryl)phthalimidine, and producing a purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidine product comprising less than 200 parts per million of the 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound. The purification agent is selected from the group consisting of an acidic material, an organic acid chloride, an organic anhydride, or a combination thereof. The 2-aryl-3-(aminoaryl)-3-(hydroxyaryl)phthalimidine compound has a formula: wherein each R1 is independently selected from a group consisting of a hydrocarbyl radical, a nitro radical, and a halogen atom; “a” is an integer from 0 to 4; and Ar1 and Ar2 are independently at each occurrence an aromatic radical. The purified 2-aryl-3,3-bis(hydroxyaryl)phthalimidines have low color, and are useful for preparing polymers, such as polycarbonates having a low color. The polycarbonates are useful for producing articles.

摘要翻译： 纯化2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶的方法包括使粗2-二芳基-3,3-双（羟基芳基）苯并二氮吡啶与纯化剂接触，除去2-芳基-3-（氨基芳基 ）-3-（羟基芳基）苯并二氮嘧啶化合物，并制备纯化的2-芳基-3,3-双（羟基芳基）苯并二氮嘧啶产物，其包含小于200份 百万的2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并嘧啶化合物。 净化剂选自酸性物质，有机酰氯，有机酸酐或其组合。 2-芳基-3-（氨基芳基）-3-（羟基芳基）苯并二氮嘧啶化合物具有下式：其中每个R 1独立地选自烃基，硝基和卤素原子; “a”是从0到4的整数; Ar 1和Ar 2在每次出现时独立地为芳族基团。 纯化的2-芳基-3,3-双（羟基芳基）苯二甲酰亚胺具有低的颜色，并且可用于制备聚合物，例如具有低颜色的聚碳酸酯。 聚碳酸酯可用于制造制品。

公开(公告)号：US07381786B2

公开(公告)日：2008-06-03

申请号：US11693314

申请日：2007-03-29

申请人： Jan Henk Kamps ,  Jan-Pleun Lens ,  James A. Mahood ,  Arakali Srinivasarao Radhakrishna ,  T. Tilak Raj ,  Ravindra Vikram Singh

发明人： Jan Henk Kamps ,  Jan-Pleun Lens ,  James A. Mahood ,  Arakali Srinivasarao Radhakrishna ,  T. Tilak Raj ,  Ravindra Vikram Singh

IPC分类号： C08G63/02 ,  C07C69/76 ,  C07C67/00

CPC分类号： C07C69/757 ,  C07C45/69 ,  C07C45/74 ,  C07C67/343 ,  C07C67/347 ,  C07C2601/14 ,  C08G64/14 ,  C07C49/223

摘要： Disclosed herein is a process for preparing a polymer comprising structural units derived from polycyclic dihydroxy compound having Formula (I), wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4. The process comprises subjecting a polycyclic dihydroxy compound of Formula (I) to polymerization.

摘要翻译： 本文公开了一种制备包含衍生自具有式（I）的多环二羟基化合物的结构单元的聚合物的方法，其中R 1选自氰基官能团，硝基官能团，脂族基团 具有1至10个碳的官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; 并且每次出现时，每个R 3和R 4可以相同或不同，并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团 具有3至10个碳，“n”是0至4的整数，“m”是0至4的整数。该方法包括使式（I）的多环二羟基化合物进行聚合。

公开(公告)号：US07326763B2

公开(公告)日：2008-02-05

申请号：US11261279

申请日：2005-10-28

申请人： Jan Henk Kamps ,  Jan-Pleun Lens ,  James A. Mahood ,  Radhakrishna Arakali Srinivasarao ,  T. Tilak Raj ,  Ravindra Vikram Singh

发明人： Jan Henk Kamps ,  Jan-Pleun Lens ,  James A. Mahood ,  Radhakrishna Arakali Srinivasarao ,  T. Tilak Raj ,  Ravindra Vikram Singh

IPC分类号： C08G63/02

CPC分类号： C08G64/14 ,  C08G63/64 ,  C08G64/06 ,  C08G64/24 ,  C08G64/28

摘要： A polymer comprises structural units derived from a polycyclic dihydroxy compound of Formula (I) wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and R3 and R4 are independently at each occurrence a hydrogen, an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons.

摘要翻译： 聚合物包含衍生自式（I）的多环二羟基化合物的结构单元，其中R 1选自氰基官能团，硝基官能团，具有1至10个碳的脂族官能团， 具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团，硝基官能团，具有2至10个碳的脂族酯官能团，具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; R 3和R 4在每次出现时独立地为氢，具有1至10个碳的脂族官能团或具有3至10个碳的脂环族官能团。