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1.发明授权Dual function partial oxidation catalyst for propane to acrylic acid conversion 有权双功能部分氧化催化剂用于丙烷到丙烯酸的转化公开(公告)号：US08921257B2
公开(公告)日：2014-12-30
申请号：US13310693
申请日：2011-12-02
IPC分类号： B01J23/00 , B01J27/057
CPC分类号： C07C51/215 , B01J23/002 , B01J23/28 , B01J23/6525 , B01J23/686 , B01J27/199 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/0036 , B01J37/031 , B01J2523/00 , C07C57/04 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/18 , B01J2523/824 , B01J2523/32 , B01J2523/828
摘要： Catalyst compositions including a compound of the following general formula (I): MoVaNbbPtcMdZeOx (I) a is a number having a value between about 0.15 and about 0.50, b is a number having a value between about 0.05 and about 0.30, c is a number having a value between about 0.0001 and about 0.10, d is a number having a value between about 0.0 and about 0.35, e is a number having a value between about 0 and about 0.10, x is a number depending on the relative amount and valence of the elements different from oxygen in formula (I), M is one or more elements selected from the group consisting of Ag, Te, and Sb, and Z is one or more element selected from Ru, Mn, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Ce, Pr, Nd, Sm, Tb, Ta, W, Re, Ir, Au, Pb, B, and mixtures thereof, where the compositions are capable of simultaneously oxidizing an alkane to a desired product and by-product carbon monoxide to carbon dioxide, with only a minor change in catalyst activity and selectivity.
摘要翻译： 包含以下通式（I）的化合物的催化剂组合物：MoVaNbbPtcMdZeOx（I）a为约0.15至约0.50的数值，b为约0.05至约0.30的数，c为数 具有在约0.0001和约0.10之间的值，d是具有在约0.0和约0.35之间的值的数，e是具有在约0和约0.10之间的值的数，x是取决于相对量和化合价的数 与式（I）中的氧不同的元素，M是选自Ag，Te和Sb中的一种或多种元素，Z是选自Ru，Mn，Sc，Ti，Cr，Fe中的一种或多种元素 ，Co，Ni，Cu，Zn，Ga，Y，Zr，Rh，Pd，In，Ce，Pr，Nd，Sm，Tb，Ta，W，Re，Ir，Au，Pb，B及其混合物 组合物能够同时将烷烃氧化成所需产物和副产物一氧化碳至二氧化碳，只有催化剂活性和选择性略有变化。
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2.发明申请DUAL FUNCTION PARTIAL OXIDATION CATALYST FOR PROPANE TO ACRYLIC ACID CONVERSION 有权用于丙烯酸转化的双功能部分氧化催化剂公开(公告)号：US20130144085A1
公开(公告)日：2013-06-06
申请号：US13310693
申请日：2011-12-02
IPC分类号： C07C51/215 , B01J23/652 , B01J27/057
CPC分类号： C07C51/215 , B01J23/002 , B01J23/28 , B01J23/6525 , B01J23/686 , B01J27/199 , B01J35/023 , B01J35/1009 , B01J35/1014 , B01J37/0009 , B01J37/0036 , B01J37/031 , B01J2523/00 , C07C57/04 , B01J2523/53 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/18 , B01J2523/824 , B01J2523/32 , B01J2523/828
摘要： Catalyst compositions including a compound of the following general formula (I): MoVaNbbPtcMdZeOx (I) a is a number having a value between about 0.15 and about 0.50, b is a number having a value between about 0.05 and about 0.30, c is a number having a value between about 0.0001 and about 0.10, d is a number having a value between about 0.0 and about 0.35, e is a number having a value between about 0 and about 0.10, x is a number depending on the relative amount and valence of the elements different from oxygen in formula (I), M is one or more elements selected from the group consisting of Ag, Te, and Sb, and Z is one or more element selected from Ru, Mn, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Ce, Pr, Nd, Sm, Tb, Ta, W, Re, Ir, Au, Pb, B, and mixtures thereof, where the compositions are capable of simultaneously oxidizing an alkane to a desired product and by-product carbon monoxide to carbon dioxide, with only a minor change in catalyst activity and selectivity.
摘要翻译： 包含以下通式（I）的化合物的催化剂组合物：MoVaNbbPtcMdZeOx（I）a为约0.15至约0.50的数值，b为约0.05至约0.30的数，c为数 具有在约0.0001和约0.10之间的值，d是具有在约0.0和约0.35之间的值的数，e是具有在约0和约0.10之间的值的数，x是取决于相对量和化合价的数 与式（I）中的氧不同的元素，M是选自Ag，Te和Sb中的一种或多种元素，Z是选自Ru，Mn，Sc，Ti，Cr，Fe中的一种或多种元素 ，Co，Ni，Cu，Zn，Ga，Y，Zr，Rh，Pd，In，Ce，Pr，Nd，Sm，Tb，Ta，W，Re，Ir，Au，Pb，B及其混合物 组合物能够同时将烷烃氧化成所需产物和副产物一氧化碳至二氧化碳，只有催化剂活性和选择性略有变化。
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