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    Durable press finishing treatment for cellulose textiles employing an aluminum acetate catalyst solution
    1.
    发明授权
    Durable press finishing treatment for cellulose textiles employing an aluminum acetate catalyst solution 失效
    使用乙酸铝催化剂溶液的纤维素纺织品的耐久压机整理处理

    公开(公告)号：US4224030A

    公开(公告)日：1980-09-23

    申请号：US1134

    申请日：1979-01-05

    Applicant: Robert M. Reinhardt ,  Russell M. H. Kullman

    Inventor： Robert M. Reinhardt ,  Russell M. H. Kullman

    IPC: D06M13/14 ,  D06M9/00 ,  D06M15/54 ,  D06M15/58

    CPC classification number: D06M13/127

    Abstract: An aluminum acetate salt solution containing sodium and chloride ions is prepared by reaction of aqueous aluminum chloride and sodium acetate. It is suitable for use as a catalyst in the treatment of cellulosic-containing textiles with formaldehyde or a formaldehyde-amide adduct crosslinking agent to produce durable press properties in the finished material. There is no discoloration in the thus-treated fabric which also exhibits greater strength than is normally present in fabric treated to the same level of wrinkle resistance with an aluminum salt catalyst.

    Abstract translation: 通过氯化铝水溶液和乙酸钠的反应制备含有钠和氯离子的乙酸铝盐溶液。 它适用于用甲醛或甲醛 - 酰胺加合物交联剂处理含纤维素的纺织品中的催化剂，以在成品材料中产生耐久的冲压性能。 在如此处理的织物中没有变色，其也显示出比用铝盐催化剂处理至相同水平的抗皱性的织物中通常存在的强度更大的强度。

    Durable-press finishing of cellulose-containing textiles with aluminum chlorhydroxide-hydrogen peroxide catalyst system
    2.
    发明授权
    Durable-press finishing of cellulose-containing textiles with aluminum chlorhydroxide-hydrogen peroxide catalyst system 失效
    用氯化氢氧化铝 - 过氧化氢催化剂体系对含纤维素的纺织品进行耐久压制加工

    公开(公告)号：US4039282A

    公开(公告)日：1977-08-02

    申请号：US706979

    申请日：1976-07-19

    Applicant: Russell M. H. Kullman ,  Robert M. Reinhardt

    Inventor： Russell M. H. Kullman ,  Robert M. Reinhardt

    IPC: D06M15/45 ,  D06M13/34 ,  B01J23/08 ,  B01J27/06

    CPC classification number: D06M15/45

    Abstract: A catalyst system composed of aluminum chlorhydroxide [Al.sub.2 (OH).sub.5 Cl] and hydrogen peroxide [H.sub.2 O.sub.2 ] is disclosed which through synergistic interaction of these components is highly efficient and effective in treatments of cellulose-containing textiles with formaldehyde-amide adduct crosslinking agents. Products with durable-press properties are produced through use of the new catalyst system in treatments employing flash curing conditions, i.e., short processing times at high temperatures, as well as in treatments employing curing temperatures down to 130.degree. C. with longer processing times. Unlike previously known synergistically activated catalyst systems based upon Al.sub.2 (OH).sub.5 Cl, the presently disclosed system utilizes the combination of Al.sub.2 (OH).sub.5 Cl with H.sub.2 O.sub.2, an oxidizing agent, rather than with an acid or a salt with latent acidic or Lewis acid properties.

    Abstract translation: 公开了由氢氧化铝[Al 2（OH）5 Cl]和过氧化氢[H 2 O 2]组成的催化剂体系，其通过这些组分的协同相互作用在使用甲醛 - 酰胺加合物交联剂处理含纤维素的纺织品中是高效且有效的。 具有耐久冲压性能的产品通过使用新的催化剂体系在使用闪光固化条件的处理中生产，即在高温下的加工时间短，以及在130℃以下的固化温度下处理较长的处理时间。 与先前已知的基于Al 2（OH）5 Cl的协同活化催化剂体系不同，本公开的系统利用Al 2（OH）5 Cl与H 2 O 2的组合，氧化剂而不是具有酸或具有潜在酸性或路易斯酸性质的盐 。

    Durable press finishing with catalysis by triazaphosphaadamantane derivatives
    3.
    发明授权
    Durable press finishing with catalysis by triazaphosphaadamantane derivatives 失效
    耐久压机整理与三氮杂磷杂金刚烷衍生物催化

    公开(公告)号：US4018950A

    公开(公告)日：1977-04-19

    申请号：US614994

    申请日：1975-09-19

    Applicant: Robert M. Reinhardt ,  Donald J. Daigle ,  Russell M. H. Kullman

    Inventor： Robert M. Reinhardt ,  Donald J. Daigle ,  Russell M. H. Kullman

    IPC: C07F9/6584 ,  B05D3/02

    CPC classification number: C07F9/6584

    Abstract: Salts of 1,3,5-triaza-7-phosphaadamantane can be utilized as catalysts for finishing cellulose-containing textile materials with methylol amide crosslinking agents to give products with improved wrinkle resistance and durable press properties. Inorganic, organic, and sulfonic acid salts, and mixed salt complexes of this new tricyclic phosphorus-containing compound provide effective catalysis in the chemical reactions needed for these finishing treatments. Salts of the corresponding phosphorus oxide, 1,3,5-triaza-7-phosphaadamantane-7-oxide, provided even stronger catalysis in similar treatments.

    Abstract translation: 可以使用1,3,5-三氮杂-7-磷杂金刚烷的盐作为用羟甲基酰胺交联剂处理含纤维素的纺织材料的催化剂，以产生具有改善的抗皱性和耐久冲压性能的产品。 这种新型三环含磷化合物的无机，有机和磺酸盐以及混合盐络合物为这些整理处理所需的化学反应提供了有效的催化作用。 相应的氧化磷，1,3,5-三氮杂-7-磷杂金刚烷-7-氧化物的盐在类似的处理中提供更强的催化作用。

    Methylolated reaction product of a hydroxy carbamate and cellulose-dyeing dyestuff containing vinyl sulfone groups
    5.
    发明授权
    Methylolated reaction product of a hydroxy carbamate and cellulose-dyeing dyestuff containing vinyl sulfone groups 失效
    羟基氨基甲酸酯和含有乙烯基砜基团的纤维素染色剂的羟甲基化反应产物

    公开(公告)号：US3975370A

    公开(公告)日：1976-08-17

    申请号：US506933

    申请日：1974-09-17

    Applicant: Russell M. H. Kullman ,  Robert M. Reinhardt

    Inventor： Russell M. H. Kullman ,  Robert M. Reinhardt

    IPC: C09B62/00 ,  C09B45/18 ,  C09B62/08 ,  C09B62/82

    CPC classification number: C09B62/00

    Abstract: The invention provides a cellulose-dyeing dyestuff having the formula ##EQU1## wherein Z is the chromophoric radical of a cellulose-dyeing dyestuff containing a vinyl sulfone group (--CH.sub.2 CH.sub.2 SO.sub.2 --), e.g. Cl Reactive Violet 4 and Cl Reactive Black 5; B is --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH.sub.2 CH.sub.2 --, or ##EQU2## A is --O-- or --S--; and X is --H, --CH.sub.2 OH, --CH.sub.2 OCH.sub.3, or ##EQU3## which dyestuff will dye a cellulosic material by heating in the presence of an acid catalyst. The cellulose-dyeing dyestuff of the invention is prepared by reacting a conventional cellulose-dyeing dyestuff having a chromophoric radical containing the aforesaid vinyl sulfone groups (e.g., Cl Reactive Black 5 and Cl Reactive Violet 4) with a hydroxy carbamate, and methylolating the resulting product. The utility of conventional cellulose-dyeing dyestuffs, which are normally reactive with cellulosic materials under alkaline conditions, is greatly extended by converting them to the methylolated derivatives of the invention, through prolonged shelf life and compatibility with selected acidic catalysts.

    Abstract translation: 本发明提供了具有式A的纤维素染色染料。其中Z是含有乙烯基砜基团（-CH 2 CH 2 SO 2 - ）的纤维素染色剂的发色团，例如， Cl活性紫4和Cl活性黑5; B是-CH 2 CH 2 - ， - CH 2 CH 2 CH 2 - 或-CH 2 CHCH 2 - ; | OH A为-O-或-S-; X为-H，-CH 2 OH，-CH 2 OCH 3或-CH 2 O-C-CH 3，PARALLEL O，其中染料将通过在酸催化剂存在下加热而染色纤维素材料。 本发明的纤维素染色剂通过将含有上述乙烯基砜基团的发色团（例如Cl活性黑5和Cl反应性紫4）的常规纤维素染色剂与羟基氨基甲酸酯反应，并将所得的 产品。 在碱性条件下通常与纤维素材料反应的常规纤维素染色剂的用途通过将其转变成本发明的羟甲基化衍生物，通过延长的保存期限和与选择的酸性催化剂的相容性而大大延长。

    Selected ammonium sulfonate catalysts for an improved process utilizing mild curing conditions in durable press finishing of cellulose-containing fabrics
    6.
    发明授权
    Selected ammonium sulfonate catalysts for an improved process utilizing mild curing conditions in durable press finishing of cellulose-containing fabrics 失效
    选择的磺酸铵催化剂用于在含纤维素的织物的耐久压光加工中使用温和固化条件的改进方法

    公开(公告)号：US3948600A

    公开(公告)日：1976-04-06

    申请号：US554054

    申请日：1975-02-27

    Applicant: Robert M. Reinhardt ,  Russell M. H. Kullman

    Inventor： Robert M. Reinhardt ,  Russell M. H. Kullman

    IPC: C08K5/42 ,  D06M15/423 ,  D06M15/56

    CPC classification number: C08K5/42 ,  D06M15/423

    Abstract: In mild cure finishing, strong catalysts are required because of the modest curing conditions employed in the process. Suitable catalysts for mild cure finishing include strong inorganic acids, strong organic acids, active inorganic complexes, salt/acid combinations, and salts that are strong Lewis acids (i.e, certain metal salts). Ammonium salts of inorganic acids, although often used in other types of treatments for producing wrinkle resistant textiles, are not satisfactory catalysts for mild cure finishing. Unexpectedly and surprisingly, it has been discovered that ammonium salts of certain, but not all, sulfonic acids can serve as effective catalysts for mild cure finishing of cellulose-containing fabrics to produce wrinkle resistance and durable press properties. Among ammonium sulfonates which provide the catalysis needed for mild cure finishing are ammonium methanesulfonate, ammonium carboxymethanesulfonate (NH.sub.4 O.sub.3 SCH.sub.2 COOH), ammonium benzenesulfonate, and ammonium p-toluenesulfonate.

    Abstract translation: 在温和固化整理中，由于在该方法中使用适度的固化条件，需要强催化剂。 用于温和固化整理的合适的催化剂包括强无机酸，强有机酸，活性无机复合物，盐/酸组合和作为强路易斯酸（即某些金属盐）的盐。 无机酸的铵盐虽然经常用于生产抗皱纺织品的其它类型的处理中，但对于温和的固化整理来说，不是令人满意的催化剂。 出人意料地和令人惊讶地发现，某些但不是全部的磺酸的铵盐可以用作用于含纤维素的织物的温和固化整理的有效催化剂，以产生抗皱性和耐久的冲压性能。 提供温和固化所需催化剂的磺酸铵是甲磺酸铵，羧甲磺酸铵（NH4O3SCH2COOH），苯磺酸铵和对甲苯磺酸铵。

    Process for reinforced yarn with glass fiber core
    7.
    发明授权
    Process for reinforced yarn with glass fiber core 失效
    玻璃纤维芯加强纱线工艺

    公开(公告)号：US4541231A

    公开(公告)日：1985-09-17

    申请号：US526751

    申请日：1983-08-26

    Applicant: Clarence O. Graham, Jr. ,  Charles L. Shepard ,  George F. Ruppenicker, Jr. ,  Russell M. H. Kullman

    Inventor： Clarence O. Graham, Jr. ,  Charles L. Shepard ,  George F. Ruppenicker, Jr. ,  Russell M. H. Kullman

    IPC: D02G3/18 ,  D02G3/28 ,  D02G3/36 ,  D02G3/16

    CPC classification number: D02G3/367 ,  D02G3/185

    Abstract: A unique process for producing torque-free or balanced yarns of staple fibers with glass filament cores is disclosed. Staple fiber roving is fed through a drafting system. Glass filament is fed into the center of the staple fiber just prior to entering the front rolls of the drafting system. Sufficient twist is applied to the fiber around the glass filament using the ring spinning process and two or more of these yarns are ply twisted in the opposite direction of the spinning direction to firmly lock the staple fiber to the glass filament. The twist multiplier range for spinning is between 3.0 to 3.5 and for plying is betwen 3.5 and 4.5. Cotton fiber is the principle fiber used with a glass filament core. The resulting yarn can be tied by knotting onto existing loom beam ends when breaks occur during weaving without shearing of the yarns.

    Abstract translation: 公开了一种用玻璃纤维芯生产无扭矩或平衡的短纤维纱线的独特工艺。 短纤维粗纱通过牵伸系统进料。 在进入牵伸系统的前辊之前，将玻璃纤维送入短纤维的中心。 使用环锭纺丝方法对玻璃纤维周围的纤维施加足够的捻度，并且将这些纱线中的两根或更多根在纺丝方向的相反方向上进行双层捻合，以将短纤维牢固地固定在玻璃丝上。 纺纱的扭转倍数范围在3.0到3.5之间，并且在3.5和4.5之间。 棉纤维是与玻璃丝芯一起使用的主要纤维。 所得到的纱线可以通过打结到现有的织机梁端部上，当织造时发生断裂而不剪切纱线。

    Ternary salts of tris(aminomethyl)phosphines and their oxides prepared by the hydrolysis of 1,3,5-triaza-7-phosphaadamantane and its oxide
    9.
    发明授权
    Ternary salts of tris(aminomethyl)phosphines and their oxides prepared by the hydrolysis of 1,3,5-triaza-7-phosphaadamantane and its oxide 失效
    通过1,3,5-三氮杂-7-磷杂金刚烷及其氧化物的水解制备的三（氨基甲基）膦及其氧化物的三元盐

    公开(公告)号：US4225512A

    公开(公告)日：1980-09-30

    申请号：US61169

    申请日：1979-07-26

    Applicant: Arlen W. Frank ,  Donald J. Daigle ,  Russell M. H. Kullman

    Inventor： Arlen W. Frank ,  Donald J. Daigle ,  Russell M. H. Kullman

    IPC: C07F9/50 ,  C07F9/53 ,  D06M15/673 ,  C07C85/20

    CPC classification number: D06M15/673 ,  C07F9/5004 ,  C07F9/5304

    Abstract: Novel ternary salts of tris(aminomethyl)phosphines and their oxides having the formula (R.sub.2 NH.sup.+ CH.sub.2).sub.3 P(O).sub.n 3X.sup.-, wherein R is hydrogen, an alkyl radical having from 1 to 6 carbon atoms or an aryl radical, n is an integer from 0 to 1, and X is a halogen, are prepared by the reaction of a hydrohalic acid, HX, with various nitrogen- and phosphorus-containing compounds including tris(aminomethyl)phosphines and their oxides, tris(N-carbalkoxylaminomethyl)phosphines oxides, and 1,3,5-triaza-7-phosphaadamantane and its 7-oxide.

    Abstract translation: 三（氨基甲基）膦的新型三元盐及其具有式（R2NH + CH2）3P（O）n3X-的氧化物，其中R是氢，具有1至6个碳原子的烷基或芳基，n是 通过氢卤酸HX与各种含氮和磷的化合物（包括三（氨基甲基）膦及其氧化物，三（N-烷氧羰基氨基甲基）膦）的反应来制备，其中X为卤素， 氧化物和1,3,5-三氮杂-7-磷杂金刚烷及其7-氧化物。

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