公开(公告)号：US3832131A

公开(公告)日：1974-08-27

申请号：US23503672

申请日：1972-03-15

Applicant: CIBA GEIGY AG

Inventor： MASSY D ,  WINTERBOTTOM K

IPC: D06M13/252 ,  D06M15/423 ,  D06M15/54 ,  D06M15/36

CPC classification number: D06M15/423 ,  D06M13/252 ,  Y10T442/2393

Abstract: CELLULOSIC TEXTILES ARE TREATED WITH AN ESTER WHICH CONTAINS, ON AVERAGE, AT LEAST TWO MERCAPTAN GROUPS PER MOLECULE, AND WITH AN AMINOPLAST WHICH IS FREE FROM ETHYLENIC UNSATURATION, AND THE AMINOPLAST IS CURED. THE TREATED TEXTILES HAVE ENHANCED DIMENSIONAL STABILITY, RESISTANCE OF CREASING, AND MAY HAVE PERMANENT CREASES IMPARTED, WHILST HAVING A FULLER, SOFTER HANDLE AND INCREASED TEAR STRENGTH COMPARED TO CELLULOSIC TEXTILES TREATED WITH THE AMINOPLAST ALONE. TYPICALLY, THE ESTER IS PREPARED BY THE REACTION OF (A) A COMPOUND CONTAINING AT LEAST TWO CARBOXYLIC ACID GROUPS, (B) A COMPOUND CONTAINING AT LEAST TWO ALCOHOLIC HYDROXYL GROUPS AND, OPTIONALLY, (C) A COMPOUND CONTAINING NOT MORE THAN ONE CARBOXYLIC ACID GROUP OR ALCOHOLIC HYDROXYL GROUP, ESPECIALLY A MONOMERCAPTOMONOCARBOXYLIC ACID OR A MONOMERCAPTOMONOHYDRIC ALCOHOL.

公开(公告)号：US3816068A

公开(公告)日：1974-06-11

申请号：US16186771

申请日：1971-07-12

Applicant: BURLINGTON INDUSTRIES INC

Inventor： RIVLIN J

IPC: C07F9/53 ,  C08K5/5397 ,  D06M13/285 ,  D06M13/28 ,  D06M15/54

CPC classification number: D06M13/285 ,  C07F9/5304 ,  C08K5/5397 ,  Y10S8/04 ,  Y10S260/24 ,  Y10S428/921

Abstract: Flame retardants for cellulosic fabrics, especially polyester blends, comprise a limited phosphine oxide class of N-methylol propionamides, particularly N-methylol-3(dimethylphosphinyl)propionamide, closely related structurally to N-methylol-3-(dimethyl phosphono)propionamide, but markedly more effective as a flame retardant.

Abstract translation: 纤维素织物，特别是聚酯共混物的阻燃剂包含有限的氧化膦类N-羟甲基丙酰胺，特别是N-羟甲基-3-（二甲基氧膦基）丙酰胺，其结构上与N-羟甲基-3-（二甲基膦酰基）丙酰胺紧密相关， 但作为阻燃剂显着更有效。

公开(公告)号：US3726639A

公开(公告)日：1973-04-10

申请号：US3726639D

申请日：1970-08-17

Applicant: PROCTER & GAMBLE

Inventor： PRENTICE J ,  NICHOLSON D ,  AMEL R

IPC: D06M13/288 ,  D06M13/292 ,  D06M15/432 ,  D06M15/433 ,  D06M13/28 ,  C09K3/28 ,  D06M13/44 ,  D06M15/54

CPC classification number: D06M13/288 ,  D06M13/292 ,  D06M15/432 ,  D06M15/433

Abstract: FLAME-RESISTANT CELLULOSE IS PREPARED BY REACTING CELLULOSE WITH (1) (A) METHYLOLMELAMINES OR (B) MELAMINE AND 2-6 MOLES OFFORMALDEHYDE PER MOLE OF MELAMINE, AND (2) (A) A-HYDROXY PHOSPHONATES OR (B) A MIXTURE OF DIALKYL PHOSPHITES AND CERTAIN CARBONYL CONTAINING COMPOUNDS AT A TEMPERATURE OF FROM ABOUT 100 TO ABOUT 200*C. FOR A PERIOD OF TIME FROM ABOUT 2 MINUTES TO AN HOUR TO PROVIDE A DURABLE FLAME-RESISTANT EFFECT.

公开(公告)号：US3700403A

公开(公告)日：1972-10-24

申请号：US3700403D

申请日：1971-01-12

Applicant: CIBA GEIGY AG

Inventor： NACHBUR HERMANN ,  MAEDER ARTHUR

IPC: C07F9/40 ,  D06M13/288 ,  D06M13/32 ,  D06M15/54

CPC classification number: D06M13/288 ,  C07F9/4006 ,  Y10S8/04 ,  Y10S8/21 ,  Y10S260/24

Abstract: THE PRESENT INVENTION RELATES TO A PROCESS FOR RENDERING CELLULOSE-CONTAINING FIBROUS MATERIALS FLAMEPROOF, WHICH COMPRISES APPLYING TO SAID MATERIALS AN AQUEOUS PREPARATION CONTAINING PHOSPHORUS-CONTAINING N,N-DIMETHYLOLCARBOXYLIC ACID AMIDES. THE FLAMEPROOF FINISH IS RESISTANT TO WASHING AND DRY-CLEANING AND IMPROVES THE DRY CREASE ANGLE AND THE WET CREASE ANGLE OF THE FINISHED MATERIAL.

公开(公告)号：US3676052A

公开(公告)日：1972-07-11

申请号：US3676052D

申请日：1969-11-03

Applicant: US AGRICULTURE

Inventor： HARPER ROBERT J JR ,  BRUNO JOSEPH S ,  GAUTREAUX GLORIA A

IPC: D06M15/423 ,  D06M15/53 ,  D06M15/10 ,  D06M15/54 ,  D06M15/58

CPC classification number: D06M15/53 ,  D06M15/423 ,  Y10S8/04

Abstract: THIS INVENTION RELATES TO FABRICS TREATED WITH ONE BATH SYSTEMS CONTAINING CROSSLINKING AGENTS AND POLYPROYLENE ALCOHOLS, GLYCOLS AND POLYOLS. THESE TREATMENTS ONCE APPLIED TO FABRICS PRODUCE FABRICS WITH WASH-WEAR AND DURABLE PRESS PERFORMANCE AND WHICH HAVE IMPROVED SOIL RELEASE CHARACTERISTICS. THIS PROVIDES GARMENTS FOR THE CONSUMER WITH BETTER WASHABILITY CHARACTERISTICS. THESE TREATMENTS ARE MOST EFFECTIVE ON ALL-COTTON FABRICS BUT THEY MAY ALSO BE APPLIED TO POLYESTER-COTTON BLENDS. THE SYSTEM UTILIZED TO ACHIEVE SOIL-RELEASE IS A ONE BATH SYSTEM READILY APPLICABLE TO EITHER PRECURED OR POSTCURED FABRICS. THESE TREATMENTS HAVE BEEN EVALUATED USING SOILING TEST FOLLOWED BY LAUNDERING AND MEASURING REFLECTANCE VALUES.

公开(公告)号：US3540835A

公开(公告)日：1970-11-17

申请号：US3540835D

申请日：1967-08-11

Applicant: DEERING MILLIKEN RES CORP

Inventor： MARCO FRANCIS W

IPC: D06M15/00 ,  D06M15/54 ,  D06M15/14

CPC classification number: D06M15/29 ,  D06M10/10 ,  D06M15/423 ,  D06M2101/06 ,  D06M2101/32 ,  D06M2200/20

公开(公告)号：US3484182A

公开(公告)日：1969-12-16

申请号：US3484182D

申请日：1966-07-01

Applicant: MONSANTO CO

Inventor： HARTGROVE EARL H JR ,  HIRSHFELD JULIAN J ,  REUBEN BERTIE J

IPC: D06M15/423 ,  D06M15/54

CPC classification number: D06M15/423

公开(公告)号：US4483689A

公开(公告)日：1984-11-20

申请号：US518779

申请日：1983-07-29

Applicant: Clark M. Welch

Inventor： Clark M. Welch

IPC: D06M14/04 ,  D06M15/54 ,  D06M15/60 ,  D06M15/64

CPC classification number: D06M14/04

Abstract: The use of 4,4'-azobis(4-cyanovaleric acid) and its salts as water-soluble free radical initiators, and simultaneously or alternatively the addition of catalytic amounts of tetrakis(hydroxymethyl)phosphonium sulfate as a polymerization accelerator, in the sequential polymerization and acid-catalyzed grafting of N-methylolacrylamide on cotton textiles from a single treating bath in a padding and two-stage heat curing operation, is disclosed. The cotton textiles as treated are free from discoloration and excessive tendering produced by peroxide-type initiators, and these textiles exhibit increased smooth drying performance, abrasion resistance and strength relative to textiles treated conventionally with dimethyloldihydroxyethyleneurea to comparable wrinkle recovery angles.

Abstract translation: 使用4,4'-偶氮二（4-氰基戊酸）及其盐作为水溶性自由基引发剂，同时或者以催化量加入硫酸四（羟甲基）鏻作为聚合促进剂，按顺序 公开了在填充和两阶段热固化操作中从单一处理浴中的N-羟甲基丙烯酰胺在棉纺织物上的聚合和酸催化接枝。 经处理的棉纺织品没有变色和过氧化物型引发剂产生的过度招标，并且这些纺织品相对于通常用二羟甲基二羟基乙烯脲处理的纺织品具有相当的皱纹恢复角度，具有更好的平滑干燥性能，耐磨性和强度。

公开(公告)号：US4376633A

公开(公告)日：1983-03-15

申请号：US272842

申请日：1981-06-12

Applicant: Robert M. Reinhardt ,  Donald J. Daigle

Inventor： Robert M. Reinhardt ,  Donald J. Daigle

IPC: D06M15/45 ,  D06M15/54 ,  D06M15/56 ,  D06M15/58

CPC classification number: D06M15/45

Abstract: Zwitterions are employed as catalysts in a chemical finishing process to treat cellulosic textiles with crosslinking agents and produce easy-care properties in the finished materials. The process comprises treatment of the textile material, such as cotton fabric, by impregnating it with a solution containing a cellulose-crosslinking agent and, as catalyst a zwitterion, alone or in combination with a magnesium salt, drying and curing the fabric. Said finished fabrics are characterized by an unusual combination of useful, desirable properties--smooth-drying appearance, wrinkle resistance, serviceable strength, and inoffensive formaldehyde release.

Abstract translation: 在化学整理过程中使用两性离子作为催化剂，用交联剂处理纤维素纺织物并在成品材料中产生易于保养的性质。 该方法包括通过用包含纤维素交联剂的溶液浸渍纺织材料如棉织物，以及作为两性离子的催化剂单独或与镁盐组合，干燥和固化织物。 所述成品织物的特征在于有用的，期望的性质 - 光滑干燥外观，抗皱性，可使用强度和无法进行的甲醛释放的不寻常的组合。

公开(公告)号：US4224030A

公开(公告)日：1980-09-23

申请号：US1134

申请日：1979-01-05

Applicant: Robert M. Reinhardt ,  Russell M. H. Kullman

Inventor： Robert M. Reinhardt ,  Russell M. H. Kullman

IPC: D06M13/14 ,  D06M9/00 ,  D06M15/54 ,  D06M15/58

CPC classification number: D06M13/127

Abstract: An aluminum acetate salt solution containing sodium and chloride ions is prepared by reaction of aqueous aluminum chloride and sodium acetate. It is suitable for use as a catalyst in the treatment of cellulosic-containing textiles with formaldehyde or a formaldehyde-amide adduct crosslinking agent to produce durable press properties in the finished material. There is no discoloration in the thus-treated fabric which also exhibits greater strength than is normally present in fabric treated to the same level of wrinkle resistance with an aluminum salt catalyst.

Abstract translation: 通过氯化铝水溶液和乙酸钠的反应制备含有钠和氯离子的乙酸铝盐溶液。 它适用于用甲醛或甲醛 - 酰胺加合物交联剂处理含纤维素的纺织品中的催化剂，以在成品材料中产生耐久的冲压性能。 在如此处理的织物中没有变色，其也显示出比用铝盐催化剂处理至相同水平的抗皱性的织物中通常存在的强度更大的强度。