公开(公告)号：US5246983A

公开(公告)日：1993-09-21

申请号：US717818

申请日：1991-06-19

申请人： Takashi Shibata ,  Hiromu Miyashita ,  Sanzi Aoki ,  Koichi Akiyama

发明人： Takashi Shibata ,  Hiromu Miyashita ,  Sanzi Aoki ,  Koichi Akiyama

IPC分类号： C08J9/32

CPC分类号： C08J9/32 ,  C08J2367/00

摘要： A resin composition comprising (a) an unsaturated polyester, (b) a vinyl monomer, (c) a thermoplastic resin, (d) a curing agent and (e) a hollow filler with a number average particle diameter of not more than 20 .mu., wherein (e) occurs in a proportion of 10 to 150 parts by weight to 100 parts by weight of (a), (b) and (c) combined, and the molding compounds obtainable by impregnating glass fiber with the said resin composition are very useful in that, because of their lower specific gravity, they provide lightweight products with excellent surface quality which are great use as automotive exterior body panels and other parts.

摘要翻译： 一种树脂组合物，其包含（a）不饱和聚酯，（b）乙烯基单体，（c）热塑性树脂，（d）固化剂和（e）数均粒径不大于20微米的中空填料 其中（e）以（a），（b）和（c）的100重量份的比例为10〜150重量份的组合，通过与所述树脂组合物浸渍玻璃纤维而获得的成型化合物为 非常有用，因为它们的比重较低，它们提供具有优异表面质量的轻质产品，其作为汽车外壳面板和其它部件是非常有用的。

公开(公告)号：US5164448A

公开(公告)日：1992-11-17

申请号：US762250

申请日：1991-09-19

申请人： Yasuhiro Mishima ,  Hisayuki Iwai ,  Kenichi Nishino ,  Sanzi Aoki ,  Mitsuo Kinoshita ,  Tatsuhiko Ozaki

发明人： Yasuhiro Mishima ,  Hisayuki Iwai ,  Kenichi Nishino ,  Sanzi Aoki ,  Mitsuo Kinoshita ,  Tatsuhiko Ozaki

IPC分类号： C08F287/00 ,  C08L67/06

CPC分类号： C08F287/00 ,  C08L67/06

摘要： Curable unsaturated polyester resin compositions from which molded products with superior surface smoothness can be obtained include a block copolymer of a specified form, an unsaturated polyester, a vinyl monomer, a filler, a curing catalyst and a reinforcing fiber. The block copolymer is of the form A--(B).sub.n where A is non-hydrogenated polyisoprene block having viscosity average molecular weight of 10000 or more, B is saturated polyester block obtainable by condensation of organic dicarboxylic anhydride and 1,2-epoxide, more than 50 mol % of terminal groups of the polyester block being carboxylic acid group, A and B are connected by ester linkage and n is not less than 2. Block copolymers of this type can be formed by starting with carboxylic acid or hydroxyl group in polyisoprene and by alternate condensation of organic dicarboxylic anhydride and 1,2-epoxide.

摘要翻译： 可以得到具有优异表面光滑度的成型品的可固化不饱和聚酯树脂组合物包括指定形式的嵌段共聚物，不饱和聚酯，乙烯基单体，填料，固化催化剂和增强纤维。 嵌段共聚物为A-（B）n形式，其中A为粘均分子量为10000以上的非氢化聚异戊二烯嵌段，B为通过有机二羧酸酐和1,2-环氧化物的缩合得到的饱和聚酯嵌段， 聚酯嵌段的端基大于50mol％为羧酸基，A和B通过酯键连接，n不小于2.这种类型的嵌段共聚物可以由羧酸或羟基开始形成 聚异戊二烯和有机二羧酸酐与1,2-环氧化物的交替缩合。

公开(公告)号：US5077326A

公开(公告)日：1991-12-31

申请号：US363215

申请日：1989-06-08

申请人： Takashi Shibata ,  Koichi Akiyama ,  Sanzi Aoki ,  Yasuhiro Mishima ,  Hisayuki Iwai ,  Ken Hatta

发明人： Takashi Shibata ,  Koichi Akiyama ,  Sanzi Aoki ,  Yasuhiro Mishima ,  Hisayuki Iwai ,  Ken Hatta

IPC分类号： C08L67/06

CPC分类号： C08L67/06

摘要： A quickly curable unsaturated polyester composition with high surface quality contains an unsaturated polyester, a vinyl monomer, either an alkane polyol polyacrylate or an alkane polyol polymethylacrylate, a thermoplastic resin, and one or more curing catalysts selected from t-butylperoxy benzoate, t-butylperoxy octoate and 2,5-dimethyl-2,5-di(benzoilperoxy) hexane. Molding compounds are obtained by impregnating glass fibers with such composition and molded products obtained by curing such molding material have improved surface smoothness.

摘要翻译： 具有高表面质量的快速固化不饱和聚酯组合物包含不饱和聚酯，乙烯基单体，烷基多元醇聚丙烯酸酯或烷基多元醇聚甲基丙烯酸酯，热塑性树脂和一种或多种选自叔丁基过氧苯甲酸酯，叔丁基过氧化物 辛酸酯和2,5-二甲基-2,5-二（苯甲酰过氧）己烷。 通过用这种组合物浸渍玻璃纤维获得成型化合物，并且通过固化这种成型材料获得的模制产品具有改善的表面平滑度。

公开(公告)号：US4952652A

公开(公告)日：1990-08-28

申请号：US232027

申请日：1988-08-15

申请人： Kenichi Nishino ,  Takashi Shibata ,  Sanzi Aoki ,  Yasuhiro Mishima ,  Hisayuki Iwai ,  Ken Hatta

发明人： Kenichi Nishino ,  Takashi Shibata ,  Sanzi Aoki ,  Yasuhiro Mishima ,  Hisayuki Iwai ,  Ken Hatta

IPC分类号： C08F283/01 ,  C08F299/04 ,  C08K5/09 ,  C08L53/02 ,  C08L67/00 ,  C08L67/06

CPC分类号： C08L53/02 ,  C08F299/0464 ,  C08L67/06

摘要： Unsaturated polyester compositions which are quickly curable and from which molded products with superior surface quality can be obtained are characterized as being composed of an unsaturated polyester, an olefinic unsaturated monomer, an aromatic vinyl-conjugated diene block copolymer or a hydrogenated aromatic vinyl-conjugated diene block copolymer, a mixture of t-butylperoxy benzoate, t-butylperoxy octoate and 1,1-bis(t-butylperoxy) 3,3,5-trimethyl cyclohexane, and at least one selected from organic compounds of cobalt, copper and manganese.

摘要翻译： 可以得到快速固化的不饱和聚酯组合物和具有优异表面质量的成型产品，其特征在于由不饱和聚酯，烯属不饱和单体，芳族乙烯基 - 共轭二烯嵌段共聚物或氢化芳族乙烯基共轭二烯 嵌段共聚物，过氧苯甲酸叔丁酯，过氧辛酸叔丁酯和1,1-双（叔丁基过氧）3,3,5-三甲基环己烷的混合物，以及选自钴，铜和锰的有机化合物中的至少一种。