公开(公告)号：US5604292A

公开(公告)日：1997-02-18

申请号：US252701

申请日：1994-05-31

申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

IPC分类号： C08G61/02 ,  C08F112/00

CPC分类号： C08G61/02

摘要： Novel conjugated amino substituted phenylene polymers are disclosed havingon-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.

摘要翻译： 公开了具有非线性光学性质的新型共轭氨基取代的亚苯基聚合物，并且其可以转化为导电聚合物。 这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐 金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。 聚合物也可以通过用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物直接制备。

公开(公告)号：US5578699A

公开(公告)日：1996-11-26

申请号：US457350

申请日：1995-05-18

申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

IPC分类号： C08G61/02 ,  C08G75/00 ,  C08F6/00

CPC分类号： C08G61/02

摘要： A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.

摘要翻译： 公开了一种合成新的共轭氨基取代的亚苯基聚合物的方法。 该方法导致具有非线性光学性质的聚合物，并且聚合物可以转化为导电聚合物。 该方法包括使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基氯化锍）与碱金属氢氧化物的新型双亚烷基锍盐 形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。 另一个方法包括用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物。