公开(公告)号：US08427812B1

公开(公告)日：2013-04-23

申请号：US12898288

申请日：2010-10-05

申请人： John D. Stenger-Smith ,  Jennifer A. Irvin ,  David J. Irvin ,  William Lai

发明人： John D. Stenger-Smith ,  Jennifer A. Irvin ,  David J. Irvin ,  William Lai

IPC分类号： H01G9/00 ,  H01G9/04 ,  H01G9/145

CPC分类号： C09D179/08 ,  B29C39/003 ,  B29D7/01 ,  B29K2035/00 ,  C07D333/22 ,  C07D409/04 ,  C08G69/26 ,  C08G69/30 ,  C08G73/1067 ,  H01G4/33 ,  H01G11/48 ,  H01G11/56

摘要： A process used to cast films including: mixing BBL and a room temperature molten salt from a range of about 35:65 weight ratio, dissolving the mixture in about 1% methanesulfonic acid to produce a BBL solution, drop casting the solution onto glass or gold coated glass at 140° C. in air and heating for about 2 hours to produce films, drying the films in a vacuum oven at about 100° C. for at least 24 hours under dynamic vacuum, and rinsing the films to remove residual ionic liquid.

公开(公告)号：US07578859B2

公开(公告)日：2009-08-25

申请号：US11169255

申请日：2005-06-22

申请人： John R. Reynolds ,  Kyukwan Zong ,  John D. Stenger-Smith ,  Nicole Anderson ,  Cynthia K. Webber ,  Andrew P. Chafin

发明人： John R. Reynolds ,  Kyukwan Zong ,  John D. Stenger-Smith ,  Nicole Anderson ,  Cynthia K. Webber ,  Andrew P. Chafin

IPC分类号： H01M4/82 ,  H01M6/00 ,  H01M4/00

CPC分类号： H01M4/60 ,  H01G11/56 ,  H01M4/606 ,  H01M10/0568 ,  H01M2300/0045 ,  H01M2300/0085 ,  Y02E60/13 ,  Y10T29/49108 ,  Y10T29/49115

摘要： A supercapacitor comprising a poly(3,4-ethylendioxythiophene) (PEDOT) and poly(3,4-propylenedioxythiophene) (PProDOT) as electrode couples for the capacitor and a pair of gel electrolyte layers disposed between the electrodes. The gel electrolytes are separated by a battery paper and are selected from a group consisting of a lithium salt and an organic electrolyte.

摘要翻译： 包含聚（3,4-乙二氧噻吩）（PEDOT）和聚（3,4-亚丙二氧基噻吩）（PProDOT）作为电容器的电极的超级电容器和设置在电极之间的一对凝胶电解质层。 凝胶电解质由电池纸分离，并且选自锂盐和有机电解质。

公开(公告)号：US07399433B1

公开(公告)日：2008-07-15

申请号：US11645259

申请日：2006-11-27

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： H01B1/00 ,  H01B1/12 ,  C25D9/00 ,  C08G61/12

CPC分类号： H01B1/127 ,  C08G61/126 ,  C08L65/00 ,  C09D5/4476 ,  C09D151/10 ,  C08L2666/02

摘要： The present invention demonstrates the synthesis by electropolymerization of a new stable n-doping conjugated polymer poly(3,4-difluorothiophene) that may easily be electrochemically characterized.

摘要翻译： 本发明证明了通过电聚合可以容易地电化学表征的新的稳定的n掺杂共轭聚合物聚（3,4-二氟噻吩）来合成。

公开(公告)号：US06965509B2

公开(公告)日：2005-11-15

申请号：US10307585

申请日：2002-12-02

申请人： John R. Reynolds ,  Kyukwan Zong ,  John D. Stenger-Smith ,  Nicole Anderson ,  Cynthia K. Webber ,  Andrew P. Chafin

发明人： John R. Reynolds ,  Kyukwan Zong ,  John D. Stenger-Smith ,  Nicole Anderson ,  Cynthia K. Webber ,  Andrew P. Chafin

IPC分类号： H01G9/02 ,  H01G9/028 ,  H01G9/04 ,  H01G9/042 ,  H01M4/60 ,  H01M10/04 ,  H01M10/0568

CPC分类号： H01M10/0568 ,  H01G11/48 ,  H01G11/56 ,  H01M4/60 ,  H01M4/606 ,  H01M2300/0085 ,  Y02E60/13

摘要： A supercapacitor comprising a poly(3,4-ethylendioxythiophene) (PEDOT) and poly(3,4-propylenedioxythiophene) (PProDOT) as electrode couples for the capacitor and a pair of gel electrolyte layers disposed between the electrodes. The gel electrolytes are separated by a battery paper and are selected from a group consisting of a lithium salt and an organic electrolyte.

摘要翻译： 包含聚（3,4-乙二氧噻吩）（PEDOT）和聚（3,4-亚丙二氧基噻吩）（PProDOT）作为电容器的电极的超级电容器和设置在电极之间的一对凝胶电解质层。 凝胶电解质由电池纸分离，并且选自锂盐和有机电解质。

公开(公告)号：US5904990A

公开(公告)日：1999-05-18

申请号：US46848

申请日：1998-03-13

申请人： John D. Stenger-Smith ,  Melvin H. Miles ,  William P. Norris ,  John Nelson ,  Peter Zarras ,  John W. Fischer ,  Andrew P. Chafin

发明人： John D. Stenger-Smith ,  Melvin H. Miles ,  William P. Norris ,  John Nelson ,  Peter Zarras ,  John W. Fischer ,  Andrew P. Chafin

IPC分类号： C09D165/00 ,  B32B15/04 ,  B32B15/08 ,  B32B27/00

CPC分类号： C09D165/00 ,  Y10T428/31504 ,  Y10T428/31678 ,  Y10T428/31692 ,  Y10T428/31855

摘要： Until recently, conducting polymers have been used as protective coatings.lthough these types of polymers appear to be effective in most cases, problems have resulted when attempting to bind these polymers to an aluminum surface. The polymers of this invention adhere extremely well to aluminum and aluminum alloys and thus, provide a very effective form of corrosion protection.

摘要翻译： 直到最近，导电聚合物已被用作保护涂层。 尽管这些类型的聚合物在大多数情况下似乎是有效的，但是当试图将这些聚合物结合到铝表面时，会产生问题。 本发明的聚合物非常适合于铝和铝合金，从而提供非常有效的防腐蚀形式。

公开(公告)号：US08183390B1

公开(公告)日：2012-05-22

申请号：US12858993

申请日：2010-08-18

申请人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

发明人： David J. Irvin ,  David L. Witker ,  John D. Stenger-Smith ,  Jennifer A. Irvin

IPC分类号： C07D409/06

CPC分类号： C08F128/06 ,  C07D333/22 ,  C07D409/06 ,  C08G61/123 ,  C08G61/126 ,  C08G73/0616 ,  C08G2261/3221 ,  C08G2261/3223 ,  C08G2261/364 ,  C08G2261/44

摘要： The invention demonstrates the synthesis of a new pyrazole-containing monomer by means of an easily implemented two-step process. This monomer can be electropolymerized to yield a stable n-doping polymer that may easily be electrochemically characterized. It is demonstrated that the electrochemical behavior of the polymer films produced is dependent upon the conditions applied during electrodeposition. Films deposited by cycling only at relatively positive potentials (0 to 2000 mV) show less intense n-doping responses than those films obtained by scanning the applied potential throughout a wider range (−2000 mV to 2000 mV).

摘要翻译： 本发明通过易于实施的两步法合成了含吡唑的单体。 该单体可以电聚合以产生可以容易地电化学表征的稳定的n掺杂聚合物。 证明所生产的聚合物膜的电化学行为取决于电沉积期间的应用条件。 通过仅在相对正电位（0至2000mV）下循环沉积的膜比通过在更宽范围（-2000mV至2000mV）范围内扫描施加电位而获得的膜显示出更少的强度n掺杂响应。

公开(公告)号：US5882785A

公开(公告)日：1999-03-16

申请号：US800943

申请日：1997-01-23

申请人： Richard A. Hollins ,  Geoffrey A. Lindsay ,  Marion J. Roberts ,  Peter Zarras ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Andrew P. Chafin

发明人： Richard A. Hollins ,  Geoffrey A. Lindsay ,  Marion J. Roberts ,  Peter Zarras ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Andrew P. Chafin

IPC分类号： B05D1/20 ,  G02F1/361 ,  C09K19/02 ,  C09K19/48

CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  G02F1/3616 ,  G02F1/3618 ,  Y10T428/261 ,  Y10T428/31504 ,  Y10T428/31728

摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.

摘要翻译： 本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。 本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。 它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。 最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。 新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。 桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

公开(公告)号：US5604292A

公开(公告)日：1997-02-18

申请号：US252701

申请日：1994-05-31

申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

IPC分类号： C08G61/02 ,  C08F112/00

CPC分类号： C08G61/02

摘要： Novel conjugated amino substituted phenylene polymers are disclosed havingon-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.

摘要翻译： 公开了具有非线性光学性质的新型共轭氨基取代的亚苯基聚合物，并且其可以转化为导电聚合物。 这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐 金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。 聚合物也可以通过用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物直接制备。

公开(公告)号：US5587488A

公开(公告)日：1996-12-24

申请号：US441178

申请日：1995-05-10

申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin

发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin

IPC分类号： C08G61/02 ,  C07D409/10

CPC分类号： C08G61/02

摘要： Novel bis-sulfonium salts of amino substituted bis(halomethyl)benzene are disclosed. The sulfonium salts are prepared by reaction of an amino substituted bis(halo methyl)benzene with an aliphatic sulfide. These sulfonium salts can be made into polymer having non-linear optical properties, and polymers which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene).

摘要翻译： 公开了氨基取代的双（卤代甲基）苯的新型双锍盐。 锍盐通过氨基取代的双（卤代甲基）苯与脂族硫醚的反应来制备。 这些锍盐可以制成具有非线性光学性质的聚合物和可以转化成导电聚合物的聚合物。 这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐 金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。

公开(公告)号：US5578699A

公开(公告)日：1996-11-26

申请号：US457350

申请日：1995-05-18

申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

IPC分类号： C08G61/02 ,  C08G75/00 ,  C08F6/00

CPC分类号： C08G61/02

摘要： A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.

摘要翻译： 公开了一种合成新的共轭氨基取代的亚苯基聚合物的方法。 该方法导致具有非线性光学性质的聚合物，并且聚合物可以转化为导电聚合物。 该方法包括使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基氯化锍）与碱金属氢氧化物的新型双亚烷基锍盐 形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。 另一个方法包括用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物。