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    Polymers with electrical and non-linear optical properties
    1.
    发明授权
    Polymers with electrical and non-linear optical properties 失效
    具有电气和非线性光学性质的聚合物

    公开(公告)号：US5604292A

    公开(公告)日：1997-02-18

    申请号：US252701

    申请日：1994-05-31

    申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

    发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

    IPC分类号： C08G61/02 ,  C08F112/00

    CPC分类号： C08G61/02

    摘要： Novel conjugated amino substituted phenylene polymers are disclosed havingon-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.

    摘要翻译： 公开了具有非线性光学性质的新型共轭氨基取代的亚苯基聚合物，并且其可以转化为导电聚合物。 这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐 金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。 聚合物也可以通过用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物直接制备。

    Process for making amino functional poly(para-phenylene vinylene)s
    2.
    发明授权
    Process for making amino functional poly(para-phenylene vinylene)s 失效
    制备氨基官能聚（对亚苯基亚乙烯基）的方法

    公开(公告)号：US5578699A

    公开(公告)日：1996-11-26

    申请号：US457350

    申请日：1995-05-18

    申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

    发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin ,  Scott T. Sackinger

    IPC分类号： C08G61/02 ,  C08G75/00 ,  C08F6/00

    CPC分类号： C08G61/02

    摘要： A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.

    摘要翻译： 公开了一种合成新的共轭氨基取代的亚苯基聚合物的方法。 该方法导致具有非线性光学性质的聚合物，并且聚合物可以转化为导电聚合物。 该方法包括使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基氯化锍）与碱金属氢氧化物的新型双亚烷基锍盐 形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。 另一个方法包括用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物。

    Bis-sulfonium salts of amino substituted bis(halomethyl) benzene
    4.
    发明授权
    Bis-sulfonium salts of amino substituted bis(halomethyl) benzene 失效
    氨基取代的双（卤代甲基）苯的双锍盐

    公开(公告)号：US5587488A

    公开(公告)日：1996-12-24

    申请号：US441178

    申请日：1995-05-10

    申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin

    发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin

    IPC分类号： C08G61/02 ,  C07D409/10

    CPC分类号： C08G61/02

    摘要： Novel bis-sulfonium salts of amino substituted bis(halomethyl)benzene are disclosed. The sulfonium salts are prepared by reaction of an amino substituted bis(halo methyl)benzene with an aliphatic sulfide. These sulfonium salts can be made into polymer having non-linear optical properties, and polymers which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene).

    摘要翻译： 公开了氨基取代的双（卤代甲基）苯的新型双锍盐。 锍盐通过氨基取代的双（卤代甲基）苯与脂族硫醚的反应来制备。 这些锍盐可以制成具有非线性光学性质的聚合物和可以转化成导电聚合物的聚合物。 这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐 金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。

    Amino substituted bishalomethyl benzene compounds
    5.
    发明授权
    Amino substituted bishalomethyl benzene compounds 失效
    氨基取代的双甲基苯化合物

    公开(公告)号：US5585522A

    公开(公告)日：1996-12-17

    申请号：US441179

    申请日：1995-05-10

    申请人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin

    发明人： John D. Stenger-Smith ,  William P. Norris ,  Andrew P. Chafin

    IPC分类号： C08G61/02 ,  C07C211/52

    CPC分类号： C08G61/02

    摘要： Novel amino substituted bishalomethyl benzene compounds, which are precurs to phenylene polymers are disclosed having non-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel amino substituted bishalomethyl benzene compound with a dialkyl sulfide to make a bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, which is 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) and reacting this sulfonium salt with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aminobenzene hydrochloride derivative with alkali metal alkoxide.

    摘要翻译： 公开了作为亚苯基聚合物的前体的新型氨基取代的双甲基苯化合物，其具有非线性光学性质，并且可以转化为导电聚合物。 这种聚合物通过使新的氨基取代的二异丙基甲基苯化合物与二烷基硫化物反应来制备2,5-N，N-四甲基苯胺盐酸盐的双亚环烷基锍盐，其为2,5-（N，N-二甲基） 苯胺盐酸盐二亚甲基双 - （四亚甲基氯化锍），并使该锍盐与碱金属氢氧化物反应形成环亚烷基锍盐前体聚合物，然后在条件下加热前体聚合物，生成氨基取代的亚苯基亚乙烯基聚合物，如聚（2 - （N，N-二甲基氨基）亚苯基亚乙烯基）。 聚合物也可以通过用碱金属醇盐处理二氯甲基二甲基氨基苯盐酸盐衍生物直接制备。

    Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers
    10.
    发明授权
    Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers 失效
    成对沉积的半离聚物共聚聚合物的极化膜

    公开(公告)号：US6114031A

    公开(公告)日：2000-09-05

    申请号：US246197

    申请日：1999-01-11

    申请人： Marion J. Roberts ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Peter Zarras ,  Andrew P. Chafin ,  Richard A. Hollins ,  Geoffrey A. Lindsay

    发明人： Marion J. Roberts ,  John D. Stenger-Smith ,  Kenneth J. Wynne ,  Peter Zarras ,  Andrew P. Chafin ,  Richard A. Hollins ,  Geoffrey A. Lindsay

    IPC分类号： B05D1/20 ,  G02F1/361

    CPC分类号： B82Y30/00 ,  B05D1/202 ,  B82Y20/00 ,  B82Y40/00 ,  G02F1/3616 ,  G02F1/3618 ,  Y10T428/261

    摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.

    摘要翻译： 本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。 本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。 它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。 最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。 新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。 桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。