公开(公告)号：US09174841B2

公开(公告)日：2015-11-03

申请号：US13568536

申请日：2012-08-07

申请人： Chang-Sing Hwang ,  Chun-Liang Chang ,  Chih-Ming Chuang ,  Chun-Huang Tsai ,  Sheng-Hui Nien ,  Shih-Wei Cheng

发明人： Chang-Sing Hwang ,  Chun-Liang Chang ,  Chih-Ming Chuang ,  Chun-Huang Tsai ,  Sheng-Hui Nien ,  Shih-Wei Cheng

IPC分类号： B82Y30/00 ,  H01M8/12 ,  H01M4/86 ,  H01M4/88 ,  H01M4/90 ,  H01M8/02

CPC分类号： B82Y30/00 ,  H01M4/8621 ,  H01M4/886 ,  H01M4/9066 ,  H01M8/0236 ,  H01M8/1226 ,  H01M2008/1293 ,  Y02E60/522 ,  Y02E60/525 ,  Y02P70/56

摘要： A nanostructured anode of solid oxide fuel cell with high stability and high efficiency and a method for manufacturing the same are revealed. This anode comprising a porous permeable metal substrate, a diffusion barrier layer and a nano-composite film is formed by atmospheric plasma spray. The nano-composite film includes a plurality of metal nanoparticles, a plurality of metal oxide nanoparticles, and a plurality of gas pores that are connected to form nano gas channels. The metal nanoparticles are connected to form a 3-dimensional network that conducts electrons, while the metal oxide nanoparticles are connected to form a 3-dimensional network that conducts oxygen ions. The network formed by metal oxide nanoparticles has certain strength to separate metal nanoparticles and prevent aggregation or agglomeration of the metal nanoparticles. Thus this anode can be applied to a solid oxide fuel cell operating in the intermediate temperatures (600˜800° C.) with high stability and high efficiency.

摘要翻译： 揭示了具有高稳定性和高效率的固体氧化物燃料电池的纳米结构阳极及其制造方法。 通过大气等离子体喷涂形成该阳极，其包含多孔透过性金属基板，扩散阻挡层和纳米复合膜。 纳米复合膜包括多个金属纳米颗粒，多个金属氧化物纳米颗粒和连接形成纳米气体通道的多个气孔。 金属纳米粒子被连接以形成导电电子的3维网络，而金属氧化物纳米粒子被连接以形成导电氧离子的3维网络。 由金属氧化物纳米颗粒形成的网络具有一定的分离金属纳米粒子的强度，并防止金属纳米粒子的聚集或聚集。 因此，该阳极可以以高稳定性和高效率应用于在中间温度（600〜800℃）下工作的固体氧化物燃料电池。

公开(公告)号：US20140045099A1

公开(公告)日：2014-02-13

申请号：US13568536

申请日：2012-08-07

申请人： CHANG-SING HWANG ,  CHUN-LIANG CHANG ,  CHIH-MING CHUANG ,  CHUN-HUANG TSAI ,  SHENG-HUI NIEN ,  SHIH-WEI CHENG

发明人： CHANG-SING HWANG ,  CHUN-LIANG CHANG ,  CHIH-MING CHUANG ,  CHUN-HUANG TSAI ,  SHENG-HUI NIEN ,  SHIH-WEI CHENG

IPC分类号： H01M4/86 ,  H01M4/88 ,  B82Y30/00

CPC分类号： B82Y30/00 ,  H01M4/8621 ,  H01M4/886 ,  H01M4/9066 ,  H01M8/0236 ,  H01M8/1226 ,  H01M2008/1293 ,  Y02E60/522 ,  Y02E60/525 ,  Y02P70/56

摘要： A nanostructured anode of solid oxide fuel cell with high stability and high efficiency and a method for manufacturing the same are revealed. This anode comprising a porous permeable metal substrate, a diffusion barrier layer and a nano-composite film is formed by atmospheric plasma spray. The nano-composite film includes a plurality of metal nanoparticles, a plurality of metal oxide nanoparticles, and a plurality of gas pores that are connected to form nano gas channels. The metal nanoparticles are connected to form a 3-dimensional network that conducts electrons, while the metal oxide nanoparticles are connected to form a 3-dimensional network that conducts oxygen ions. The network formed by metal oxide nanoparticles has certain strength to separate metal nanoparticles and prevent aggregation or agglomeration of the metal nanoparticles. Thus this anode can be applied to a solid oxide fuel cell operating in the intermediate temperatures (600˜800° C.) with high stability and high efficiency.

摘要翻译： 揭示了具有高稳定性和高效率的固体氧化物燃料电池的纳米结构阳极及其制造方法。 通过大气等离子体喷涂形成该阳极，其包含多孔透过性金属基板，扩散阻挡层和纳米复合膜。 纳米复合膜包括多个金属纳米颗粒，多个金属氧化物纳米颗粒和连接形成纳米气体通道的多个气孔。 金属纳米粒子被连接以形成导电电子的3维网络，而金属氧化物纳米粒子被连接以形成导电氧离子的3维网络。 由金属氧化物纳米颗粒形成的网络具有一定的分离金属纳米粒子的强度，并防止金属纳米粒子的聚集或聚集。 因此，该阳极可以以高稳定性和高效率应用于在中间温度（600〜800℃）下工作的固体氧化物燃料电池。