公开(公告)号：US06200926B1

公开(公告)日：2001-03-13

申请号：US08769446

申请日：1996-12-19

申请人： Gilbert Blanchard ,  Paolo Burattin ,  Fabrizio Cavani ,  Stéfano Masetti ,  Ferruccio Trifiro

发明人： Gilbert Blanchard ,  Paolo Burattin ,  Fabrizio Cavani ,  Stéfano Masetti ,  Ferruccio Trifiro

IPC分类号： B01J2300

CPC分类号： B01J37/0203 ,  B01J23/002 ,  B01J23/14 ,  B01J23/18 ,  B01J23/22 ,  B01J23/8472 ,  B01J37/0205 ,  B01J37/08 ,  B01J2523/00 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/55

摘要： Solid catalysts suited for the fluidized/moving bed catalytic ammoxidation of alkanes comprise an active catalytic phase having the empirical formula (I): VSbaSnbTicFedEeOx  (I) in which E is an element which provides an oxide of rutile structure or an element which, in combination with V, Sb, Sn, Ti, Fe and/or with another element E, provides a phase of rutile or trirutile structure, or a solid solution of rutile structure, a is a whole or fractional number equal to or greater than 0.5, b, c, d and e, independently, are each a whole or fractional number ranging from 0 to 100, and x is a whole or fractional number determined by the oxidation state of the other elements, such active catalytic phase being deposited onto/into particulates of a solid and porous oxidic support therefor, and are produced by (a) impregnating the solid and porous oxidic support with a solution, in at least one saturated alcohol, of compounds of vanadium and antimony and, optionally, compounds of tin and/or titanium and/or of iron and/or of element E, (b) contacting the solid and porous oxidic support thus impregnated with an aqueous buffer solution having a pH ranging from about 6 to 8, (c) separating the solids from such aqueous buffer solution and drying same, and (d) calcining the dried solids in two stages.

摘要翻译： 适用于流化/移动床的固体催化剂催化氨基氧化烷烃包括具有经验式（I）的活性催化相：其中E是提供金红石结构的氧化物的元素或与V，Sb ，Sn，Ti，Fe和/或另一元素E提供金红石或三元结构的相或金红石结构的固溶体，a是等于或大于0.5的整数或分数，b，c，d 和e独立地分别为0至100的整数或分数，x为由其它元素的氧化态确定的整数或分数，该活性催化相沉积在固体颗粒中， 通过（a）在至少一种饱和醇中的溶液中浸渍固体和多孔氧化载体来制备，其中钒和锑的化合物以及任选的锡和/或钛和/或 的铁和 /或元素E，（b）使由此浸渍的固体和多孔氧化物载体与pH范围为约6至8的水性缓冲溶液接触，（c）将该固体与该缓冲溶液分离并干燥，和 d）分两步焙烧干固体。