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    Ammoxidation catalysts for fluidized/moving bed reactors
    1.
    发明授权
    Ammoxidation catalysts for fluidized/moving bed reactors 失效
    用于流化/移动床反应器的氨氧化催化剂

    公开(公告)号：US06200926B1

    公开(公告)日：2001-03-13

    申请号：US08769446

    申请日：1996-12-19

    申请人： Gilbert Blanchard ,  Paolo Burattin ,  Fabrizio Cavani ,  Stéfano Masetti ,  Ferruccio Trifiro

    发明人： Gilbert Blanchard ,  Paolo Burattin ,  Fabrizio Cavani ,  Stéfano Masetti ,  Ferruccio Trifiro

    IPC分类号： B01J2300

    CPC分类号： B01J37/0203 ,  B01J23/002 ,  B01J23/14 ,  B01J23/18 ,  B01J23/22 ,  B01J23/8472 ,  B01J37/0205 ,  B01J37/08 ,  B01J2523/00 ,  B01J2523/43 ,  B01J2523/53 ,  B01J2523/55

    摘要： Solid catalysts suited for the fluidized/moving bed catalytic ammoxidation of alkanes comprise an active catalytic phase having the empirical formula (I): VSbaSnbTicFedEeOx  (I) in which E is an element which provides an oxide of rutile structure or an element which, in combination with V, Sb, Sn, Ti, Fe and/or with another element E, provides a phase of rutile or trirutile structure, or a solid solution of rutile structure, a is a whole or fractional number equal to or greater than 0.5, b, c, d and e, independently, are each a whole or fractional number ranging from 0 to 100, and x is a whole or fractional number determined by the oxidation state of the other elements, such active catalytic phase being deposited onto/into particulates of a solid and porous oxidic support therefor, and are produced by (a) impregnating the solid and porous oxidic support with a solution, in at least one saturated alcohol, of compounds of vanadium and antimony and, optionally, compounds of tin and/or titanium and/or of iron and/or of element E, (b) contacting the solid and porous oxidic support thus impregnated with an aqueous buffer solution having a pH ranging from about 6 to 8, (c) separating the solids from such aqueous buffer solution and drying same, and (d) calcining the dried solids in two stages.

    摘要翻译： 适用于流化/移动床的固体催化剂催化氨基氧化烷烃包括具有经验式（I）的活性催化相：其中E是提供金红石结构的氧化物的元素或与V，Sb ，Sn，Ti，Fe和/或另一元素E提供金红石或三元结构的相或金红石结构的固溶体，a是等于或大于0.5的整数或分数，b，c，d 和e独立地分别为0至100的整数或分数，x为由其它元素的氧化态确定的整数或分数，该活性催化相沉积在固体颗粒中， 通过（a）在至少一种饱和醇中的溶液中浸渍固体和多孔氧化载体来制备，其中钒和锑的化合物以及任选的锡和/或钛和/或 的铁和 /或元素E，（b）使由此浸渍的固体和多孔氧化物载体与pH范围为约6至8的水性缓冲溶液接触，（c）将该固体与该缓冲溶液分离并干燥，和 d）分两步焙烧干固体。

    Production of nitriles via hydrocyanation of ethylenically unsaturated organic compounds
    6.
    发明授权
    Production of nitriles via hydrocyanation of ethylenically unsaturated organic compounds 失效
    通过烯属不饱和有机化合物的氢氰化生产腈

    公开(公告)号：US06469194B2

    公开(公告)日：2002-10-22

    申请号：US09886288

    申请日：2001-06-22

    申请人： Paolo Burattin ,  Pierre Coqueret ,  Marc Huser

    发明人： Paolo Burattin ,  Pierre Coqueret ,  Marc Huser

    IPC分类号： C07C25300

    CPC分类号： B01J31/2404 ,  B01J31/24 ,  B01J31/403 ,  B01J31/4053 ,  B01J2231/343 ,  B01J2231/52 ,  B01J2531/847 ,  B01J2531/96 ,  C07C253/10 ,  C07C253/30 ,  Y02P20/584 ,  C07C255/07

    摘要： Ethylenically unsaturated organic compounds, for example diolefins, olefinic nitriles and monoolefins, are noncontaminatingly hydrocyanated into corresponding nitriles by (a) reacting such ethylenically unsaturated organic compounds with hydrogen cyanide in the presence of an aqueous solution containing a catalytically effective amount of a catalyst which comprises at least one nickel compound and at least one water-soluble phosphine, (b) thereafter separating the organic phase from the aqueous phase which result, the separated aqueous phase comprising a solid phase formed during hydrocyanation, and (c) thence treating the separated aqueous phase, or a solid phase removed therefrom, with hydrogen cyanide to thus at least partially dissolve said solid phase contained therein or removed therefrom.

    摘要翻译： 烯键式不饱和有机化合物，例如二烯烃，烯属腈和单烯烃，通过（a）在含有催化有效量的催化剂的水溶液存在下，使这种烯属不饱和有机化合物与氰化氢反应，将其非氰化氢氰化成相应的腈， 至少一种镍化合物和至少一种水溶性膦，（b）此后从水相中分离出有机相，导致分离的水相包括在氢氰化期间形成的固相，和（c）然后处理分离的水溶液 相或其中除去的固相，与氰化氢反应，从而至少部分溶解其中所含的固相或从其中除去。

    Method for making nitrile compounds from ethylenically unsaturated compounds
    7.
    发明授权
    Method for making nitrile compounds from ethylenically unsaturated compounds 有权
    由烯键式不饱和化合物制备腈化合物的方法

    公开(公告)号：US07105696B2

    公开(公告)日：2006-09-12

    申请号：US10250477

    申请日：2001-12-21

    申请人： Paolo Burattin ,  Alex Chamard ,  Jean-Christophe Galland

    发明人： Paolo Burattin ,  Alex Chamard ,  Jean-Christophe Galland

    IPC分类号： C07C253/00

    CPC分类号： C07C253/10 ,  C07C255/04

    摘要： The invention concerns a method for hydrocyanation of ethylenically unsaturated organic compounds comprising at least a nitrile function. The invention provides a method for hydrocyanation of an ethylenically unsaturated hydrocarbon compound by reacting in liquid medium the hydrogen cyanide in the presence of a catalyst comprising a metal element selected among transition metals and an organophosphorous ligand, characterised in that the organophosphorous ligand is a furylphosphine. The invention is in particular useful for synthesizing adiponitrile from butadiene.

    摘要翻译： 本发明涉及一种含有至少一个腈官能团的烯属不饱和有机化合物的氢氰化方法。 本发明提供了一种通过在液体介质中在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，使氰化氢反应的方法，其特征在于有机磷配体是呋喃基膦。 本发明特别适用于从丁二烯合成己二腈。

    Production of hydrocyanation catalysts
    8.
    发明授权
    Production of hydrocyanation catalysts 失效
    生产氢氰化催化剂

    公开(公告)号：US06884751B2

    公开(公告)日：2005-04-26

    申请号：US09886289

    申请日：2001-06-22

    申请人： Paolo Burattin ,  Pierre Coqueret ,  Marc Huser

    发明人： Paolo Burattin ,  Pierre Coqueret ,  Marc Huser

    IPC分类号： B01J31/28 ,  B01J23/755 ,  B01J27/26 ,  B01J31/24 ,  B01J37/00 ,  B01J37/04 ,  B01J37/16 ,  B01J37/24 ,  C07B61/00 ,  C07C253/08 ,  C07C253/10 ,  C07C255/01 ,  B01J31/00 ,  B01J27/189

    CPC分类号： B01J31/2404 ,  B01J27/26 ,  B01J37/16 ,  B01J2531/847 ,  B01J2540/32

    摘要： Hydrocyanation catalysts comprising aqueous solutions of at least one water-soluble phosphine and nickel values, well suited for the hydrocyanation of ethylenically unsaturated organic compounds such as diolefins, olefinic nitrites and monolefins, are produced by (a) admixing an aqueous solution of such at least one water-soluble phosphine with a nickel hydroxide, (b) adding hydrogen cyanide or a compound which generates hydrogen cyanide to the mixture thus formed, (c) stirring the resulting mixture until the nickel values have at least partially dissolved, and (d) reducing at least a portion of said nickel values having an oxidation state of greater than zero to the zero oxidation state.

    摘要翻译： 包含至少一种水溶性膦和镍值的水溶液的氢氰化催化剂通过以下方法制备：（a）将至少一种水溶液至少混合到水溶液中，所述水溶液非常适合于烯属不饱和有机化合物如二烯烃，烯属亚硝酸盐和单烯烃的氢化， 一种与氢氧化镍的水溶性膦，（b）向如此形成的混合物中加入氰化氢或产生氰化氢的化合物，（c）搅拌所得混合物直到镍值至少部分溶解，和（d） 将至少一部分具有大于零的氧化态的所述镍值还原为零氧化态。