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    LOW EQUIVALENT WEIGHT POLYMERS
    3.
    发明申请
    LOW EQUIVALENT WEIGHT POLYMERS 有权
    低等量重量聚合物

    公开(公告)号：US20140141357A1

    公开(公告)日：2014-05-22

    申请号：US14234464

    申请日：2012-07-27

    申请人： Kai H. Lochhaas ,  Steven J. Hamrock ,  Klaus Hintzer

    发明人： Kai H. Lochhaas ,  Steven J. Hamrock ,  Klaus Hintzer

    IPC分类号： H01M8/10

    CPC分类号： H01M8/102 ,  C08F214/18 ,  C08J5/2237 ,  C08L41/00 ,  H01M8/1023 ,  H01M8/1032 ,  H01M8/1039 ,  H01M8/1051 ,  H01M8/1072 ,  H01M8/109 ,  H01M2300/0082 ,  Y02P70/56

    摘要： Described herein is a composition comprising: a polymer derived from (a) a fluorinated olefin monomer; (b) a highly fluorinated sulfur-containing monomer of the formula: CX1X2═CX3[(CX4X5)w—O—R1—SO2Y] where X1, X2, X3, X4, and X5 are independently selected from H, Cl, or F; w is 0 or 1; R1 is a non-fluorinated or fluorinated alkylene group; and Y is selected from F, Cl, Br, I, or OM, where M is a cation; and (c) a poly-functional monomer comprising at least two functional groups, wherein the functional groups are selected from the group consisting of: (i) a fluorovinyl ether group, (ii) a fluoroallyl ether group, (iii) a fluorinated olefinic group, and (iv) combinations thereof; articles thereof; and a method of making such polymers.

    摘要翻译： 本文描述的组合物包含：衍生自（a）氟化烯烃单体的聚合物; （b）具有下式的高度含氟的含硫单体：CX1X2 = C3 [[（CX4X5）w-O-R1-SO2Y]其中X1，X2，X3，X4和X5独立地选自H，Cl或F ; w为0或1; R1是非氟化或氟化亚烷基; Y选自F，Cl，Br，I或OM，其中M是阳离子; 和（c）包含至少两个官能团的多官能单体，其中所述官能团选自：（i）氟乙烯基醚基团，（ii）氟烯基醚基团，（iii）氟化烯烃 组，和（iv）它们的组合; 其制品; 和制备这种聚合物的方法。

    Aqueous emulsion polymerization of functionalized fluoromonomers
    4.
    发明授权
    Aqueous emulsion polymerization of functionalized fluoromonomers 有权
    官能化含氟单体的水乳液聚合

    公开(公告)号：US07071271B2

    公开(公告)日：2006-07-04

    申请号：US10697768

    申请日：2003-10-30

    申请人： Arne Thaler ,  Klaus Hintzer ,  Kai H. Lochhaas ,  Franz Maerz ,  Steven J. Hamrock

    发明人： Arne Thaler ,  Klaus Hintzer ,  Kai H. Lochhaas ,  Franz Maerz ,  Steven J. Hamrock

    IPC分类号： C08F114/18

    CPC分类号： C08F214/18 ,  C08F214/184

    摘要： A method is provided for aqueous emulsion co-polymerization of two or more fluoromonomers comprising the steps of: 1) forming an aqueous pre-emulsion by mixing a fluoromonomer according to formula I: F2C═CF—R1—SO2X  (I) wherein R1 is a branched or unbranched perfluoroalkyl, perfluoroalkoxy or perfluoroether group comprising 1–15 carbon atoms and 0–4 oxygen atoms and wherein X is F, Cl or Br, together with 0.001–0.9 molar equivalents of a base, in the absence of added emulsifier; and 2) reacting the pre-emulsion with one or more perfluorinated comonomers in the absence of added emulsifier so as to form a fluoropolymer latex comprising a fluoropolymer wherein more than 1 mol % of monomer units are derived from the fluoromonomer according to formula I. In another aspect, the present invention provides a fluoropolymer derived from the fluoropolymer latex made according to the method of the present invention which is free of added emulsifier. In another aspect, the present invention provides a polymer electrolyte membrane comprising the fluoropolymer made according to the method of the present invention which is free of added emulsifier.

    摘要翻译： 提供了一种用于两种或更多种含氟单体的水乳液共聚的方法，包括以下步骤：1）通过混合式I的含氟单体形成水性预乳液：<？in-line-formula description =“In-line 公式“end =”lead“？> F 2 C-CF-R 1 -SO 2 X（I）<βin-line -formulae description =“In-line Formulas”end =“tail”？>其中R 1是支链或非支链全氟烷基，包含1-15个碳原子和0-4个氧原子的全氟烷氧基或全氟醚基团 在不加入乳化剂的情况下，X是F，Cl或Br，以及0.001-0.9摩尔当量的碱; 和2）在不存在加入的乳化剂的情况下使预乳液与一种或多种全氟化共聚单体反应，以便形成含氟聚合物的含氟聚合物胶乳，其中大于1mol％的单体单元衍生自根据式I的含氟单体。 另一方面，本发明提供了衍生自根据本发明的方法制备的含氟聚合物胶乳的氟聚合物，其不含添加的乳化剂。 另一方面，本发明提供了一种聚合物电解质膜，其包含根据本发明的方法制备的含氟聚合物，其不含添加的乳化剂。

    Fluorinated ether compositions and methods of using the same
    8.
    发明授权
    Fluorinated ether compositions and methods of using the same 失效
    氟化醚组合物及其使用方法

    公开(公告)号：US08476385B2

    公开(公告)日：2013-07-02

    申请号：US12602877

    申请日：2008-06-06

    申请人： Rudolf J. Dams ,  Miguel A. Guerra ,  Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Kai H. Lochhaas ,  Andreas R. Maurer ,  Zai-Ming Qiu ,  Werner Schwertfeger ,  Michael S. Terrazas ,  Tilman C. Zipplies

    发明人： Rudolf J. Dams ,  Miguel A. Guerra ,  Klaus Hintzer ,  Michael Jürgens ,  Harald Kaspar ,  Kai H. Lochhaas ,  Andreas R. Maurer ,  Zai-Ming Qiu ,  Werner Schwertfeger ,  Michael S. Terrazas ,  Tilman C. Zipplies

    IPC分类号： C08F18/20

    CPC分类号： C08F220/24 ,  C08F220/28 ,  C08F220/36 ,  C08F230/08 ,  C08G65/007 ,  C08L33/08 ,  C08L35/06 ,  C09D133/08 ,  C09D133/14 ,  C09D135/06 ,  C08L2666/04

    摘要： A composition including at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHF—(CF2)n—; [Rfa—(O)t—C(L)H—CF2—O]m—W—; Rfb-O—(CF2)p-; F(CkF2k)—(O—CkF2k)P—O—CF2—; and CF3—O—(CF2)3—(OCF(CF3)—CF2)Z—O-L1-. Each Q is independently selected from the group consisting of a bond, —C(O)—N(R1)—, and —C(O)—O—. Each X is independently selected from the group consisting of alkylene and arylalkylene, wherein alkylene and arylalkylene are each optionally interrupted by at least one ether linkage and optionally terminated by —N(R1)—C(O)— or —O—C(O)—. R and R1 are each independently selected from the group consisting of hydrogen and alkyl having from 1 to 4 carbon atoms. Rfa represents a partially or fully fluorinated alkyl group having from 1 to 10 carbon atoms and optionally interrupted with at least one oxygen atom. Rfb is selected from the group consisting of CF3CFH— and F(CjF2j)-. Methods of reducing surface tension of a liquid, making foams, and treating a surface using the compositions are also disclosed.

    摘要翻译： 包含至少一个由式表示的第一二价单元的组合物：每个Rf独立地选自Rfa-（O）t-CHF-（CF 2）n - ; [Rfa-（O）t -C（L）H-CF 2 -O] m -W-; Rfb-O-（CF2）p-; F（CkF2k） - （O-CkF2k）P-O-CF2-; 和CF 3 -O-（CF 2）3 - （OCF（CF 3）-CF 2）Z-O-L 1。 每个Q独立地选自由键，-C（O）-N（R 1） - 和-C（O）-O-组成的组。 每个X独立地选自亚烷基和芳基亚烷基，其中亚烷基和芳基亚烷基各自任选地被至少一个醚键中断，并且任选地被-N（R 1）-C（O） - 或-OC（O） - 。 R和R 1各自独立地选自氢和具有1至4个碳原子的烷基。 Rfa表示具有1至10个碳原子并且任选被至少一个氧原子中断的部分或完全氟化的烷基。 Rfb选自CF 3 CFH-和F（C 1 F 2）） - 。 还公开了降低液体的表面张力，制造泡沫和使用组合物处理表面的方法。