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公开(公告)号：US08981043B2
公开(公告)日：2015-03-17
申请号：US13611723
申请日：2012-09-12
申请人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , BunYeoul Lee , SungJae Na
发明人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , BunYeoul Lee , SungJae Na
IPC分类号： C08G64/02 , C08G65/26 , C07F15/06 , C07C39/23 , C07C249/00
CPC分类号： C08G64/34 , C07F15/065 , C08G64/0208 , C08G65/2603 , C08G65/266
摘要： The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst.According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.
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2.发明授权Method for preparing carbon dioxide/epoxide copolymers containing ether linkages 有权制备含醚键的二氧化碳/环氧化物共聚物的方法公开(公告)号：US08871898B2
公开(公告)日：2014-10-28
申请号：US13406065
申请日：2012-02-27
申请人： JiSu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , BunYeoul Lee , Kodiyan Varghese Jobi
发明人： JiSu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , BunYeoul Lee , Kodiyan Varghese Jobi
CPC分类号： C08G64/34 , C08G65/2603 , C08G65/2663
摘要： Provided is a method for preparing poly(alkylene carbonate) containing ether linkages, by the copolymerization of an epoxy compound and carbon dioxide, with a trivalent metal complex prepared from a salen type ligand containing a quaternary ammonium salt, and a double metal cyanide (DMC) catalyst together. The amount of ether linkages can be controlled by regulating the weight ratio of two catalysts and the carbon dioxide pressure.
摘要翻译： 提供了通过环氧化合物和二氧化碳的共聚合制备由含有季铵盐的salen型配体和双金属氰化物（DMC）制备的三价金属络合物制备含有醚键的聚（碳酸亚烷基酯）的方法 ）催化剂。 醚键的量可以通过调节两种催化剂的重量比和二氧化碳压力来控制。
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3.发明授权Polymer electrolyte composition and dye-sensitized solar cell containing the same 有权聚合物电解质组合物和含有它的染料敏化太阳能电池公开(公告)号：US08900483B2
公开(公告)日：2014-12-02
申请号：US13431411
申请日：2012-03-27
申请人： Yonggyu Han , Sujith Sudevan , MyungAhn Ok , Jisu Jeong , SungJae Na , KwangJin Chung , Dong-Won Kim , YeonJeong Choi
发明人： Yonggyu Han , Sujith Sudevan , MyungAhn Ok , Jisu Jeong , SungJae Na , KwangJin Chung , Dong-Won Kim , YeonJeong Choi
CPC分类号： H01B1/124 , C08K3/16 , C08K3/20 , C08K3/22 , C08K3/36 , H01G9/2009 , Y02E10/542 , C08L69/00
摘要： Disclosed is a polymer electrolyte composition, a gel-type polymer electrolyte obtained by mixing the same at normal temperature, and a dye-sensitized solar cell containing the electrolyte. Since the poly(alkylene carbonate)-based polymer is included, a crosslinking process by radiation of heat or UV is not required when the polymer electrolyte is manufactured, such that a manufacturing process is simple. Accordingly, the polymer electrolyte is useful for mass production of a solar cell and maintained in a uniform state without a phase separation between two components due to excellent affinity between the polymer and the organic solvent included in the electrolyte, and has excellent electrode-electrolyte interface property in the solar cell due to an adhesive property of the gelled polymer electrolyte.
摘要翻译： 公开了一种聚合物电解质组合物，通常在常温下将其混合而获得的凝胶型聚合物电解质和含有电解质的染料敏化太阳能电池。 由于包含聚（碳酸亚烷基碳酸酯）基聚合物，所以当制造聚合物电解质时，不需要通过辐射热或UV的交联过程，使得制造过程简单。 因此，由于聚合物与包含在电解质中的有机溶剂之间的亲和性优异，聚合物电解质可用于大量生产太阳能电池并保持在均匀状态，而不会由于两种组分之间的相分离，并且具有优异的电极 - 电解质界面 由于胶凝聚合物电解质的粘合性，在太阳能电池中的性能。
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4.发明授权Precise control of molecular weight and chain shape control in carbon dioxide/epoxide alternating copolymerization and preparation of low molecular weight poly(alkylene carbonate) thereby 有权精确控制二氧化碳/环氧交联共聚中的分子量和链形状控制，从而制备低分子量聚（碳酸亚烷基酯）公开(公告)号：US08530616B2
公开(公告)日：2013-09-10
申请号：US12952642
申请日：2010-11-23
申请人： Jisu Jeong , SungJae Na , Sujith Sudevan , Myungahn Ok , YoungGyu Han , KwangJin Chung , Bun Yeoul Lee , Anish Cyriac
发明人： Jisu Jeong , SungJae Na , Sujith Sudevan , Myungahn Ok , YoungGyu Han , KwangJin Chung , Bun Yeoul Lee , Anish Cyriac
CPC分类号： C08G64/0208 , C08G64/0216 , C08G64/34 , C08G64/406 , C08G65/2603
摘要： This invention relates to a method of preparing poly(alkylene carbonate) that has a molecular weight and polymer chain structure precisely controlled by adding a chain transfer agent composed of a compound having an alcohol or carboxylic acid functional group upon alternating copolymerization of an epoxide compound and carbon dioxide using a catalyst composed of a trivalent metal complex compound synthesized from a quaternary ammonium salt-containing Salen type ligand, and to a polymer compound prepared thereby. According to this invention, the polymer compound having a star-shaped chain as well as the polymer having a linear chain can be prepared. The low-molecular-weight poly(alkylene carbonate) has an —OH terminal group and can be used alone as a coating agent, etc., and also in mixtures with an isocyanate compound and thus can be easily utilized to prepare polyurethane.
摘要翻译： 本发明涉及一种制备聚（亚烷基碳酸酯）的方法，该聚（碳酸亚烷基酯）具有通过在环氧化合物与环氧化合物交替共聚合的情况下由具有醇或羧酸官能团的化合物组成的链转移剂， 使用由含有季铵盐的Salen型配体合成的三价金属络合物组成的催化剂和由其制备的高分子化合物。 根据本发明，可以制备具有星形链的高分子化合物以及具有直链的聚合物。 低分子量聚（碳酸亚烷基酯）具有-OH端基，可以单独使用作为涂布剂等，也可以与异氰酸酯化合物的混合物使用，因此可以容易地用于制备聚氨酯。
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5.发明申请Block and Graft Copolymers of Poly(Alkylene Carbonate) and Various Polymers 有权聚（碳酸亚烷基酯）和各种聚合物的嵌段和接枝共聚物公开(公告)号：US20110251355A1
公开(公告)日：2011-10-13
申请号：US13036714
申请日：2011-02-28
申请人： JiSu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , Bun Yeoul Lee , Anish Cyriac , SangHwan Lee
发明人： JiSu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , Bun Yeoul Lee , Anish Cyriac , SangHwan Lee
IPC分类号： C08G64/42
CPC分类号： C08G81/027 , C08G63/64 , C08G64/18 , C08G64/183 , C08G64/186 , C08G64/34
摘要： Provided is preparation of poly(alkylene carbonate) by alternating copolymerization of carbon dioxide and epoxide. To be specific, provided are a method for preparing block or graft copolymers of the polymer compound and poly(alkylene carbonate) by alternating-copolymerization of an epoxide compound and carbon dioxide by using a metal (III) compound prepared from salen-type ligand with a quaternary ammonium salt as a catalyst in the presence of a polymer compound having a functional group of hydroxyl or carboxylic acid, and block or graft copolymers prepared by the method.
摘要翻译： 提供通过二氧化碳和环氧化物的交替共聚制备聚（碳酸亚烷基酯）。 具体来说，提供了通过使用由salen型配体制备的金属（III）化合物与环氧化合物和二氧化碳的交替共聚来制备高分子化合物和聚（碳酸亚烷基酯）的嵌段或接枝共聚物的方法， 在具有羟基或羧酸官能团的高分子化合物存在下作为催化剂的季铵盐，以及通过该方法制备的嵌段或接枝共聚物。
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6.发明授权Flame-retarding carbon dioxide/epoxide copolymer and method for preparing the same 有权阻燃二氧化碳/环氧化物共聚物及其制备方法公开(公告)号：US08912307B2
公开(公告)日：2014-12-16
申请号：US13369991
申请日：2012-02-09
申请人： Jisu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , BunYeoul Lee , Anish Cyriac , SangHwan Lee
发明人： Jisu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , BunYeoul Lee , Anish Cyriac , SangHwan Lee
IPC分类号： C08G59/68 , C08G65/10 , C08G64/40 , C08G64/02 , C08G65/26 , C08G64/34 , C08G59/00 , C08G65/04
CPC分类号： C08G64/34 , C08G64/0208 , C08G64/0258 , C08G64/403 , C08G64/406 , C08G65/2603
摘要： There is provided a method for preparing a low-molecular weight poly(alkylene carbonate) of which the molecular weight and chain shape are precisely controlled, by introducing a phosphorous compound having a hydroxyl group as a chain transfer agent in order to regulate the molecular weight, in alternating copolymerizing an epoxide compound and carbon dioxide by using trivalent metal complex prepared from a Salen type ligand containing a quaternary ammonium salt, and a polymer prepared by the method.Since poly(alkylene carbonate) prepared according to the present invention includes a phosphate or phosphonate group in the polymer chain, it has flame-retarding property.
摘要翻译： 提供了通过引入具有羟基的磷化合物作为链转移剂来制备其分子量和链形状被精确控制的低分子量聚（碳酸亚烷基酯）的方法，以调节分子量 通过使用由含有季铵盐的Salen型配体制备的三价金属络合物和通过该方法制备的聚合物来交替共聚环氧化合物和二氧化碳。 由于根据本发明制备的聚（碳酸亚烷基酯）在聚合物链中包含磷酸酯或膦酸酯基，因此具有阻燃性。
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公开(公告)号：US20130131308A1
公开(公告)日：2013-05-23
申请号：US13611723
申请日：2012-09-12
申请人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , Bun Yeoul Lee , SungJae Na
发明人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , Bun Yeoul Lee , SungJae Na
IPC分类号： C08G64/02
CPC分类号： C08G64/34 , C07F15/065 , C08G64/0208 , C08G65/2603 , C08G65/266
摘要： The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst.According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.
摘要翻译： 本发明涉及一种制备聚碳酸酯的方法，包括使用钴（III）或铬（III）共聚环氧化合物和CO 2的方法，其中配体含有至少3个铵阳离子，中心金属具有正电荷-1， 两个阳离子铵基团的共轭阴离子是酸碱共结合作为催化剂。 根据本发明，当制造所述聚碳酸酯时可以减少初始诱导时间，并且可以提高催化剂的活性和所得聚合物的分子量。
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8.发明申请Flame-Retarding Carbon Dioxide/Epoxide Copolymer and Method for Preparing the Same 有权阻燃二氧化碳/环氧化物共聚物及其制备方法公开(公告)号：US20120208979A1
公开(公告)日：2012-08-16
申请号：US13369991
申请日：2012-02-09
申请人： Jisu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , BunYeoul Lee , Anish Cyriac , SangHwan Lee
发明人： Jisu Jeong , SungJae Na , Sujith Sudevan , MyungAhn Ok , YongGyu Han , KwangJin Chung , BunYeoul Lee , Anish Cyriac , SangHwan Lee
IPC分类号： C08G79/04
CPC分类号： C08G64/34 , C08G64/0208 , C08G64/0258 , C08G64/403 , C08G64/406 , C08G65/2603
摘要： There is provided a method for preparing a low-molecular weight poly(alkylene carbonate) of which the molecular weight and chain shape are precisely controlled, by introducing a phosphorous compound having a hydroxyl group as a chain transfer agent in order to regulate the molecular weight, in alternating copolymerizing an epoxide compound and carbon dioxide by using trivalent metal complex prepared from a Salen type ligand containing a quaternary ammonium salt, and a polymer prepared by the method.Since poly(alkylene carbonate) prepared according to the present invention includes a phosphate or phosphonate group in the polymer chain, it has flame-retarding property.
摘要翻译： 提供了通过引入具有羟基的磷化合物作为链转移剂来制备其分子量和链形状被精确控制的低分子量聚（碳酸亚烷基酯）的方法，以调节分子量 通过使用由含有季铵盐的Salen型配体制备的三价金属络合物和通过该方法制备的聚合物来交替共聚环氧化合物和二氧化碳。 由于根据本发明制备的聚（碳酸亚烷基酯）在聚合物链中包含磷酸酯或膦酸酯基，因此具有阻燃性。
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公开(公告)号：US20100324260A1
公开(公告)日：2010-12-23
申请号：US12817588
申请日：2010-06-17
申请人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , BunYeoul Lee , SungJae Na
发明人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , BunYeoul Lee , SungJae Na
CPC分类号： C08G64/34 , C07F15/065 , C08G64/0208 , C08G65/2603 , C08G65/266
摘要： The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst.According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.
摘要翻译： 本发明涉及一种制备聚碳酸酯的方法，包括使用钴（III）或铬（III）共聚环氧化合物和CO 2的方法，其中配体含有至少3个铵阳离子，中心金属具有正电荷-1， 两个阳离子铵基团的共轭阴离子是酸碱共结合作为催化剂。 根据本发明，当制造所述聚碳酸酯时可以减少初始诱导时间，并且可以提高催化剂的活性和所得聚合物的分子量。
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公开(公告)号：US08987411B2
公开(公告)日：2015-03-24
申请号：US12817588
申请日：2010-06-17
申请人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , BunYeoul Lee , SungJae Na
发明人： Jisu Jeong , Sujith Sudevan , Myungahn Ok , Jieun Yoo , BunYeoul Lee , SungJae Na
CPC分类号： C08G64/34 , C07F15/065 , C08G64/0208 , C08G65/2603 , C08G65/266
摘要： The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal −1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst.According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.
摘要翻译： 本发明涉及一种制备聚碳酸酯的方法，包括使用钴（III）或铬（III）共聚环氧化合物和CO 2的方法，其中配体含有至少3个铵阳离子，中心金属具有正电荷-1， 两个阳离子铵基团的共轭阴离子是酸碱共结合作为催化剂。 根据本发明，当制造所述聚碳酸酯时可以减少初始诱导时间，并且可以提高催化剂的活性和所得聚合物的分子量。
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