公开(公告)号：US09921503B2

公开(公告)日：2018-03-20

申请号：US15122087

申请日：2015-01-06

申请人： Hiroshi Yamada ,  Tsuyoshi Sugimoto ,  Susumu Chiba ,  Shinsuke Nagai ,  Kohsuke Nagata ,  Shinya Nakayama ,  Yuka Mizoguchi ,  Suzuka Amemori

发明人： Hiroshi Yamada ,  Tsuyoshi Sugimoto ,  Susumu Chiba ,  Shinsuke Nagai ,  Kohsuke Nagata ,  Shinya Nakayama ,  Yuka Mizoguchi ,  Suzuka Amemori

IPC分类号： G03G9/08 ,  G03G9/087 ,  G03G9/09 ,  G03G15/08

CPC分类号： G03G9/08755 ,  G03G9/0806 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/0904 ,  G03G15/08

摘要： A toner including: a pigment; polyester resin A that is insoluble in tetrahydrofuran (THF); and polyester resin B that is soluble in THF, wherein the toner satisfies requirements (1) to (3) below: (1) the polyester resin A includes one or more aliphatic diols including from 3 through 10 carbon atoms, as a component constituting the polyester resin A; (2) the polyester resin B includes at least an alkylene glycol in an amount of 40 mol % or more, as a component constituting the polyester resin B; and (3) a glass transition temperature (Tg1st) of the toner at first heating in differential scanning calorimetry (DSC) of the toner is from 20° C. through 50° C.

公开(公告)号：US09885967B2

公开(公告)日：2018-02-06

申请号：US15021638

申请日：2014-08-13

申请人： Azumi Miyaake ,  Daisuke Asahina ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Shinya Nakayama ,  Susumu Chiba ,  Satoyuki Sekiguchi

发明人： Azumi Miyaake ,  Daisuke Asahina ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Tsuyoshi Sugimoto ,  Shinya Nakayama ,  Susumu Chiba ,  Satoyuki Sekiguchi

IPC分类号： G03G9/087 ,  G03G9/08 ,  G03G15/08

CPC分类号： G03G9/0821 ,  G03G9/08764 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/08

摘要： Provided is a resin for a toner, which is a copolymer including a crystalline segment, and having a maximum elastic stress value at 100° C. (ES100) of 1,000 Pa or less, and a maximum elastic stress value at 70° C. (ES70) of 1,000 Pa or greater when the temperature is lowered from 100° C. to 70° C., where the maximum elastic stress values are measured according to a large amplitude oscillatory shear procedure.

公开(公告)号：US09785075B2

公开(公告)日：2017-10-10

申请号：US14433770

申请日：2013-10-11

申请人： Shinya Nakayama ,  Atsushi Yamamoto ,  Minoru Masuda ,  Susumu Chiba ,  Toyoshi Sawada ,  Hiroshi Yamashita

发明人： Shinya Nakayama ,  Atsushi Yamamoto ,  Minoru Masuda ,  Susumu Chiba ,  Toyoshi Sawada ,  Hiroshi Yamashita

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08764 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797

摘要： Provided is a toner containing a binder resin. The binder resin contains a crystalline resin. The toner has a maximum endothermic peak temperature (P1) of from 50° C. to 80° C. and a total endothermic amount (Q) of from 35 J/g to 90 J/g at a first temperature elevation of differential scanning calorimetry. A ratio (Qp/Q) of a total endothermic amount (Qp) of the toner in a temperature range of from 20° C. to the maximum endothermic peak temperature (P1) to the total endothermic amount (Q) of the toner is from 0.65 to 0.83.

公开(公告)号：US20170017175A1

公开(公告)日：2017-01-19

申请号：US15122087

申请日：2015-01-06

申请人： Hiroshi YAMADA ,  Tsuyoshi SUGIMOTO ,  Susumu CHIBA ,  Shinsuke NAGAI ,  Kohsuke NAGATA ,  Shinya NAKAYAMA ,  Yuka MIZOGUCHI ,  Suzuka AMEMORI

发明人： Hiroshi YAMADA ,  Tsuyoshi SUGIMOTO ,  Susumu CHIBA ,  Shinsuke NAGAI ,  Kohsuke NAGATA ,  Shinya NAKAYAMA ,  Yuka MIZOGUCHI ,  Suzuka AMEMORI

IPC分类号： G03G9/00

CPC分类号： G03G9/08755 ,  G03G9/0806 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/0904 ,  G03G15/08

摘要： A toner including: a pigment; polyester resin A that is insoluble in tetrahydrofuran (THF); and polyester resin B that is soluble in THF, wherein the toner satisfies requirements (1) to (3) below:(1) the polyester resin A includes one or more aliphatic diols including from 3 through 10 carbon atoms, as a component constituting the polyester resin A; (2) the polyester resin B includes at least an alkylene glycol in an amount of 40 mol % or more, as a component constituting the polyester resin B; and (3) a glass transition temperature (Tg1st) of the toner at first heating in differential scanning calorimetry (DSC) of the toner is from 20° C. through 50° C.

摘要翻译： 一种调色剂，包括：颜料; 不溶于四氢呋喃（THF）的聚酯树脂A; 和可溶于THF的聚酯树脂B，其中调色剂满足以下要求（1）至（3）：（1）聚酯树脂A包括一种或多种包含3至10个碳原子的脂族二醇作为构成 聚酯树脂A; （2）作为构成聚酯树脂B的成分，聚酯树脂B至少含有40摩尔％以上的亚烷基二醇， 和（3）调色剂的差示扫描量热法（DSC）中第一次加热时调色剂的玻璃化转变温度（Tglst）为20℃至50℃。

公开(公告)号：US20160223926A1

公开(公告)日：2016-08-04

申请号：US15021638

申请日：2014-08-13

申请人： Azumi MIYAAKE ,  Daisuke ASAHINA ,  Toyoshi SAWADA ,  Hiroshi YAMASHITA ,  Tsuyoshi SUGIMOTO ,  Shinya NAKAYAMA ,  Susumu CHIBA ,  Satoyuki SEKIGUCHI

发明人： Azumi MIYAAKE ,  Daisuke ASAHINA ,  Toyoshi SAWADA ,  Hiroshi YAMASHITA ,  Tsuyoshi SUGIMOTO ,  Shinya NAKAYAMA ,  Susumu CHIBA ,  Satoyuki SEKIGUCHI

IPC分类号： G03G9/08 ,  G03G15/08 ,  G03G9/087

CPC分类号： G03G9/0821 ,  G03G9/08764 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/08

摘要： Provided is a resin for a toner, which is a copolymer including a crystalline segment, and having a maximum elastic stress value at 100° C. (ES-100) of 1,000 Pa or less, and a maximum elastic stress value at 70° C. (ES70) of 1,000 Pa or greater when the temperature is lowered from 100° C. to 70° C., where the maximum elastic stress values are measured according to a large amplitude oscillatory shear procedure.

摘要翻译： 本发明提供一种调色剂用树脂，其为含有结晶性部分的共聚物，在100℃（ES-100）为1000Pa以下，70℃时的最大弹性应力值为最大弹性应力值 （ES70）当温度从100℃降低到70℃时为1,000Pa以上，其中最大弹性应力值根据大幅度振荡剪切程序测量。

公开(公告)号：US20150132690A1

公开(公告)日：2015-05-14

申请号：US14534495

申请日：2014-11-06

申请人： Daisuke ASAHINA ,  Azumi MIYAAKE ,  Tsuyoshi SUGIMOTO ,  Susumu CHIBA ,  Shinya NAKAYAMA ,  Hiroshi YAMASHITA ,  Satoyuki SEKIGUCHI

发明人： Daisuke ASAHINA ,  Azumi MIYAAKE ,  Tsuyoshi SUGIMOTO ,  Susumu CHIBA ,  Shinya NAKAYAMA ,  Hiroshi YAMASHITA ,  Satoyuki SEKIGUCHI

IPC分类号： G03G9/00

CPC分类号： G03G9/08755 ,  G03G9/0821 ,  G03G9/08795 ,  G03G9/08797

摘要： A toner includes a binder resin including a copolymer resin (A) having a structural unit derived from a crystalline polyester resin (A1) and another structural unit derived from an amorphous polyester resin (A2), and an amorphous resin (B) in an amount of from 30 to 70% by weight based on total weight of the binder resin. The binarized image of the AFM phase image of the binder resin consists of first phase-contrast images serving as large-phase-difference portions and second phase-contrast images serving as small-phase-difference portions with the first phase-contrast images dispersed in the second phase-contrast images forming a dot-like or streaky structure. The average value of dispersion diameters, corresponding to maximum Feret diameters, of the first phase-contrast images in the dot-like structure, or widths, corresponding to minimum Feret diameters, of the first phase-contrast images in the streaky structure, is less than 100 nm.

摘要翻译： 调色剂包括具有来自结晶性聚酯树脂（A1）的结构单元和来自非晶质聚酯树脂（A2）的另一结构单元的共聚物树脂（A）和来自非晶质聚酯树脂（A2）的非晶性树脂（B）的粘合剂树脂， 为基于粘合剂树脂的总重量的30至70重量％。 粘合剂树脂的AFM相图像的二值化图像由用作大相差部分的第一相位对比图像和用作小相位差部分的第二相位差图像组成，第一相位对比图像分散在 第二相差图像形成点状或条纹结构。 相对于条纹结构中的第一相对比图像的点状结构中的第一相对比图像或对应于最小Feret直径的宽度的最大Feret直径的色散直径的平均值较小 超过100nm。

公开(公告)号：US20140051019A1

公开(公告)日：2014-02-20

申请号：US13958745

申请日：2013-08-05

申请人： Satoyuki Sekiguchi ,  Hiroshi Yamashita ,  Minoru Masuda ,  Susumu Chiba ,  Tatsuya Morita ,  Atsushi Yamamoto ,  Shinya Nakayama ,  Masahide Yamada ,  Kohsuke Nagata ,  Keiji Makabe ,  Toyoshi Sawada

发明人： Satoyuki Sekiguchi ,  Hiroshi Yamashita ,  Minoru Masuda ,  Susumu Chiba ,  Tatsuya Morita ,  Atsushi Yamamoto ,  Shinya Nakayama ,  Masahide Yamada ,  Kohsuke Nagata ,  Keiji Makabe ,  Toyoshi Sawada

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08764 ,  G03G9/0804 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/08797

摘要： Toner contains a binder resin containing a crystalline resin having a urethane and/or urea bonding; and a colorant, wherein in a diffraction spectrum of the toner as measured by an X-ray diffraction instrument, a ratio {C/(C+A)} of an integral intensity C of the spectrum derived from the crystalline structure to an integral intensity A of the spectrum derived from the non-crystalline structure is 0.12 or greater, wherein the toner satisfies the following relation 1: T1−T2≦30° C. (Relation 1), where T1 represents the maximum endothermic peak in the first temperature rising from 0° C. to 100° C. at the temperature rising rate of 10° C./min and T2 represents the maximum exothermic peak in the first temperature falling from 100° C. to 0° C. at the temperature falling rate of 10° C./min as T1 and T2 are measured by diffraction scanning calorimetry (DSC).

摘要翻译： 调色剂含有含有具有氨基甲酸酯和/或脲键合的结晶性树脂的粘合剂树脂; 和着色剂，其中在通过X射线衍射仪测量的调色剂的衍射光谱中，从晶体结构衍生的光谱的积分强度C与积分强度之比{C /（C + A）} 衍生自非晶体结构的光谱的A为0.12或更大，其中调色剂满足以下关系1：T1-T2 @ 30℃（关系1），其中T1表示第一升温中的最大吸热峰 0℃至100℃，升温速率为10℃/分钟，T2表示在100℃至0℃的第一温度下的最大放热峰，温度下降速率为 10℃/ min，通过衍射扫描量热法（DSC）测量T1和T2。

公开(公告)号：US20140023965A1

公开(公告)日：2014-01-23

申请号：US13932556

申请日：2013-07-01

申请人： Susumu CHIBA ,  Hiroshi YAMASHITA ,  Daisuke ASAHINA ,  Tsuyoshi SUGIMOTO ,  Taichi NEMOTO ,  Satoyuki SEKIGUCHI

发明人： Susumu CHIBA ,  Hiroshi YAMASHITA ,  Daisuke ASAHINA ,  Tsuyoshi SUGIMOTO ,  Taichi NEMOTO ,  Satoyuki SEKIGUCHI

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08755 ,  G03G9/08795 ,  G03G9/08797

摘要： Toner contains a binder resin and a colorant, wherein the binder resin contains a resin having a polyhydroxy carboxylic acid skeleton, wherein the toner has a half effusion temperature of from 80° C. to 120° C. as measured by a temperature rising method using a flow tester.

摘要翻译： 调色剂含有粘合剂树脂和着色剂，其中粘合剂树脂含有具有多羟基羧酸骨架的树脂，其中调色剂的半渗透温度为80℃至120℃，通过使用温度升高法 流量测试仪。

公开(公告)号：US20130337374A1

公开(公告)日：2013-12-19

申请号：US13915804

申请日：2013-06-12

申请人： Tsuyoshi SUGIMOTO ,  Hiroshi YAMASHITA ,  Susumu CHIBA ,  Satoyuki SEKIGUCHI

发明人： Tsuyoshi SUGIMOTO ,  Hiroshi YAMASHITA ,  Susumu CHIBA ,  Satoyuki SEKIGUCHI

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/0821 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner including a binder resin and a colorant, wherein the toner has a glass transition temperature by differential scanning calorimetry (DSC) of 20° C. or greater and less than 50° C., an endothermic peak temperature by DSC of 50° C. or greater and less than 80° C. and an amount of compressive deformation at 50° C. by a thermomechanical analysis of 5% or less.

摘要翻译： 为了提供包含粘合剂树脂和着色剂的调色剂，其中调色剂通过差示扫描量热法（DSC）为20℃以上且小于50℃的玻璃化转变温度，DSC的吸热峰值温度为50℃ ℃以上且小于80℃，通过5％以下的热机械分析，在50℃下的压缩变形量。

公开(公告)号：US20120237869A1

公开(公告)日：2012-09-20

申请号：US13412231

申请日：2012-03-05

申请人： Susumu CHIBA ,  Hiroshi YAMASHITA ,  Masaki WATANABE ,  Satoyuki SEKIGUCHI ,  Daisuke ASAHINA

发明人： Susumu CHIBA ,  Hiroshi YAMASHITA ,  Masaki WATANABE ,  Satoyuki SEKIGUCHI ,  Daisuke ASAHINA

IPC分类号： G03G9/087

CPC分类号： G03G9/08755 ,  G03G9/0804 ,  G03G9/0806 ,  G03G9/0819 ,  G03G9/0821 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/09708

摘要： A toner including a colorant and a binder resin is provided. The binder resin includes a polyester resin having a glass transition temperature of 18 to 40° C., a weight average molecular weight of 10,000 to 100,000, and a flow beginning temperature of 70 to 120° C. The toner has a volume average particle diameter of 3 to 10 μm.

摘要翻译： 提供了包括着色剂和粘合剂树脂的调色剂。 粘合剂树脂包括玻璃化转变温度为18〜40℃，重均分子量为10,000〜100,000，流动开始温度为70〜120℃的聚酯树脂。调色剂的体积平均粒径 为3〜10μm。