公开(公告)号：US09176406B2

公开(公告)日：2015-11-03

申请号：US13958745

申请日：2013-08-05

申请人： Satoyuki Sekiguchi ,  Hiroshi Yamashita ,  Minoru Masuda ,  Susumu Chiba ,  Tatsuya Morita ,  Atsushi Yamamoto ,  Shinya Nakayama ,  Masahide Yamada ,  Kohsuke Nagata ,  Keiji Makabe ,  Toyoshi Sawada

发明人： Satoyuki Sekiguchi ,  Hiroshi Yamashita ,  Minoru Masuda ,  Susumu Chiba ,  Tatsuya Morita ,  Atsushi Yamamoto ,  Shinya Nakayama ,  Masahide Yamada ,  Kohsuke Nagata ,  Keiji Makabe ,  Toyoshi Sawada

IPC分类号： G03G9/00 ,  G03G9/087 ,  G03G9/13 ,  G03G9/08

CPC分类号： G03G9/08764 ,  G03G9/0804 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/08797

摘要： Toner contains a binder resin containing a crystalline resin having a urethane and/or urea bonding; and a colorant, wherein in a diffraction spectrum of the toner as measured by an X-ray diffraction instrument, a ratio {C/(C+A)} of an integral intensity C of the spectrum derived from the crystalline structure to an integral intensity A of the spectrum derived from the non-crystalline structure is 0.12 or greater, wherein the toner satisfies the following relation 1: T1−T2≦30° C. (Relation 1), where T1 represents the maximum endothermic peak in the first temperature rising from 0° C. to 100° C. at the temperature rising rate of 10° C./min and T2 represents the maximum exothermic peak in the first temperature falling from 100° C. to 0° C. at the temperature falling rate of 10° C./min as T1 and T2 are measured by diffraction scanning calorimetry (DSC).

摘要翻译： 调色剂含有含有具有氨基甲酸酯和/或脲键合的结晶性树脂的粘合剂树脂; 和着色剂，其中在通过X射线衍射仪测量的调色剂的衍射光谱中，从晶体结构衍生的光谱的积分强度C与积分强度之比{C /（C + A）} 衍生自非晶体结构的光谱的A为0.12或更大，其中调色剂满足以下关系1：T1-T2＆nlE; 30℃（关系1），其中T1表示第一升温中的最大吸热峰 0℃至100℃，升温速率为10℃/分钟，T2表示在100℃至0℃的第一温度下的最大放热峰，温度下降速率为 10℃/ min，通过衍射扫描量热法（DSC）测量T1和T2。

公开(公告)号：US20150248073A1

公开(公告)日：2015-09-03

申请号：US14433770

申请日：2013-10-11

申请人： Shinya Nakayama ,  Atsushi Yamamoto ,  Minoru Masuda ,  Susumu Chiba ,  Toyoshi Sawada ,  Hiroshi Yamashita

发明人： Shinya Nakayama ,  Atsushi Yamamoto ,  Minoru Masuda ,  Susumu Chiba ,  Toyoshi Sawada ,  Hiroshi Yamashita

IPC分类号： G03G9/00

CPC分类号： G03G9/08764 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797

摘要： Provided is a toner containing a binder resin. The binder resin contains a crystalline resin. The toner has a maximum endothermic peak temperature (P1) of from 50° C. to 80° C. and a total endothermic amount (Q) of from 35 J/g to 90 J/g at a first temperature elevation of differential scanning calorimetry. A ratio (Qp/Q) of a total endothermic amount (Qp) of the toner in a temperature range of from 20° C. to the maximum endothermic peak temperature (P1) to the total endothermic amount (Q) of the toner is from 0.65 to 0.83.

摘要翻译： 提供含有粘合剂树脂的调色剂。 粘合剂树脂含有结晶性树脂。 在差示扫描量热法的第一温度升高下，调色剂具有50℃至80℃的最大吸热峰温度（P1）和35J / g至90J / g的总吸热量（Q） 。 调色剂在20℃至最大吸热峰温度（P1）的温度范围内的总吸热量（Qp）与总吸热量（Q）之间的比例（Qp / Q）来自 0.65〜0.83。

公开(公告)号：US09785075B2

公开(公告)日：2017-10-10

申请号：US14433770

申请日：2013-10-11

申请人： Shinya Nakayama ,  Atsushi Yamamoto ,  Minoru Masuda ,  Susumu Chiba ,  Toyoshi Sawada ,  Hiroshi Yamashita

发明人： Shinya Nakayama ,  Atsushi Yamamoto ,  Minoru Masuda ,  Susumu Chiba ,  Toyoshi Sawada ,  Hiroshi Yamashita

IPC分类号： G03G9/087 ,  G03G9/08

CPC分类号： G03G9/08764 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08788 ,  G03G9/08795 ,  G03G9/08797

摘要： Provided is a toner containing a binder resin. The binder resin contains a crystalline resin. The toner has a maximum endothermic peak temperature (P1) of from 50° C. to 80° C. and a total endothermic amount (Q) of from 35 J/g to 90 J/g at a first temperature elevation of differential scanning calorimetry. A ratio (Qp/Q) of a total endothermic amount (Qp) of the toner in a temperature range of from 20° C. to the maximum endothermic peak temperature (P1) to the total endothermic amount (Q) of the toner is from 0.65 to 0.83.

公开(公告)号：US20140051019A1

公开(公告)日：2014-02-20

申请号：US13958745

申请日：2013-08-05

申请人： Satoyuki Sekiguchi ,  Hiroshi Yamashita ,  Minoru Masuda ,  Susumu Chiba ,  Tatsuya Morita ,  Atsushi Yamamoto ,  Shinya Nakayama ,  Masahide Yamada ,  Kohsuke Nagata ,  Keiji Makabe ,  Toyoshi Sawada

发明人： Satoyuki Sekiguchi ,  Hiroshi Yamashita ,  Minoru Masuda ,  Susumu Chiba ,  Tatsuya Morita ,  Atsushi Yamamoto ,  Shinya Nakayama ,  Masahide Yamada ,  Kohsuke Nagata ,  Keiji Makabe ,  Toyoshi Sawada

IPC分类号： G03G9/00 ,  G03G15/08

CPC分类号： G03G9/08764 ,  G03G9/0804 ,  G03G9/08755 ,  G03G9/08795 ,  G03G9/08797

摘要： Toner contains a binder resin containing a crystalline resin having a urethane and/or urea bonding; and a colorant, wherein in a diffraction spectrum of the toner as measured by an X-ray diffraction instrument, a ratio {C/(C+A)} of an integral intensity C of the spectrum derived from the crystalline structure to an integral intensity A of the spectrum derived from the non-crystalline structure is 0.12 or greater, wherein the toner satisfies the following relation 1: T1−T2≦30° C. (Relation 1), where T1 represents the maximum endothermic peak in the first temperature rising from 0° C. to 100° C. at the temperature rising rate of 10° C./min and T2 represents the maximum exothermic peak in the first temperature falling from 100° C. to 0° C. at the temperature falling rate of 10° C./min as T1 and T2 are measured by diffraction scanning calorimetry (DSC).

摘要翻译： 调色剂含有含有具有氨基甲酸酯和/或脲键合的结晶性树脂的粘合剂树脂; 和着色剂，其中在通过X射线衍射仪测量的调色剂的衍射光谱中，从晶体结构衍生的光谱的积分强度C与积分强度之比{C /（C + A）} 衍生自非晶体结构的光谱的A为0.12或更大，其中调色剂满足以下关系1：T1-T2 @ 30℃（关系1），其中T1表示第一升温中的最大吸热峰 0℃至100℃，升温速率为10℃/分钟，T2表示在100℃至0℃的第一温度下的最大放热峰，温度下降速率为 10℃/ min，通过衍射扫描量热法（DSC）测量T1和T2。

公开(公告)号：US09851649B2

公开(公告)日：2017-12-26

申请号：US14891032

申请日：2013-11-27

申请人： Keiji Makabe ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Suzuka Amemori ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Daisuke Asahina ,  Satoyuki Sekiguchi

发明人： Keiji Makabe ,  Tsuyoshi Sugimoto ,  Akinori Saito ,  Suzuka Amemori ,  Toyoshi Sawada ,  Hiroshi Yamashita ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Daisuke Asahina ,  Satoyuki Sekiguchi

IPC分类号： G03G9/00 ,  G03G9/087 ,  G03G15/01

CPC分类号： G03G9/08788 ,  G03G9/08755 ,  G03G9/08791 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G15/0126

摘要： A toner includes a binder resin including a copolymer resin containing structural units derived from crystalline and non-crystalline resins, respectively. Spin-spin relaxation time (t50) of the toner at 50° C. measured by pulse NMR is ≦0.05 msec., spin-spin relaxation time (t130) at 130° C. when warmed from 50° C. to 130° C. is >15 msec., and spin-spin relaxation time (t′70) at 70° C. when cooled from 130° C. to 70° C. is ≦1.00 msec. A binarized image obtained by binarizing a phase image of the toner observed by a tapping mode AFM based on intermediate value between maximum and minimum phase difference values in the phase image includes first phase difference images constituted by large phase-difference portions and a second phase difference image constituted by a small phase-difference portion. The first phase difference images are dispersed in the second phase difference image. The dispersion diameter of the first phase difference images is 150 nm or less.

公开(公告)号：US09042802B2

公开(公告)日：2015-05-26

申请号：US14190459

申请日：2014-02-26

申请人： Takamasa Hase ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Hideyuki Santo ,  Minoru Masuda ,  Yukiko Iwasaki ,  Tsuneyasu Nagatomo

发明人： Takamasa Hase ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Hideyuki Santo ,  Minoru Masuda ,  Yukiko Iwasaki ,  Tsuneyasu Nagatomo

IPC分类号： G03G15/20

CPC分类号： G03G15/2064 ,  G03G15/2028 ,  G03G2215/2032 ,  G03G2215/2035

摘要： An image forming apparatus includes: an image bearing member; a charger; an irradiator; a development device having an accommodation unit to accommodate toner to obtain a visible image; a transfer device; and a fixing device to fix the visible image transferred onto a recording medium. The fixing device having a fixing rotation member; and a pressure rotation member to form a nipping portion by contacting the fixing rotation member, wherein the surface pressure of the nipping portion is 1.5 kgf/cm2 or less, wherein the fixing rotation member has a Martens hardness of 1.0 N/mm2 or less at 23° C., wherein the ratio of the projected area of a single particle of the toner onto the recording medium at 120° C. to the projected area of a single particle of the toner onto the recording medium at 23° C. is 1.60 or less.

摘要翻译： 图像形成装置包括：图像承载部件; 充电器 辐照器 具有容纳单元以容纳调色剂以获得可见图像的显影装置; 转移装置; 以及固定装置，用于固定转印到记录介质上的可见图像。 固定装置具有固定旋转构件; 以及压力旋转构件，其通过使所述固定旋转构件接触而形成夹持部，其中所述夹持部的表面压力为1.5kgf / cm 2以下，其中，所述固定旋转构件的马氏体硬度为1.0N / mm 2以下， 23℃，其中调色剂的单个颗粒在120℃下的投影面积与在23℃下记录介质上调色剂的单个颗粒的投影面积的比率为1.60 或更少。

公开(公告)号：US20140270874A1

公开(公告)日：2014-09-18

申请号：US14190459

申请日：2014-02-26

申请人： Takamasa Hase ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Hideyuki Santo ,  Minoru Masuda ,  Yukiko Iwasaki ,  Tsuneyasu Nagatomo

发明人： Takamasa Hase ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Hideyuki Santo ,  Minoru Masuda ,  Yukiko Iwasaki ,  Tsuneyasu Nagatomo

IPC分类号： G03G15/20

CPC分类号： G03G15/2064 ,  G03G15/2028 ,  G03G2215/2032 ,  G03G2215/2035

摘要： An image forming apparatus includes: an image bearing member; a charger; an irradiator; a development device having an accommodation unit to accommodate toner to obtain a visible image; a transfer device; and a fixing device to fix the visible image transferred onto a recording medium. The fixing device having a fixing rotation member; and a pressure rotation member to form a nipping portion by contacting the fixing rotation member, wherein the surface pressure of the nipping portion is 1.5 kgf/cm2 or less, wherein the fixing rotation member has a Martens hardness of 1.0 N/mm2 or less at 23° C., wherein the ratio of the projected area of a single particle of the toner onto the recording medium at 120° C. to the projected area of a single particle of the toner onto the recording medium at 23° C. is 1.60 or less.

摘要翻译： 图像形成装置包括：图像承载部件; 充电器 辐照器 具有容纳单元以容纳调色剂以获得可见图像的显影装置; 转移装置; 以及固定装置，用于固定转印到记录介质上的可见图像。 固定装置具有固定旋转构件; 以及压力旋转构件，其通过使所述固定旋转构件接触而形成夹持部，其中所述夹持部的表面压力为1.5kgf / cm 2以下，其中，所述固定旋转构件的马氏体硬度为1.0N / mm 2以下， 23℃，其中调色剂的单个颗粒在120℃下的投影面积与在23℃下记录介质上调色剂的单个颗粒的投影面积的比率为1.60 或更少。

公开(公告)号：US08795940B2

公开(公告)日：2014-08-05

申请号：US13684883

申请日：2012-11-26

申请人： Tsuyoshi Sugimoto ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

发明人： Tsuyoshi Sugimoto ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

IPC分类号： G03G9/08

CPC分类号： G03G9/08 ,  G03G9/0804 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner, including at least: a non-crystalline polyester resin; and a crystalline polyester resin, wherein the toner has a glass transition temperature in a first heating Tg1st and a glass transition temperature in a second heating Tg2nd, and a difference between Tg1st and Tg2nd (Tg1st-Tg2nd) is 10° C. or greater, and wherein the crystalline polyester resin is a modified crystalline polyester resin having a urethane skeleton or a urea skeleton, or both thereof.

摘要翻译： 提供至少包括非结晶性聚酯树脂的调色剂; 和结晶性聚酯树脂，其中调色剂在第一加热Tg1st中具有玻璃化转变温度，在第二加热Tg2nd中具有玻璃化转变温度，Tg1st和Tg2nd（Tg1st-Tg2nd）之间的差为10℃以上， 并且其中所述结晶性聚酯树脂是具有氨基甲酸酯骨架或脲骨架的改性结晶性聚酯树脂或其二者。

公开(公告)号：US20130157184A1

公开(公告)日：2013-06-20

申请号：US13684883

申请日：2012-11-26

申请人： Tsuyoshi SUGIMOTO ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

发明人： Tsuyoshi SUGIMOTO ,  Hiroshi Yamashita ,  Daisuke Asahina ,  Rintaro Takahashi ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Shingo Sakashita

IPC分类号： G03G9/08

CPC分类号： G03G9/08 ,  G03G9/0804 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08795 ,  G03G9/08797

摘要： To provide a toner, including at least: a non-crystalline polyester resin; and a crystalline polyester resin, wherein the toner has a glass transition temperature in a first heating Tg1st and a glass transition temperature in a second heating Tg2nd, and a difference between Tg1st and Tg2nd (Tg1st−Tg2nd) is 10° C. or greater, and wherein the crystalline polyester resin is a modified crystalline polyester resin having a urethane skeleton or a urea skeleton, or both thereof.

摘要翻译： 提供至少包括非结晶性聚酯树脂的调色剂; 和结晶性聚酯树脂，其中调色剂在第一加热Tg1st中具有玻璃化转变温度，在第二加热Tg2nd中具有玻璃化转变温度，Tg1st和Tg2nd（Tg1st-Tg2nd）之间的差为10℃以上， 并且其中所述结晶性聚酯树脂是具有氨基甲酸酯骨架或脲骨架的改性结晶性聚酯树脂或其二者。

公开(公告)号：US08883385B2

公开(公告)日：2014-11-11

申请号：US13705811

申请日：2012-12-05

申请人： Shingo Sakashita ,  Hiroshi Yamashita ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Yukiko Nakajima

发明人： Shingo Sakashita ,  Hiroshi Yamashita ,  Masahide Yamada ,  Shinya Nakayama ,  Atsushi Yamamoto ,  Yukiko Nakajima

IPC分类号： G03G9/097 ,  G03G9/08

CPC分类号： G03G9/08 ,  G03G9/0821 ,  G03G9/08755 ,  G03G9/08764 ,  G03G9/08782 ,  G03G9/08788 ,  G03G9/08793 ,  G03G9/08795 ,  G03G9/08797 ,  G03G9/097

摘要： A toner includes a binder resin, a coloring agent, and a releasing agent containing two or more kinds of alkyl monoester compounds having a different number of carbon atoms in a range of from 30 to 50 carbon atoms. The toner has a crystallinity of 10% or more as measured by x-ray diffraction and/or the binder resin is a crystalline resin in an amount of 50% by weight or more of the binder resin. The two or more kinds of alkyl monoester compounds include a component A accounting for the largest amount ranging from 30% by weight to less than 50% by weight of the releasing agent and a component B accounting for the second largest amount ranging from 10% by weight to less than 50% by weight of the releasing agent.

摘要翻译： 调色剂包括粘合剂树脂，着色剂和含有碳原子数不同于30至50碳原子的两种或更多种烷基单酯化合物的脱模剂。 调色剂通过x射线衍射测得的结晶度为10％以上，和/或粘合剂树脂为粘合剂树脂的50重量％以上的结晶性树脂。 两种或更多种烷基单酯化合物包括占脱模剂重量的30重量％至小于50重量％的最大量的组分A和占第二大量的组分B的10重量％ 重量至小于50重量％的脱模剂。