摘要:
A CRUDE AMMONIA SYNTHESIS GAS IS PASSED THROUGH A SCRUBBING ZONE IN WHICH IT IS CONTACTED BY A SCRUBBING SOLUTION COMPRISING LIQUID AMMONIA AND A SUBSTANCE FOR ASSISTING THE DISSOLUTION OF AMMONIA CARBAMATE, WITH THE AMMONIA BEING SUPPLIED AT A RATE SO THAT THE MOLAR RATIO OF NH3/CO2 IN THE SCRUBBING SOLUTION ADJACENT THE DISCHARGE END OF THE SCRUBBING ZONE IS AT LEAST 3,0:1, PREFERABLY 4.0:1 TO 20.0:1. RESIDUAL CARBON DIOXIDE IN THE AMMONIA SYNTHESIS GAS LEAVING THE SCRUBBING ZONE CAN BE REMOVED BY ADDING WATER OR AN AQUEOUS SOLUTION THERETO AND/OR BY SUBJECTING SAID GAS TO A METHANIZATION REACTION. HEAT IS REMOVED FROM SAID GAS, BY INDIRECT HEAT EXCHANGE, ONLY AFTER SUBSTANTIALLY ALL OF THE CARBON DIOXIDE HAS BEEN REMOVED THEREFROM.
摘要:
A process and apparatus for removing excess carbon dioxide from a crude ammonia synthesis gas to be used for producing ammonia and urea, in which the incoming crude ammonia synthesis gas is separated into two streams. One stream is flowed into a scrubbing zone wherein it is contacted with a scrubbing solution so that the partial pressure of the carbon dioxide in the one stream leaving the scrubbing zone is in the range of about 0.02-1.5 atmospheres, under a total pressure of above about 10 atmospheres, at a temperature of about 85*-130* C. The other stream is not scrubbed. The two streams are then combined and are fed to an ammonia and a urea synthesis system. The amount of carbon dioxide removed is changed by adjusting the amounts of gas flowing in the two streams.
摘要:
Olefins are manufactured by catalytically cracking a hydrocarbon feedstock by contacting said feedstock with steam at a temperature of 650*-900* C in the presence of a catalyst consisting essentially of at least 20 wt. percent of an oxide selected from the group consisting of beryllium oxide, calcium oxide and strontium oxide and the balance is aluminum oxide.
摘要:
In a circulating pressurized synthesis system, such as an ammonia synthesis system and a methanol synthesis system, a portion of the circulating stream of the circulatory synthesis system is separated from the circulating stream, fresh reactants are, if desired, added to the portion, and then the portion is compressed at least once to a pressure higher than that of the circulatory pressurized synthesis system. The compressed portion is passed through a synthesis reactor containing catalyst at high temperature so that a further reaction is promoted. The product obtained by the further synthesis reaction is separated from the effluent of the synthesis reactor, and, if desired, the energy which is generated by expanding the balance of the effluent to a pressure lower than that of the circulatory pressurized synthesis system is utilized to supply the power necessary to initially compress the portion.
摘要:
A PROCESS FOR PRODUCING FROM HYDROCARBONS A HYDROGEN-CONTAINING GAS IN WHICH A MIXTURE OF HYDROCARBONS AND A GASIFYING AGENT IS FED INTO A FURNACE WHERE IT IS HEATED BY A HIGH TEMPERATURE COMBUSTION GAS AND THE
COMBUSTION GAS IS THEN FED TO AT LEAST ONE TURBINE TO RECOVER USEFUL ENERGY.